Solid gold-nickel alloy nanoparticle

Patent metadata

Field	Value
Publication number	US-11229949-B2
Application number	US-201816021795-A
Country	US
Kind code	B2
Filing date	Jun 28, 2018
Priority date	Mar 16, 2012
Publication date	Jan 25, 2022
Grant date	Jan 25, 2022

Abstract

The purpose of the present invention is to provide novel solid gold-nickel alloy nanoparticles and a production method thereof. Provided are solid gold-nickel alloy nanoparticles having a particle diameter of 500 nm or less. In particular, gold-nickel alloy nanoparticle are provided in which the concentration of nickel in the gold-nickel alloy is 2.0-92.7 wt %, and the main component is a gold-nickel alloy in which gold and nickel are in a nano-level fine mixed state. The gold-nickel alloy particles have as the main component a substitutional solid solution of gold and nickel. These gold-nickel alloy particles are optimally formed by mixing and discharging gold ions, and a substance having reducing characteristics in the thin film fluid occurring between processing surfaces which are arranged facing each other, which can move towards and away from each other, and at least one of which rotates relative to the other.

First claim

The invention claimed is:

1. A gold-nickel alloy nanoparticle, which is a solid gold-nickel alloy nanoparticle having a particle diameter of larger than 10 nm, wherein as a result of microrange analysis of the solid gold-nickel alloy nanoparticle by an energy dispersive X-ray spectroscopy under observation with a transmission electron microscope (TEM-EDS) analysis using a beam diameter of 5 nm, molar ratios of gold and of nickel in 50% or more of analysis points thereof are detected within ±30% of molar ratios of gold and nickel obtained by inductively coupled plasma atomic emission spectrophotometry (ICP) analysis result of the solid gold-nickel alloy nanoparticle.

2. The gold-nickel alloy nanoparticle according to claim 1 , wherein the gold-nickel alloy nanoparticle forms a solid solution.

3. The gold-nickel alloy nanoparticle according to claim 1 , wherein the gold-nickel alloy nanoparticle is separated by mixing a gold ion, a nickel ion, and a substance having a reducing property in a thin film fluid formed between at least two processing surfaces which are disposed in a position facing each other so as to be able to approach to and separate from each other, at least one of which rotates relative to the other.

4. The gold-nickel alloy nanoparticle according to claim 3 , wherein the substance having a reducing property is at least two components each having a reducing property.

5. The gold-nickel alloy nanoparticle according to claim 4 , wherein the at least two components each having a reducing property is at least one component selected from the group consisting of a reducing agent, a dispersant showing a reducing property, and a solvent showing a reducing property.

6. The gold-nickel alloy nanoparticle according to claim 1 , wherein the gold-nickel alloy nanoparticle comprises 50% or more by volume of a substitutional solid solution.

7. The gold-nickel alloy nanoparticle according to claim 6 , wherein the substitutional solid solution is the one in which a lattice fringe in a surged state is observed in a crystallite thereof in a transmission electron microscope (TEM) picture or a scanning transmission electron microscope (STEM) picture.

8. The gold-nickel alloy nanoparticle according to claim 1 , wherein both gold and nickel are detected in the range of 2.0 to 92.7% by weight of concentration of nickel contained in the gold-nickel alloy in all of the analysis points as a result of the microrange analysis by the energy dispersive X-ray spectroscopy under observation with a transmission electron microscope (TEM-EDS) analysis using a beam diameter of 5 nm.

9. The gold-nickel alloy nanoparticle according to claim 1 , wherein both gold and nickel are detected in the range of 2.0 to 92.7% by weight of concentration of nickel contained in the gold-nickel alloy in all of the analysis points as a result of the microrange analysis by the energy dispersive X-ray spectroscopy under observation with a scanning transmission electron microscope (STEM-EDS) analysis using a beam diameter of 0.2 nm.

10. The gold-nickel alloy nanoparticle according to claim 1 , wherein the gold-nickel alloy nanoparticle has a particle diameter of larger than 10 nm and 500 nm or less.

11. The gold-nickel alloy nanoparticle according to claim 1 , wherein the gold-nickel alloy nanoparticle has a particle diameter of larger than 10 nm and 100 nm or less.

12. A gold-nickel alloy nanoparticle, which is a solid gold-nickel alloy nanoparticle, wherein as a result of microrange analysis of the solid gold-nickel alloy nanoparticle by an energy dispersive X-ray spectroscopy under observation with a scanning transmission electron microscope (STEM-EDS) analysis using a beam diameter of 0.2 nm, molar ratios of gold and nickel in 50% or more of analysis points thereof are detected within ±30% of molar ratios of gold and nickel obtained by inductively coupled plasma atomic emission spectrophotometry (ICP) analysis result of the solid gold-nickel alloy nanoparticle.

13. The gold-nickel alloy nanoparticle according to claim 12 , wherein the gold-nickel alloy nanoparticle forms a solid solution.

14. The gold-nickel alloy nanoparticle according to claim 12 , wherein the gold-nickel alloy nanoparticle is separated by mixing a gold ion, a nickel ion, and a substance having a reducing property in a thin film fluid formed between at least two processing surfaces which are disposed in a position facing each other so as to be able to approach to and separate from each other, at least one of which rotates relative to the other.

15. The gold-nickel alloy nanoparticle according to claim 12 , wherein the gold-nickel alloy nanoparticle has a particle diameter of larger than 10 nm.

16. The gold-nickel alloy nanoparticle according to claim 12 , wherein molar ratios of gold and nickel in 80% or more of analysis points thereof are detected within ±10% of molar ratios of gold and nickel obtained by inductively coupled plasma atomic emission spectrophotometry (ICP) analysis result of the solid gold-nickel alloy nanoparticle.

Assignees

• M Technique Co Ltd

Inventors

• Maekawa Masaki
• Araki Kazuya
• Honda Daisuke
• Enomura Masakazu

Classifications

• B22F1/09

  Mixtures of metallic powders · CPC title

• B22F1/07

  Metallic powder characterised by particles having a nanoscale microstructure (nanosized particles B22F1/054) · CPC title

• B22F9/24 Primary

  starting from liquid metal compounds, e.g. solutions · CPC title

• B82Y30/00

  Nanotechnology for materials or surface science, e.g. nanocomposites · CPC title

• C22C19/03

  based on nickel · CPC title