Adsorbents comprising organic-inorganic hybrid nanoporous materials for sorption of water or alcohol and use thereof

Patent metadata

Field	Value
Publication number	US-11224856-B2
Application number	US-201615575246-A
Country	US
Kind code	B2
Filing date	May 18, 2016
Priority date	May 18, 2015
Publication date	Jan 18, 2022
Grant date	Jan 18, 2022

Abstract

Provided are a water and/or alcohol adsorbent including organic-inorganic hybrid nanoporous materials, and use thereof, and more particularly, a water and/or alcohol adsorbent having a high adsorption amount at a low relative humidity or partial pressure, of which desorption/regeneration is possible at a low temperature, the water and/or alcohol adsorbent including organic-inorganic hybrid nanoporous materials having 0.5 to 3 mol of a hydroxyl group (OH) or a hydroxide anion group (OH − ) per 1 mol of a central metal ion, and use thereof.

First claim

The invention claimed is:

1. An adsorption heat transfer device using water or alcohol as a working fluid, the adsorption heat transfer device comprising, as a water adsorbent or an alcohol adsorbent, an organic-inorganic hybrid nanoporous material having 0.5 to 3 mol of i) hydrophilic hydroxyl group (OH), or ii) hydroxide anion group (OH − ) as a ligand per 1 mol of a central metal ion in a nanopore, wherein the organic-inorganic hybrid nanoporous material has a structure selected from an orthorhombic space group and a tetragonal space group, and wherein the central metal ion is an aluminum ion.

2. An adsorption water controlling device comprising, as a water adsorbent, an organic-inorganic hybrid nanoporous material having 0.5 to 3 mol of i) hydrophilic hydroxyl group (OH), or ii) hydroxide anion group (OH − ) as a ligand per 1 mol of a central metal ion in a nanopore, wherein the organic-inorganic hybrid nanoporous material has a structure selected from an orthorhombic space group and a tetragonal space group, and wherein the central metal ion is an aluminum ion.

3. The adsorption device of claim 1 , wherein the organic-inorganic hybrid nanoporous material has a water or alcohol adsorption capacity of 0.15 gram or more per 1 gram or 1 milliliter thereof at a saturation vapor pressure of the adsorbate.

4. The adsorption device of claim 1 , wherein the adsorption heat transfer device is a heat pump, a heating or cooling system, or a refrigerator.

5. The adsorption device of claim 1 , wherein the organic-inorganic hybrid nanoporous material as the water or alcohol adsorbent is regenerated by desorbing 80% or more of the total adsorption amount of adsorbed water or alcohol at 150° C. or lower.

6. The adsorption device of claim 5 , wherein the organic-inorganic hybrid nanoporous material as the water or alcohol adsorbent is regenerated by desorbing 50% or more of the total adsorption amount of adsorbed water or alcohol at 100° C. or lower.

7. The adsorption device of claim 1 , wherein the organic-inorganic hybrid nanoporous material as the water adsorbent or alcohol adsorbent exhibits adsorption of 50% or more of the total adsorption amount of the water or alcohol working fluid at a partial pressure p/p 0 of 0.10 to 0.50 (herein, p 0 represents a saturated vapor pressure at an application temperature and p represents a vapor pressure upon adsorption).

8. The adsorption device of claim 1 , wherein the ligand is one or more selected from the group consisting of furan dicarboxylic acid anion, pyridine dicarboxylic acid anion, thiophene dicarboxylic acid anion, and pyrazole dicarboxylic acid anion.

9. The adsorption device of claim 1 , wherein the organic-inorganic hybrid nanoporous material is represented by any one of the following Chemical Formulae 1 to 8:
[Al(OH)[(O 2 C)—C 4 OH 2 —(CO 2 )]. n (solvent)  [Chemical Formula 1]

[Al(OH)[(O 2 C)—C 4 OH 2 —(CO 2 )]  [Chemical Formula 2]

[Al(OH)[(O 2 C)—C 5 NH 3 —(CO 2 )]. n (solvent)  [Chemical Formula 3]

[Al(OH)[(O 2 C)—C 5 NH 3 —(CO 2 )]  [Chemical Formula 4]

[Al(OH))[(O 2 C)—C 4 SH 2 —(CO 2 )]. n (solvent)  [Chemical Formula 5]

[Al(OH)[(O 2 C)—C 4 SH 2 —(CO 2 )]  [Chemical Formula 6]

Al 2 (OH) 4 [(O 2 C)—C 3 N 2 H 2 —(CO 2 )]. n (solvent)  [Chemical Formula 7]

Al 2 (OH) 4 [(O 2 C)—C 3 N 2 H 2 —(CO 2 )]  [Chemical Formula 8]

in Chemical Formula 1, the solvent is H 2 O, and n is a real number of 0.1 to 10,
in Chemical Formula 3, the solvent is H 2 O, an organic solvent, or a combination thereof, and n is a real number of 0.1 to 10,
in Chemical Formula 5, the solvent is H 2 O, an organic solvent, or a combination thereof, and n is a real number of 0.1 to 10, and
in Chemical Formula 7, the solvent is H 2 O, and n is a real number of 0.1 to 10.

10. An organic-inorganic hybrid nanoporous material having a structure selected from an orthorhombic space group and a tetragonal space group, the organic-inorganic hybrid nanoporous material comprising 0.5 to 3 mol of i) hydrophilic hydroxyl group (OH), or ii) hydroxide anion (OH − ) group as a ligand per 1 mol of a central metal ion, and wherein the central metal ion is an aluminum ion.

11. The organic-inorganic hybrid nanoporous material of claim 10 , which is represented by any one of the following Chemical Formulae 1 to 8:
[Al(OH)[(O 2 C)—C 4 OH 2 —(CO 2 )]. n (solvent)  [Chemical Formula 1]

[Al(OH)[(O 2 C)—C 4 OH 2 —(CO 2 )]  [Chemical Formula 2]

[Al(OH)[(O 2 C)—C 5 NH 3 —(CO 2 )]. n (solvent)  [Chemical Formula 3]

[Al(OH)[(O 2 C)—C 5 NH 3 —(CO 2 )]  [Chemical Formula 4]

[Al(OH))[(O 2 C)—C 4 SH 2 —(CO 2 )]. n (solvent)  [Chemical Formula 5]

[Al(OH)[(O 2 C)—C 4 SH 2 —(CO 2 )]  [Chemical Formula 6]

Al 2 (OH) 4 [(O 2 C)—C 3 N 2 H 2 —(CO 2 )]. n (solvent)  [Chemical Formula 7]

Al 2 (OH) 4 [(O 2 C)—C 3 N 2 H 2 —(CO 2 )]  [Chemical Formula 8]

in Chemical Formula 1, the solvent is H 2 O, and n is a real number of 0.1 to 10,
in Chemical Formula 3, the solvent is H 2 O, an organic solvent, or a combination thereof, and n is a real number of 0.1 to 10,
in Chemical Formula 5, the solvent is H 2 O, an organic solvent, or a combination thereof, and n is a real number of 0.1 to 10, and
in Chemical Formula 7, the solvent is H 2 O, and n is a real number of 0.1 to 10.

12. The adsorption device of claim 2 , wherein the organic-inorganic hybrid nanoporous material has a water or alcohol adsorption capacity of 0.15 gram or more per 1 gram or 1 milliliter thereof at a saturation vapor pressure of the adsorbate.

13. The adsorption device of claim 2 , wherein the adsorption water controlling device is a dehumidifier, a dryer, or a humidifier.

14. The adsorption device of claim 2 , wherein the organic-inorganic hybrid nanoporous material as the water or alcohol adsorbent is regenerated by desorbing 80% or more of the total adsorption amount of adsorbed water or alcohol at 150° C. or lower.

15. An organic light emitting device or a secondary battery device comprising, as a getter, the organic-inorganic hybrid nanoporous material of claim 10 .

16. A method of adsorbing water or alcohol, by using, as a water or alcohol adsorbent, the organic-inorganic hybrid nanoporous material of claim 10 .

17. The method of claim 16 , wherein in the organic-inorganic hybrid nanoporous material, the central metal ion forms octahedral coordinate bonds and square-shaped porous channels.

Assignees

• Korea Res Inst Chemical Tech

Inventors

• Chang Jong San
• Lee U Hwang
• Hwang Young Kyu
• Serre Christian
• Devic Thomas
• Cadiau Amandine
• Stock Norbert
• Reimer Nele
• Wharmby Michael T

Classifications

• C07F5/069

  without C-aluminium linkages · CPC title

• H01M10/4235

  Safety or regulating additives or arrangements in electrodes, separators or electrolyte (H01M10/4242 takes precedence) · CPC title

• B01J20/28069

  Pore volume, e.g. total pore volume, mesopore volume, micropore volume · CPC title

• Y02E60/10

  Energy storage using batteries · CPC title

• B01J20/3085

  Chemical treatments not covered by groups B01J20/3007 - B01J20/3078 · CPC title