Fine silver particle dispersion

Patent metadata

Field	Value
Publication number	US-11227702-B2
Application number	US-201916374882-A
Country	US
Kind code	B2
Filing date	Apr 4, 2019
Priority date	Apr 4, 2019
Publication date	Jan 18, 2022
Grant date	Jan 18, 2022

Abstract

This disclosure relates to a fine silver particle dispersion including: (1) 65 to 95.4% by weight of fine silver particles which have an average primary particle diameter of 10 to 190 nm and which comprise 25% by number or less of silver particles having a primary particle diameter of 100 nm or larger, (2) 4.5 to 34.5% by weight of a solvent, and (3) 0.1 to 1.0% by weight of ethyl cellulose having a weight average molecular weight of 10,000 to 120,000.

First claim

What is claimed is:

1. A fine silver particle dispersion comprising:
(1) 65 to 95.4% by weight of fine silver particles which have an average primary particle diameter of 10 to 190 nm and which comprise 25% by number or less of silver particles having a primary particle diameter of 100 nm or larger,
(2) 4.5 to 34.5% by weight of a solvent, and
(3) 0.3 to 0.6% by weight of ethyl cellulose having a weight average molecular weight of 30,000 to 105,000,
wherein the fine silver particle dispersion contains does not contain terpene and does not contain silver microparticles having an average primary particle diameter of 1 μm or more.

2. The fine silver particle dispersion of claim 1 , wherein the fine silver particles are coated with an organic protective material.

3. The fine silver particle dispersion of claim 2 , wherein the organic protective material is an amine with carbon number of from 8 to 12.

4. The fine silver particle dispersion of claim 1 , wherein a boiling point of the solvent is 150 to 350° C.

5. The fine silver particle dispersion of claim 1 , wherein the solvent is selected from the group consisting of diethylene glycol monobutyl ether, diethylene glycol dibutyl ether, diethylene glycol monobutyl ether acetate, and a mixture thereof.

6. The fine silver particle dispersion of claim 1 , wherein a viscosity of the fine silver particle dispersion is 30 to 350 Pa·s.

7. The fine silver particle dispersion of claim 1 , wherein the ethyl cellulose has a weight average molecular weight of 50,000 to 90,000.

8. The fine silver particle dispersion of claim 1 , comprising 0.3 to 0.5% by weight of the ethyl cellulose.

9. The fine silver particle dispersion of claim 8 , wherein the ethyl cellulose has a weight average molecular weight of from 50,000 to 90,000.

10. The fine silver particle dispersion of claim 8 , wherein the ethyl cellulose has a weight average molecular weight of from 65,000 to 85,000.

11. The fine silver particle dispersion of claim 1 , wherein the fine silver particles have an average primary particle diameter of 25 to 110 nm.

12. The fine silver particle dispersion of claim 1 , comprising 70 to 87% by weight of the fine silver particles.

13. The fine silver particle dispersion of claim 1 , wherein the fine silver particles comprise 15% by number or less of silver particles having a primary particle diameter of 100 nm or larger.

14. The fine silver particle dispersion of claim 1 , further comprising a substance having a weight average molecular weight of 150,000 or more, and wherein an amount of the substance in the fine silver particle dispersion is 0.09% by weight or less.

15. The fine silver particle dispersion of claim 1 , comprising 11.1 to 31.5% by weight of the solvent.

16. The fine silver particle dispersion of claim 1 , further comprising a substance having a weight average molecular weight of 150,000 or more, and wherein an amount of the substance in the fine silver particle dispersion is 0.05% by weight or less.

17. The fine silver particle dispersion of claim 1 , wherein the dispersion has 0.1 to 1.0%, of ethyl cellulose with a weight average molecular weight of 10,000 to 120,000.

18. A fine silver particle dispersion comprising:
(1) 65 to 95.4% by weight of fine silver particles which have an average primary particle diameter of 10 to 190 nm and which comprise 25% by number or less of silver particles having a primary particle diameter of 100 nm or larger,
(2) 4.5 to 34.5% by weight of a solvent, and
(3) 0.3 to 0.6% by weight of ethyl cellulose having a weight average molecular weight of 30,000 to 885,000,
wherein the fine silver particle dispersion does not contain silver microparticles having an average primary particle diameter of 1 μm or more.

19. The fine silver particle dispersion of claim 18 , wherein the solvent consists of a solvent selected from the group consisting of diethylene glycol monobutyl ether, diethylene glycol dibutyl ether, diethylene glycol monobutyl ether acetate, and a mixture thereof.

Assignees

• Dowa Electronics Materials Co Ltd

Inventors

• Teragawa Shingo
• Hinotsu Takashi
• Hui Dave
• Wolfe Michael Stephen
• Glicksman Howard David
• Yang Haixin

Classifications

• B22F1/147

  Making a dispersion · CPC title

• B22F1/145

  Chemical treatment, e.g. passivation or decarburisation · CPC title

• B22F1/0545

  Dispersions or suspensions of nanosized particles · CPC title

• B22F1/052

  characterised by a mixture of particles of different sizes or by the particle size distribution · CPC title

• B22F1/102

  Metallic powder coated with organic material · CPC title