Systems and methods for selectively removing hydrogen sulfide from a feed gas stream

Patent metadata

Field	Value
Publication number	US-11229874-B2
Application number	US-201916454107-A
Country	US
Kind code	B2
Filing date	Jun 27, 2019
Priority date	Jul 20, 2018
Publication date	Jan 25, 2022
Grant date	Jan 25, 2022

Abstract

Systems and methods for selectively removing hydrogen sulfide from a feed gas stream. The systems include an absorber-heat exchanger (ABHEX) assembly configured to exchange thermal energy between a mixed stream and a thermal management fluid stream. The ABHEX assembly defines a mixed stream volume and a thermal management fluid stream volume. The ABHEX assembly includes an isolation structure that maintains fluid separation between the mixed stream and the thermal management fluid stream and facilitates thermal communication between the mixed stream and the thermal management fluid stream. The ABHEX assembly is configured to receive and to mix the feed gas stream and a lean solvent stream to generate the mixed stream, to separate the mixed stream into a product gas stream and a rich solvent stream, and to cool the mixed stream. The methods include methods of operating the systems.

First claim

The invention claimed is:

1. A selective hydrogen sulfide removal system, comprising:
an absorber-heat exchanger (ABHEX) assembly configured to exchange thermal energy between a mixed stream and a thermal management fluid stream, wherein the ABHEX assembly:
(i) defines a mixed stream volume configured to contain the mixed stream;
(ii) defines a thermal management fluid stream volume configured to contain the thermal management fluid stream; and
(iii) includes an isolation structure configured to maintain fluid separation between the mixed stream and the thermal management fluid stream and to facilitate thermal communication between the mixed stream and the thermal management fluid stream;
a feed gas supply conduit configured to provide a feed gas stream, which includes hydrogen sulfide, carbon dioxide, and hydrocarbon gas, to the mixed stream volume;
a lean solvent supply conduit configured to provide a lean solvent stream, which includes a hydrogen sulfide-absorbing solvent, to the mixed stream volume;
a product gas discharge conduit configured to discharge a product gas stream, which includes purified hydrocarbon gas and carbon dioxide from the feed gas stream, from the mixed stream volume;
a rich solvent discharge conduit configured to discharge a rich solvent stream, which includes a substantial portion of the hydrogen sulfide and the hydrogen sulfide-absorbing solvent, from the mixed stream volume;
a thermal management fluid supply conduit configured to provide the thermal management fluid stream to the thermal management fluid stream volume; and
a thermal management fluid discharge conduit configured to discharge the thermal management fluid stream from the thermal management fluid stream volume;
wherein the ABHEX assembly includes a shell and tube heat exchanger that defines a shell side and a tube side, wherein the shell side defines the thermal management fluid stream volume and the tube side defines the mixed stream volume; and
wherein the ABHEX assembly is configured to:
(i) mix the feed gas stream and the lean solvent stream, within the mixed stream volume, to facilitate selective absorption of hydrogen sulfide by the lean solvent stream and to generate the mixed stream;
(ii) separate the mixed stream into the product gas stream and the rich solvent stream; and
(iii) cool the mixed stream, via heat transfer to the thermal management fluid stream, to absorb thermal energy generated upon mixing of the feed gas stream and the lean solvent stream.

2. The selective hydrogen sulfide removal system of claim 1 , wherein the ABHEX assembly includes at least one turbulator configured to induce turbulent flow within the feed gas stream as the feed gas stream flows within the mixed stream volume.

3. The selective hydrogen sulfide removal system of claim 1 , wherein the selective hydrogen sulfide removal system further includes a feed gas stream cooling assembly configured to cool the feed gas stream to a feed gas stream temperature prior to supply of the feed gas stream to the ABHEX assembly.

4. The selective hydrogen sulfide removal system of claim 1 , wherein the selective hydrogen sulfide removal system further includes a water separation assembly configured to remove liquid water from the feed gas stream prior to supply of the feed gas stream to the ABHEX assembly.

5. The selective hydrogen sulfide removal system of claim 1 , wherein the hydrogen sulfide-absorbing solvent absorbs hydrogen sulfide at a hydrogen sulfide absorption rate and absorbs carbon dioxide at a carbon dioxide absorption rate that is less than the hydrogen sulfide absorption rate.

6. The selective hydrogen sulfide removal system of claim 1 , wherein the thermal management fluid supply conduit and the thermal management fluid discharge conduit are in fluid communication with a thermal management fluid supply system, and wherein the thermal management fluid supply conduit, the thermal management fluid stream volume, the thermal management discharge conduit, and the thermal management fluid supply system are configured to circulate the thermal management fluid stream in a closed loop.

7. The selective hydrogen sulfide removal system of claim 1 , wherein the ABHEX assembly is configured to fluidly contact the feed gas stream with the lean solvent stream to partition at least a portion of the hydrogen sulfide from the feed gas stream into the lean solvent stream and to generate the rich solvent stream and the product gas stream, and further wherein the selective hydrogen sulfide removal system further includes:
(i) a solvent regeneration assembly configured to separate the hydrogen sulfide from the rich solvent stream to generate an acid gas stream, which includes a substantial fraction of the hydrogen sulfide from the rich solvent stream, and a lean solvent recycle stream, which includes a substantial fraction of the hydrogen sulfide-absorbing solvent from the rich solvent stream; and
(ii) a solvent recirculation assembly configured to provide the lean solvent recycle stream to the ABHEX assembly as the lean solvent stream.

8. The selective hydrogen sulfide removal system of claim 7 , wherein the solvent recirculation assembly includes a circulation pump configured to convey the lean solvent recycle stream from the solvent regeneration assembly to the ABHEX assembly as the lean solvent stream.

9. The selective hydrogen sulfide removal system of claim 7 , wherein the solvent recirculation assembly includes a filter configured to remove particulate material from at least a portion of the lean solvent recycle stream.

10. The selective hydrogen sulfide removal system of claim 7 , wherein the solvent recirculation assembly includes a lean solvent cooling assembly configured to cool the lean solvent recycle stream to generate a cooled lean solvent recycle stream, which is provided to the ABHEX assembly as the lean solvent stream, wherein a cooled lean solvent recycle stream temperature of the cooled lean solvent recycle stream is less than a lean solvent recycle stream temperature of the lean solvent recycle stream.

11. The selective hydrogen sulfide removal system of claim 7 , wherein the selective hydrogen sulfide removal system includes a flash vessel configured to vaporize a portion of the rich solvent stream to generate a vaporized rich solvent stream prior to supply of the rich solvent stream to the solvent regeneration assembly.

12. The selective hydrogen sulfide removal system of claim 7 , wherein the selective hydrogen sulfide removal system includes a rich/lean heat exchanger configured to exchange thermal energy between the rich solvent stream and the lean solvent recycle stream.

13. The selective hydrogen sulfide removal system of claim 7 , wherein the solvent regeneration assembly includes a stripping vessel.

14. The selective hydrogen sulfide removal system of claim 13 , wherein the solvent regeneration assembly further includes a reboiler assembly configured to receive the lean solvent recycle stream from the stripping vessel and to vaporize at least a portion of the lean solvent recycle stream to generate a vaporized solvent return stream, wherein the stripping vessel includes a vaporized solvent return stream inlet configured to receive a portion of the vaporized solvent return stream.

15. The selective hydrogen sulfide removal system of claim 14 , wherein the solvent regeneration assembly further includes a reflux system configured to return at least a portion of the acid gas stream to the stripping vessel as a reflux stream.

16. The selective hydrogen sulfide removal system of claim 15 , wherein the reflux

Assignees

• Victory Donald J
• Mondkar Suhas P
• Northrop P Scott
• Seagraves Jenny P
• Exxonmobil Upstream Res Co

Inventors

• Victory Donald J
• Mondkar Suhas P
• Northrop P Scott
• Seagraves Jenny P

Classifications

• B01D2256/24

  Hydrocarbons · CPC title

• C10L2290/541

  Absorption of impurities during preparation or upgrading of a fuel · CPC title

• C10L3/103

  Sulfur containing contaminants · CPC title

• B01D2252/204

  Amines · CPC title

• B01D2257/504

  Carbon dioxide · CPC title