Grease composition

Patent metadata

Field	Value
Publication number	US-11220650-B2
Application number	US-201816652599-A
Country	US
Kind code	B2
Filing date	Sep 28, 2018
Priority date	Oct 2, 2017
Publication date	Jan 11, 2022
Grant date	Jan 11, 2022

Abstract

A grease composition containing a base oil and a calcium complex soap as a thickening agent, wherein a C18-22 straight chain, substituted or unsubstituted higher fatty acid; a substituted or unsubstituted aromatic monocarboxylic acid having a benzene ring; a C2-4 straight-chain saturated lower fatty acid; and a substituted or unsubstituted saturated dicarboxylic acid are used as carboxylic acids constituting the calcium complex soap.

First claim

That which is claimed is:

1. A grease composition comprising:
(a) a base oil; and
(b) a calcium complex soap as a thickening agent, wherein the calcium complex soap comprises a carboxylic acid mixture comprising:
(i) a higher mono fatty acid comprising a substituted or unsubstituted C18-22 straight hydrocarbon chain;
(ii) an aromatic monocarboxylic acid comprising a substituted or unsubstituted aromatic monocarboxylic acid having a benzene ring;
(iii) a saturated lower mono fatty acid comprising an unsubstituted C2-4 straight hydrocarbon chain; and
(iv) a dicarboxylic acid comprising a substituted or unsubstituted saturated dicarboxylic acid,
wherein the mass ratio of the aromatic monocarboxylic acid to the dicarboxylic acid ranges from 5:95 to 70:30.

2. The grease composition according to claim 1 , wherein a calcium salt of the dicarboxylic acid accounts for 5 to 70% by weight of the calcium complex soap.

3. The grease composition according to claim 1 , wherein the substituted or unsubstituted saturated dicarboxylic acid has 4 to 20 carbon atoms.

4. The grease composition according to claim 1 , wherein the higher mono fatty acid is selected from the group consisting of stearic acid, tuberculostearic acid, arachidic acid, heneicosanoic acid, behenic acid, hydroxystearic acid, oleic acid, linoleic acid, gadoleic acid, eicosadienoic acid, mead acid, erucic acid, and docosadienoic acid.

5. The grease composition according to claim 1 , wherein the aromatic monocarboxylic acid is selected from the group consisting of benzoic acid, methyl benzoic acid, p-toluic acid, m-toluic acid, o-toluic acid, dimethyl benzoic acid, xylyl acid, hemellitic acid, mesitylenic acid, trimethyl benzoic acid, prehnitylic acid, durylic acid, isodurylic acid, 4-isopropylbenzoic acid, hydroxybenzoic acid, dihydroxybenzoic acid, pyrocatechuic acid, resorcylic acid, gentisic acid, protocatechuic acid, trihydroxybenzoic acid, hydroxy-methyl benzoic acid, cresotinic acid, dihydroxymethyl benzoic acid, methoxybenzoic acid, anisic acid, dimethoxybenzoic acid, trimethoxybenzoic acid, hydroxy-methoxy benzoic acid, and hydroxy-dimethoxy benzoic acid.

6. The grease composition according to claim 1 , wherein the saturated lower mono fatty acid is selected from the group consisting of acetic acid, propionic acid, and butyric acid.

7. The grease composition according to claim 1 , wherein the dicarboxylic acid is selected from the group consisting of oxalic acid, malonic acid, succinic acid, pentanedioic acid, 2-methylsuccinic acid, glutaric acid, hexanedioic acid, adipic acid, heptanedioic acid, octanedioic acid, nonanedioic acid, decanedioic acid, undecanedioic acid, dodecanedioic acid, tridecanedioic acid, tetradecanedioic acid, pentadecandioic acid, hexadecandioic acid, heptadecandioic acid, octadecanedioic acid, nonadecanedioic acid, and icosanedioic acid.

8. The grease composition according to claim 1 , wherein the mass ratio of the saturated lower mono fatty acid to the dicarboxylic acid ranges from 5:95 to 85:15.

9. The grease composition according to claim 1 , wherein the mass ratio of the higher mono fatty acid to the dicarboxylic acid ranges from 20:80 to 95:5.

Assignees

• Shell Oil Co

Inventors

• Watanabe Kazuya
• Tanaka Keiji
• Yano Hiroki

Classifications

• C10N2040/02

  Bearings · CPC title

• C10M117/00 Primary

  Lubricating compositions characterised by the thickener being a non-macromolecular carboxylic acid or salt thereof · CPC title

• C10N2030/08

  Resistance to extreme temperature · CPC title

• C10M2207/1216

  used as thickening agent · CPC title

• C10N2040/04

  Oil-bath; Gear-boxes; Automatic transmissions; Traction drives · CPC title