Fluorine-containing ether compound, lubricant for magnetic recording medium, and magnetic recording medium

Patent metadata

Field	Value
Publication number	US-11220649-B2
Application number	US-201716480464-A
Country	US
Kind code	B2
Filing date	Dec 4, 2017
Priority date	Jan 26, 2017
Publication date	Jan 11, 2022
Grant date	Jan 11, 2022

Abstract

A fluorine-containing ether compound represented by Formula (1) is provided;R1—R2—CH2—R3—CH2—R4—R5  (1)(In Formula (1), R1 and R5 may be the same as or different from each other and each represents an alkenyl group having 2 to 8 carbon atoms or an alkynyl group having 3 to 8 carbon atoms, R2 and R4 may be the same as or different from each other and each represents a divalent linking group having a polar group, and R3 represents a perfluoropolyether chain, with a proviso that R1 and R2 are, and R4 and R5 are divided due to the presence of an atom other than the carbon atom such as an oxygen atom).

First claim

The invention claimed is:

1. A fluorine-containing ether compound represented by Formula (1):
R 1 —R 2 —CH 2 —R 3 —CH 2 —R 4 —R 5   (1)

(in Formula (1), R 1 and R 5 may be the same as or different from each other and each represents an alkenyl group having 2 to 8 carbon atoms or an alkynyl group having 3 to 8 carbon atoms, R 2 and R 4 may be the same as or different from each other and each represents a divalent linking group having a polar group, and R 3 represents a perfluoropolyether chain, with a proviso that R 1 and R 2 are, and R 4 and R 5 are divided due to the presence of an atom other than the carbon atom such as an oxygen atom.).

2. The fluorine-containing ether compound according to claim 1 ,
wherein R 1 and R 5 each represents an alkenyl group having 2 to 5 carbon atoms or an alkynyl group having 3 to 5 carbon atoms.

3. The fluorine-containing ether compound according to claim 2 ,
wherein R 1 and R 5 each represents one selected from the group consisting of a vinyl group, an allyl group, a 3-butenyl group, a 4-pentenyl group, a propargyl group, a 3-butynyl group, and a 4-pentynyl group.

4. The fluorine-containing ether compound according to claim 1 ,
wherein the polar group included in R 2 and R 4 is a hydroxy group.

5. The fluorine-containing ether compound according to claim 1 ,
wherein R 2 and R 4 are represented by Formula (2-1) or (2-2)
—O—(CH 2 CH(OH)CH 2 O) a —  (2-1)

(in Formula (2-1), a represents 1 to 3)
—O—(CH 2 CH(OH)CH 2 O) a —CH 2 CH 2 O—  (2-2)

(in Formula (2-2), a represents 1 to 3).

6. The fluorine-containing ether compound according to claim 1 ,
wherein R 3 is represented by any one of Formulas (3) to (5)
—CF 2 —(OCF 2 CF 2 ) b —(OCF 2 ) c —OCF 2 —  (3)

(in Formula (3), b and c each represents 0 to 20, but b and c are not 0 simultaneously)
—CF(CF 3 )—(OCF(CF 3 )CF 2 ) d —OCF(CF 3 )—  (4)

(in Formula (4), d represents 1 to 20)
—CF 2 CF 2 —(OCF 2 CF 2 CF 2 ) e —OCF 2 CF 2 —  (5)

(in Formula (5), e represents 1 to 20).

7. The fluorine-containing ether compound according to claim 1 ,
wherein a number average molecular weight thereof is within a range of 500 to 10000.

8. The fluorine-containing ether compound according to claim 1 ,
wherein the fluorine-containing ether compound is any one of compounds represented by Formulas (A) to (0)

(in Formula (A), f and g each represents 0 to 7, and f and g are not 0 simultaneously)

(in Formula (B), h and i each represents 0 to 7, and h and i are not 0 simultaneously)

(in Formula (C), j and k each represents 0 to 7, and j and k are not 0 simultaneously)

(in Formula (D), m and n each represents 0 to 7, and m and n are not 0 simultaneously)

(in Formula (E), p and q each represents 0 to 7, and p and q are not 0 simultaneously)

(in Formula (F), r and s each represents 0 to 7, and r and s are not 0 simultaneously)

(in Formula (G), t and u each represents 0 to 7, and t and u are not 0 simultaneously)

(in Formula (H), v and w each represents 0 to 7, and v and w are not 0 simultaneously)

(in Formula (I), x and y each represents 0 to 7, and x and y are not 0 simultaneously)

(in Formula (J), z and aa each represents 0 to 7, and z and aa are not 0 simultaneously)

(in Formula (K), ab and ac each represents 0 to 7, and ab and ac are not 0 simultaneously)

(in Formula (L), ad and ae each represents 0 to 7, and ad and ae are not 0 simultaneously)

(in Formula (M), af and ag each represents 0 to 7, and af and ag are not 0 simultaneously)

(in Formula (N), ah and ai each represents 0 to 7, and ah and ai are not 0 simultaneously)

(in Formula (0), aj represents 1 to 7).

Assignees

• Showa Denko Kk

Inventors

• Fukumoto Naoya
• Yagyu Daisuke
• Yamaguchi Yuta
• UETAKE Shoko
• Kato Tsuyoshi
• Tomita Hiroyuki
• MIYASAKA Ryuuta
• Murofushi Katsumi

Classifications

• G11B5/7257 Primary

  Perfluoropolyether lubricant · CPC title

• C10M107/38

  containing halogen · CPC title

• C07C43/1786

  containing halogen · CPC title

• C10N2050/023

  Multi-layer lubricant coatings · CPC title

• C08G65/331

  containing oxygen {(cyclic ether compounds C08G65/26)} · CPC title