Recovering deactivated metal/zeolite catalysts

Patent metadata

Field	Value
Publication number	US-11220944-B2
Application number	US-201616062266-A
Country	US
Kind code	B2
Filing date	Dec 27, 2016
Priority date	Dec 30, 2015
Publication date	Jan 11, 2022
Grant date	Jan 11, 2022

Abstract

A method of recovering selective catalytic reduction catalysts relates to metal-Zeolite based catalysts. A selective catalytic reduction catalyst service event where a metal-Zeolite based selective catalytic reduction catalyst of an exhaust aftertreatment system may perform below a threshold level of performance is determined. The selective catalytic reduction catalyst then exposed to a recovery fluid selected to facilitate movement of metal ions.

First claim

What is claimed is:

1. A method of recovering inactivated metal-Zeolite based selective catalytic reduction catalysts, comprising:
determining a selective catalytic reduction catalyst service event where a metal-Zeolite based selective catalytic reduction catalyst of an exhaust aftertreatment system may perform below a threshold level of performance; and
applying a recovery fluid comprising an acidic fluid to the metal-Zeolite based selective catalytic reduction catalyst so as to facilitate movement of metal ions.

2. The method of claim 1 , further comprising heating the metal-Zeolite based selective reduction catalyst.

3. The method of claim 2 , wherein heating the metal-Zeolite based selective reduction catalyst includes adding a fuel post-injection to combustion cycles of an associated internal combustion engine.

4. The method of claim 2 , wherein heating the metal-Zeolite based selective reduction catalyst includes structuring an exhaust gas recirculation system to recirculate exhaust gas from an associated exhaust system back to an associated internal combustion engine.

5. The method of claim 1 , wherein the recovery fluid includes SO x .

6. The method of claim 5 , wherein the SO x is in vapor form.

7. The method of claim 5 , wherein the recovery fluid further includes H 2 SO 4 .

8. A method of recovering inactivated metal-Zeolite based selective catalytic reduction catalysts, comprising:
determining a selective catalytic reduction catalyst service event where a metal-Zeolite based selective catalytic reduction catalyst of an exhaust aftertreatment system may perform below a threshold level of performance; and
exposing the metal-Zeolite based selective catalytic reduction catalyst to a recovery fluid selected to facilitate movement of metal ions, the recovery fluid comprising SO x ;
wherein exposing the metal-Zeolite based selective catalytic reduction catalyst to the recovery fluid includes adding high sulfur diesel fuel to a fuel reservoir of an associated vehicle, and operating an associated internal combustion engine after adding the high sulfur diesel fuel while the metal-Zeolite based selective catalytic reduction catalyst is coupled to the exhaust aftertreatment system.

9. The method of claim 5 , wherein exposing the metal-Zeolite based selective catalytic reduction catalyst to the recovery fluid includes a first exposure to SO x and a subsequent second exposure to a de-SO x .

10. The method of claim 1 , wherein the metal-Zeolite based selective catalytic reduction catalyst service event is determined as a service event due at a defined service interval.

11. The method of claim 1 , wherein the metal-Zeolite based selective catalytic reduction catalyst service event is determined by detecting that levels of regulated emissions coming from the aftertreatment system are above a threshold level.

12. The method of claim 1 , wherein the method is performed while the metal-Zeolite based selective catalytic reduction catalyst is positioned within the aftertreatment system of a vehicle.

13. The method of claim 1 , wherein the method is performed while the metal-Zeolite based selective catalytic reduction catalyst is removed from the aftertreatment system of a vehicle.

14. The method of claim 1 , wherein the recovery fluid comprises one of, or a combination of, acetic acid, oxalic acid, hydrochloric acid, citric acid, nitric acid, formic acid, or sulfuric acid.

15. An exhaust aftertreatment system comprising:
a selective catalytic reduction (SCR) component configured to recover inactivated metal- Zeolite based SCR catalysts by:
determining a SCR catalyst service event where a metal-Zeolite based SCR catalyst of an exhaust aftertreatment system may perform below a threshold level of performance; and
applying a recovery fluid comprising an acidic fluid to the metal-Zeolite based SCR catalyst so as to facilitate movement of metal ions.

16. The system of claim 15 , wherein the recovery fluid includes SO x .

17. An exhaust aftertreatment system comprising:
a selective catalytic reduction (SCR) component configured to recover inactivated metal-Zeolite based SCR catalysts by:
determining a SCR catalyst service event where a metal-Zeolite based SCR catalyst of an exhaust aftertreatment system may perform below a threshold level of performance; and
exposing the metal-Zeolite based SCR catalyst to a recovery fluid selected to facilitate movement of metal ions, the recovery fluid comprising SO x ;

wherein exposing the metal-Zeolite based SCR catalyst to the recovery fluid includes adding high sulfur diesel fuel to a fuel reservoir of an associated vehicle, and operating an associated internal combustion engine after adding the high sulfur diesel fuel while the metal-Zeolite based SCR catalyst is coupled to the exhaust aftertreatment system.

18. The system of claim 16 , wherein exposing the metal-Zeolite based SCR catalyst to the recover fluid includes a first exposure to SO x and a subsequent second exposure to a de-SO x .

19. The system of claim 15 , wherein the recovery fluid comprises at least one of, acetic acid, oxalic acid, hydrochloric acid, citric acid, nitric acid, formic acid, or sulfuric acid.

Assignees

• Cummins Inc

Inventors

• Luo Jinyong
• Kumar Ashok
• Kamasamudram Krishna
• Currier Neal W
• Yezerets Aleksey
• Tang Yadan
• Cunningham Michael J
• Wang Di

Classifications

• B01J29/90

  Regeneration or reactivation · CPC title

• F01N3/2066

  Selective catalytic reduction [SCR] · CPC title

• F01N3/2006

  Periodically heating or cooling catalytic reactors, e.g. at cold starting or overheating (by electrically controlling the supply of combustible mixture or its constituents only F02D41/0235) · CPC title

• F01N11/00

  Monitoring or diagnostic devices for exhaust-gas treatment apparatus · CPC title

• Y02T10/40

  Engine management systems · CPC title