Polymer compositions including a poly(ether sulfone) blend and articles made therefrom

Patent metadata

Field	Value
Publication number	US-11225574-B2
Application number	US-201615780194-A
Country	US
Kind code	B2
Filing date	Nov 25, 2016
Priority date	Dec 1, 2015
Publication date	Jan 18, 2022
Grant date	Jan 18, 2022

Abstract

Described herein are polymer compositions having a poly(ether sulfone) polymer and (i) a polysulfone polymer or (ii) a poly(phenyl sulfone) polymer. In some embodiments, the polymer compositions can optionally include one or more additives. It has been surprisingly found that the aforementioned polymer compositions have outstanding anti-stick properties with respect to proteins.

First claim

The invention claimed is:

1. An article comprising a surface configured to contact a protein, the surface comprising a polymer composition, the polymer composition comprising:
component (a): from about 50 wt. % to about 98.5 wt. % of a poly(ether sulfone), PES polymer (M1);
component (b):
from about 1 wt. % to about 40 wt. % of a polysulfone, PSU polymer (M2), or
from about 1 wt. % to about 40 wt. % of a poly(phenyl ether sulfone), PPSU polymer (M3), or
from about 1 wt. % to about 40 wt. % of a mixture of the PSU polymer (M2) and the PPSU polymer (M3);

optionally from about 1 wt. % to about 40 wt. % of at least one clay mineral filler (F) wherein all the wt. % are relative to the total weight of the polymer composition and with the proviso that if the polymer composition comprises from about 1 wt. % to about 7 wt. % of the PPSU polymer (M3), the clay mineral filler (F) is present from at least about 7 wt. % to about 40 wt. %,
wherein the PES polymer (M1) comprises at least 80 mol. % of recurring units (R PES ) of formula (II):

wherein:
each R i , equal to or different from each other, is selected from the group consisting of a halogen, an alkyl, an alkenyl, an alkynyl, an aryl, an ether, a thioether, a carboxylic acid, an ester, an amide, an imide, an alkali or alkaline earth metal sulfonate, an alkyl sulfonate, an alkali or alkaline earth metal phosphonate, an alkyl phosphonate, an amine, and a quaternary ammonium, and
each i, equal to or different from each other, is an integer ranging from 0 to 4.

2. The article of claim 1 , wherein the clay mineral filler (F) is kaolin or mica.

3. The article of claim 1 , wherein the polymer composition is free of a polysulfone, PSU polymer (M2).

4. The article of claim 1 , wherein the polymer composition comprises from about 67 wt. % to about 95 wt. % of component (a).

5. The article of claim 4 further comprising about 5 wt. % to about 10 wt. % of component (b).

6. The article of claim 1 , wherein the surface comprises a substrate and a film or coating having an average thickness from about 25 μm to about 1 mm disposed on the substrate, and wherein the film or coating comprises the polymer composition.

7. The article of claim 1 , wherein the article is selected from the group consisting of a food container, a food utensil, and a medical article.

8. The article of claim 1 , wherein the PES polymer (M1) has a glass transition temperature of at least about 200° C., as measured by differential scanning calorimetry according to the ASTM D3418 standard.

9. A method for reducing sticking between the article of claim 1 and a protein, the method comprising forming at least a portion of the surface from the polymer composition.

10. A process for preparing the article of claim 1 , the process comprising:
blending components (a) and (b), and optionally the clay mineral filler (F), and optionally other ingredients, and
forming the surface comprising the polymer composition, or coating or laminating at least one different surface of the article with the polymer composition to form the surface comprising the polymer composition.

11. A polymer composition comprising:
component (a): from about 60 wt. % to about 98.5 wt. % of a poly(ether sulfone), PES polymer (M1);
component (b):
from about 1 wt. % to about 20 wt. % of a polysulfone, PSU polymer (M2), or
from about 1 wt. % to about 40 wt. % of a poly(phenyl ether sulfone), PPSU polymer (M3), or
from about 1 wt. % to about 40 wt. % of a mixture of the PSU polymer (M2) and the PPSU polymer (M3);

optionally from about 1 wt. % to about 40 wt. % of at least one clay mineral filler (F) wherein all the wt. % are relative to the total weight of the polymer composition and with the proviso that if the polymer composition comprises from about 1 wt. % to about 7 wt. % of the PPSU polymer (M3), the clay mineral filler (F) is present from at least about 7 wt. % to about 40 wt. %,
wherein the PES polymer (M1) comprises at least 80 mol. % of recurring units (R PES ) of formula (II):

wherein:
each R i , equal to or different from each other, is selected from the group consisting of a halogen, an alkyl, an alkenyl, an alkynyl, an aryl, an ether, a thioether, a carboxylic acid, an ester, an amide, an imide, an alkali or alkaline earth metal sulfonate, an alkyl sulfonate, an alkali or alkaline earth metal phosphonate, an alkyl phosphonate, an amine, and a quaternary ammonium, and
each i, equal to or different from each other, is an integer ranging from 0 to 4.

12. The polymer composition of claim 11 , wherein the PSU polymer (M2) is of formula (X):

wherein:
each R k , equal to or different from each other, is selected from the group consisting of a halogen, an alkyl, an alkenyl, an alkynyl, an aryl, an ether, a thioether, a carboxylic acid, an ester, an amide, an imide, an alkali or alkaline earth metal sulfonate, an alkyl sulfonate, an alkali or alkaline earth metal phosphonate, an alkyl phosphonate, an amine, and a quaternary ammonium;
R′ and R″, equal to or different from each other, is selected from the group consisting of a hydrogen, a halogen, an alkyl, an alkenyl, an alkynyl, an aryl, an ether, a thioether, a carboxylic acid, an ester, an amide, an imide, an alkali or alkaline earth metal sulfonate, an alkyl sulfonate, an alkali or alkaline earth metal phosphonate, an alkyl phosphonate, an amine, and a quaternary ammonium; and
each k, equal to or different from each other, is an integer ranging from 0 to 4.

13. The polymer composition of claim 12 , wherein each k=0, R′ and R″ are a methyl group, or both.

14. The polymer composition of claim 11 , wherein the PPSU polymer (M3) is of formula (XII):

wherein:
each R l , equal to or different from each other, is selected from the group consisting of a halogen, an alkyl, an alkenyl, an alkynyl, an aryl, an ether, a thioether, a carboxylic acid, an ester, an amide, an imide, an alkali or alkaline earth metal sulfonate, an alkyl sulfonate, an alkali or alkaline earth metal phosphonate, an alkyl phosphonate, an amine, and a quaternary ammonium, and
each l, equal to or different from each other, is an integer ranging from 0 to 4.

15. The polymer composition of claim 14 , wherein each l=0, the mineral filler (F) comprises kaolin or mica, or both.

16. The polymer composition of claim 11 , wherein the polymer composition comprises less than 0.1 wt. % of the PSU polymer (M2).

17. An article comprising a surface configured to contact a protein, the surface comprising the polymer composition of claim 11 , wherein the article is selected from the group consisting of a food container, a food utensil, and a medical article.

Assignees

• Solvay Specialty Polymers Usa

Inventors

• Momtaz Maryam

Classifications

• C08G75/20

  Polysulfones · CPC title

• C08L71/02

  Polyalkylene oxides · CPC title

• C08L81/06 Primary

  Polysulfones; Polyethersulfones · CPC title

• A47J36/025

  Vessels with non-stick features, e.g. coatings · CPC title

• C08L71/00

  Compositions of polyethers obtained by reactions forming an ether link in the main chain (of polyacetals C08L59/00; of epoxy resins C08L63/00; of polythioether-ethers C08L81/02; of polyether-sulfones C08L81/06); Compositions of derivatives of such polymers · CPC title