Mist elimination system for electrochemical cells

Patent metadata

Field	Value
Publication number	US-11228066-B2
Application number	US-201716318560-A
Country	US
Kind code	B2
Filing date	Jul 24, 2017
Priority date	Jul 22, 2016
Publication date	Jan 18, 2022
Grant date	Jan 18, 2022

Abstract

An electrochemical cell includes a mist elimination system that prevents mist from escaping from the cell chamber and conserves moisture within the cell. An exemplary mist elimination system includes a spill prevention device that reduces or prevents an electrolyte from escaping from the cell chamber in the event of an upset, wherein the electrochemical cell is tipped over. A mist elimination system includes a recombination portion that reacts with hydrogen to produce water, that may be reintroduced into the cell chamber. A mist elimination system includes a neutralizer portion that reacts with an electrolyte to bring the pH closer to neutral, as acid/base reaction. A mist elimination system includes a filter that captures mist that may be reintroduced into the cell chamber. A mist elimination system includes a hydrophobic filter on the outer surface to prevent water and other liquids from entering into the mist elimination system.

First claim

What is claimed is:

1. An electrochemical cell comprising:
a cell housing comprising:
i) an air chamber;
ii) an air chamber air inlet;
iii) an air chamber air outlet;
iv) an electrolyte chamber,

an ionically conductive liquid electrolyte in the electrolyte chamber, wherein a gas space is defined in the electrolyte chamber above the electrolyte and has a cell gas;
an oxidant reduction electrode for reducing a gaseous oxidant between the air chamber and the electrolyte chamber,
a fuel electrode comprising a metal fuel at least partially within the electrolyte chamber;
a mist elimination system configured between the electrolyte chamber and an exhaust vent to separate the cell gas from a mist comprising the ionically conductive liquid electrolyte; wherein the mist elimination system is configured above the volume of ionically conductive liquid electrolyte; the mist elimination system comprising:
a spill prevention device;
a hydrogen recombination portion, comprising a hydrogen recombination catalyst configured to react with hydrogen gas within the cell gas and form water;
a filter body portion comprised of at least one layer of filter media for capturing said mist;
a neutralizer portion comprising a neutralizer media configured to react with and neutralize the ionically conductive liquid electrolyte contained within the mist; and

wherein the filter body portion contains pores to permit permeation of said cell gas therethrough,
wherein the neutralizer portion is configured downstream of the hydrogen recombination portion, the filter body portion, and the spill prevention device.

2. The electrochemical cell of claim 1 , wherein the spill prevention device comprising a tortuous path conduit, from an inlet to an outlet, for transferring cell gas therethrough;
wherein the tortuous path conduit inlet faces the electrolyte chamber for receiving cell gas.

3. The electrochemical cell of claim 1 , wherein the spill prevention device comprises a safety valve.

4. The electrochemical cell of claim 3 , wherein the safety valve comprises a ball retained within a conduit having a sealing seat on a downstream side, wherein the ball is pressed against the sealing seat to prevent liquid passage through the safety valve when liquid enters the conduit.

5. The electrochemical cell of claim 1 , wherein the filter body portion is formed in a concave shape with an apex directed upwardly in the cell's upright orientation, and body surface extending downwardly from said apex so as to drain absorbed ionically conductive medium back into the electrolyte chamber.

6. The electrochemical cell of claim 1 , wherein the water from the reaction of hydrogen with the recombination catalyst is introduced back into the cell through the spill prevention device.

7. The electrochemical cell of claim 1 , wherein the hydrogen recombination catalyst is selected from the group consisting of: perovskites, spinels, precious metal based-platinum, palladium, MnO 2 , Nickel and a combination thereof.

8. The electrochemical cell of claim 1 , wherein the hydrogen recombination portion is configured downstream of the spill prevention device.

9. The electrochemical cell of claim 1 , wherein the neutralizer media comprises an acid component.

10. The electrochemical cell of claim 1 , wherein the neutralizer media comprises an acid component selected from the group consisting of: citric, oxalic, carboxylic, sulfamic, benzoic, boric, sulfuric, hydrochloric, and nitric acid.

11. The electrochemical cell of claim 1 , wherein the neutralizer media comprises a solid acid.

12. The electrochemical cell of claim 1 , wherein the mist elimination system further comprises a hydrophobic filter configured downstream of the neutralizer portion on an exhaust end of the mist elimination system.

13. The electrochemical cell of claim 12 , wherein the hydrophobic filter comprises a fluoropolymer filter media.

14. The electrochemical cell of claim 12 , wherein the hydrophobic filter comprises an expanded microporous fluoropolymer filter media.

15. The electrochemical cell of claim 1 , wherein the mist elimination system comprises a first mist elimination stack and a second mist elimination stack, wherein each of the first mist elimination stack and the second mist elimination stack comprises: the hydrogen recombination portion, the filter body portion, and the neutralizer portion, wherein each filter body portion contains pores to permit permeation of said cell gas therethrough, wherein each neutralizer portion is configured downstream of the hydrogen recombination portion and the filter body portion in their respective stack, and wherein the second mist elimination stack is stacked over the first mist elimination stack.

16. The electrochemical cell according to claim 1 , wherein the spill prevention device comprises a safety valve comprising:
a ball retained within a conduit;
a sealing seat on a downstream side of said conduit,
wherein the ball is pressed against the sealing seat to prevent liquid passage through the safety valve when liquid enters the conduit; and
wherein the mist elimination system further comprises:
a hydrophobic filter,
wherein the hydrophobic filter is configured on an exhaust end of the mist elimination system;
and
wherein the hydrophobic filter is configured downstream of the neutralizer portion and is on an exterior of a mist elimination system.

17. The electrochemical cell of claim 1 , wherein the mist elimination system comprises a stack comprising the hydrogen recombination portion, the filter body portion, and the neutralizer portion.

18. The electrochemical cell of claim 1 , wherein the fuel electrode is positioned apart from the oxidant reduction electrode, thereby defining a gap, and wherein said ionically conductive liquid electrolyte is in the gap.

Assignees

• Form Energy Inc

Inventors

• Krishnan Ramkumar
• Hayes Joel
• Klug Scott
• Samuleson Patrick
• Trzebny Craig

Classifications

• H01M50/367

  Internal gas exhaust passages forming part of the battery cover or case; Double cover vent systems · CPC title

• Y02E60/50

  Fuel cells · CPC title

• H01M4/38 Primary

  of elements or alloys · CPC title

• H01M50/394

  Gas-pervious parts or elements · CPC title

• Y02E60/10

  Energy storage using batteries · CPC title