Methods for the separation of at least one emulsion by applying an electrical field and device for carrying out said method

Patent metadata

Field	Value
Publication number	US-11224828-B2
Application number	US-202117140325-A
Country	US
Kind code	B2
Filing date	Jan 4, 2021
Priority date	Jan 29, 2016
Publication date	Jan 18, 2022
Grant date	Jan 18, 2022

Abstract

The present invention relates to a method for the break-up of at least one emulsion and separation of the light and heavy phase with at least an de-emulsification rate of more than 95% in only one apparatus (module) within less than 5 min by applying at least one time dependent or temporal changeable electrical field wherein the at least one electrical field is a high frequency (HF) singular alternating current (AC) field with an electrical field strength between 2,000 and 100,000 V/m and a frequency (HF) between 12,000 Hz and 200,000 Hz. The present invention relates furthermore to a method for the treatment of at least one emulsion by applying at least one direct current (DC) field and at least one high frequency alternating current—HF/AC field wherein the at least one DC field, in particular a pulsed DC-field, and the at least one HF/AC field are applied in series to the emulsion to be treated. The present invention refers further to a device for conducting said methods.

First claim

The invention claimed is:

1. A method for the separation of at least one emulsion comprising:
introducing the at least one emulsion into a vessel; and
applying at least one direct current (DC) field and at least one alternating current (AC) field in series to the emulsion to be treated within the vessel, wherein the at least one alternating current (AC) field is applied with an electrical field strength between 2,000 and 100,000 V/m and a high frequency (HF) between 5,000 Hz and 200,000 Hz and the at least one DC field is applied with an electrical field strength between 500 and 20,000 V/m.

2. The method according to claim 1 , wherein the at least one DC field is a steady DC field or a pulsed DC field.

3. The method according to claim 1 , wherein the at least one DC field is applied with an electrical field strength between 1,000 and 10,000 V/m.

4. The method according to claim 1 , wherein the at least one DC field and the at least one AC field are applied to the at least one emulsion in the serial order of the DC field upstream of the AC field.

5. The method according to claim 1 , wherein the at least one DC field and the at least one AC field are applied to the at least one emulsion in the serial order of the AC field upstream of the DC field.

6. The method according to claim 1 , wherein at least one DC field and at least two AC fields are applied to the at least one emulsion in the serial order of the at least one first AC field upstream of the DC field and of the at least one second AC field downstream of the DC field.

7. The method according to claim 1 , wherein the field strength of the at least one AC field applied to the at least one emulsion is in the range between 4,000 and 70,000 V/m.

8. The method according to claim 1 , wherein the field strength of the at least one AC field applied to the at least one emulsion is in the range between 30,000 and 50,000 V/m.

9. The method according to claim 1 , wherein the frequency of the at least one AC field is between 5,000 and 150,000 Hz.

10. The method according to claim 2 , wherein a frequency of the at least one pulsed DC-field applied to the at least one emulsion is between 1 and 1,000 Hz.

11. The method according to claim 1 , wherein the separation of the at least one emulsion in a light and a heavy phase with a de-emulsification rate of at least 95% is achieved within less than 5 min.

12. The method according to claim 11 , wherein the separation of the at least one emulsion in a light and a heavy phase with a de-emulsification rate of at least 95% is achieved within less than 2 min.

13. The method according to claim 1 , wherein the at least one emulsion to be separated is at least one Water-in-Oil (W/O) emulsion or at least one multiple Oil-Water-Oil (O/W/O) emulsion with a water content of up to 70 Mass %.

14. The method according to claim 1 , wherein the emulsion to be separated is a phenolic water emulsion of the Hock-synthesis with an equimolar Phenol/Acetone-ratio and water contents up to 70 wt. %.

15. A method for the separation of at least one liquid/liquid (L/L) emulsion comprising:
introducing the at least one liquid/liquid (L/L) emulsion into a vessel, wherein the at least one liquid/liquid (L/L) emulsion comprises a water content up to 70 mass %; and
applying at least one direct current (DC) field and at least one alternating current (AC) field in series to the emulsion to be treated within the vessel, wherein the at least one alternating current (AC) field is applied with an electrical field strength between 2,000 and 100,000 V/m and a high frequency (HF) between 10,000 Hz and 200,000 Hz and the at least one DC field is applied with an electrical field strength between 500 and 20,000 V/m.

16. The method according to claim 15 , wherein the at least one direct current (DC) field and at least one alternating current (AC) field are applied in serial order of the DC field upstream of the HF/AC field to the at least one emulsion to be treated, and the at least one alternating current (AC) field is applied with an electrical field strength between 2,000 and 100,000 V/m and a high frequency (HF) between 10,000 Hz and 50,000 Hz.

Assignees

• Borealis Ag

Inventors

• Leitner Andreas
• Schadenböck Michael
• Muster Udo

Classifications

• B03C11/00

  Separation by high-voltage electrical fields, not provided for in other groups of this subclass · CPC title

• B01D17/06 Primary

  Separation of liquids from each other by electricity · CPC title

• B03C2201/02

  Electrostatic separation of liquids from liquids · CPC title

• C10G33/02

  with electrical or magnetic means · CPC title