Coating materials, and personal protective clothing items coated with the coating materials

Patent metadata

Field	Value
Publication number	US-11220781-B2
Application number	US-201716308324-A
Country	US
Kind code	B2
Filing date	Jun 7, 2017
Priority date	Jun 7, 2016
Publication date	Jan 11, 2022
Grant date	Jan 11, 2022

Abstract

Coating materials and coated personal protective clothing items incorporating the coating material are described. The coating material includes a polymeric component; a metal oxide component; and a catalytic component. The catalytic component includes a metal oxide or a mixed metal oxide which is an effective catalyst for an oxidation reaction. The coated personal protective clothing item includes a personal protective clothing substrate with a coating including the coating material.

First claim

The invention claimed is:

1. A catalytic oxidation coating material comprising:
a polymeric component to reduce adherence of polycyclic aromatic hydrocarbons to a substrate;
a metal oxide component comprising an amphiphilic compound; and
a catalytic component, the catalytic component comprising a metal oxide or a mixed metal oxide which is an effective catalyst for catalytic oxidation of the polycyclic aromatic hydrocarbons.

2. The coating material of claim 1 wherein the polymeric component comprises a fluorocarbon polymer.

3. The coating material of claim 1 wherein the metal oxide component comprises the amphiphilic compound with the following structural formula:

where M=metal oxide or binary metal oxide,
A 1 is selected from compounds with surface energy greater than or equal to 25 dynes per centimeter,
A 2 is selected from compounds with surface energy less than or equal to 12 dynes per centimeter,
A 3 is selected from compounds having more than one reactive functional group,
x=NH 2 , NHR′ or NR′ 2 (R′=methyl, ethyl, propyl or isopropyl),
y=COOH, SO 3 H or PO 3 H, and
R═H or halogen; and
where one of the A 1 -x, A 2 , or A 3 -y may be replaced by a second O—R;
or

where M=metal oxide or binary metal oxide,
A 1 is selected from compounds with surface energy greater than or equal to 25 dynes per centimeter,
A 2 is selected from compounds with surface energy greater than or equal to 7 dynes per centimeter,
x=NH 2 , NHR′ or NR′ 2 (R′=methyl, ethyl, propyl or isopropyl), and
R═H or halogen; and
where one of the A 1 -x, or A 2 may be replaced by a second O—R.

4. The coating material of claim 1 wherein the catalytic component comprises metal oxide nanoparticles.

5. The coating material of claim 1 wherein the metal oxide component, the catalytic component, and the polymeric component are separate layers on the substrate.

6. The coating material of claim 1 wherein the metal oxide component and the polymeric component are mixed together and applied to the substrate, and wherein the catalytic component is applied separately to the substrate.

7. The coating material of claim 1 wherein the coating material is used for a protective purpose, the polymeric component providing a first protective function and the catalytic component providing a second protective function.

8. The coating material of claim 1 wherein the catalytic component comprises cerium oxide nanoparticles having a particle size of 200 nm or less, and wherein the catalytic component is effective to oxidize the polycyclic aromatic hydrocarbon at a temperature below 100° C.

9. The coating material of claim 1 wherein the catalytic component comprises cerium oxide nanoparticles having a particle size of 200 nm or less, and wherein the catalytic component is effective to oxidize the polycyclic aromatic hydrocarbon without requiring the presence of a noble metal.

10. The coating material of claim 1 wherein the coating material comprises 25 mg/in 2 to 300 mg/in 2 of the polymeric component, 40 mg/in 2 to 200 mg/in 2 of the metal oxide component, and 1 mg/in 2 to 25 mg/in 2 of the catalytic component.

11. The coating material of claim 1 wherein the polymeric component comprises a fluorocarbon polymer including perfluoroalkyl chains having a surface energy greater than or equal to 7 dynes per centimeter, the catalytic component comprises cerium oxide, and wherein the metal oxide component comprises an amphiphilic compound with the following structural formula:

where M=metal oxide or binary metal oxide,
A 1 is selected from compounds with surface energy greater than or equal to 25 dynes per centimeter,
A 2 is selected from compounds with surface energy greater than or equal to 7 dynes per centimeter,
x=NH 2 , NHR′ or NR′ 2 (R′=methyl, ethyl, propyl or isopropyl), and
R═H or halogen; and
where one of the A 1 -x, or A 2 may be replaced by a second O—R.

12. A coating material comprising:
a polymeric component;
a metal oxide component comprising an amphiphilic compound; and
a catalytic component, the catalytic component comprising a metal oxide or a mixed metal oxide which is an effective catalyst for an oxidation reaction,
wherein the metal oxide component and the polymeric component are mixed together and applied to a substrate, and wherein the catalytic component is applied separately to the substrate.

13. A coating material comprising:
25 mg/in 2 to 300 mg/in 2 of a polymeric component;
40 mg/in 2 to 200 mg/in 2 of a metal oxide component comprising an amphiphilic compound; and
1 mg/in 2 to 25 mg/in 2 of a catalytic component, the catalytic component comprising a metal oxide or a mixed metal oxide which is an effective catalyst for an oxidation reaction.

14. The coating material of claim 1 wherein the catalytic component comprises the metal oxide or the mixed metal oxide of a metal selected from one or more of cerium, cesium, zirconium, chromium, molybdenum, tungsten, lanthanum, silver, vanadium, manganese, iron, cobalt, nickel, or copper.

15. The coating material of claim 1 wherein the polymeric component comprises a fluorocarbon polymer, a silicone polymer, or a polyacrylate polymer.

Assignees

• Battelle Memorial Institute

Inventors

• Lalgudi Ramanathan S
• Cain Robert J
• Shqau Krenar
• Edwards Erik W

Classifications

• D06M15/657

  containing fluorine · CPC title

• D06M23/08

  Processes in which the treating agent is applied in powder or granular form (adhesives for multi-layer textile fabrics D06M17/00) · CPC title

• A41D31/04

  characterised by special function or use (protective clothing affording protection against heat or harmful chemical agents or for use at high altitudes A62B17/00; composition of materials for coverings or clothing affording protection against harmful chemical agents A62D5/00) · CPC title

• C09D183/04

  Polysiloxanes · CPC title

• D06M11/36 Primary

  with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond · CPC title