Method for producing aluminum

Patent metadata

Field	Value
Publication number	US-11225725-B2
Application number	US-201916506081-A
Country	US
Kind code	B2
Filing date	Jul 9, 2019
Priority date	Feb 9, 2017
Publication date	Jan 18, 2022
Grant date	Jan 18, 2022

Abstract

A method for producing aluminum includes: a dissolution step of dissolving a hydrate containing Al in water to prepare an aqueous solution that contains Al ions; an extraction step of bringing an organic phase that is composed of an extractant into contact with an aqueous phase that is composed of the aqueous solution to extract the Al ions in the aqueous phase into the organic phase; and an electrodeposition step of electrolyzing the organic phase as an electrolytic solution to electrodeposit metallic Al onto a surface of a cathode from the Al ions in the electrolytic solution.

First claim

What is claimed is:

1. A method for producing aluminum comprising:
a dissolution step of dissolving a hydrate containing aluminum in water to prepare an aqueous solution that contains aluminum ions;
an extraction step of bringing an organic phase that is composed of an extractant into contact with an aqueous phase that is composed of the aqueous solution to extract the aluminum ions in the aqueous phase into the organic phase; and
an electrodeposition step of electrolyzing the organic phase as an electrolytic solution to electrodeposit metallic aluminum onto surface of a cathode from the aluminum ions in the electrolytic solution,
in the dissolution step, a concentration of the aluminum ions in the prepared aqueous solution being 0.01 to 1 M;
as for extraction conditions in the extraction step, a volume ratio between the aqueous phase and the organic phase that are brought into contact with each other (aqueous phase/organic phase) being 0.1 to 2, a bath temperature being 20 to 100° C., and a stirring time period being 1 to 60 minutes; and
as for electrodeposition conditions in the electrodeposition step, a bath temperature being 20 to 350° C., and an electric current density being 1 to 1000 μA/cm 2 .

2. The method for producing aluminum according to claim 1 , wherein the hydrate containing aluminum is a hydrate of an aluminum halide.

3. The method for producing aluminum according to claim 1 , wherein the electrolytic solution is the organic phase from which the aqueous phase is separated after the extraction step.

4. The method for producing aluminum according to claim 1 , wherein the extractant is a hydrophobic ionic liquid including an imidazolium-based cation and an imide-based or amide-based anion.

5. The method for producing aluminum according to claim 4 , wherein the imidazolium-based cation is 1-butyl-3-methylimidazolium cation and the imide-based anion is bis(nonafluorobutanesulfonyl) imide anion.

Assignees

• Uacj Corp

Inventors

• NUNOMURA Junji
• Honkawa Yukio
• Kojima Yoichi
• Ueda Mikito

Classifications

• C25C3/18 Primary

  Electrolytes · CPC title