Fused anti-soiling and anti-reflective coatings

Patent metadata

Field	Value
Publication number	US-11220605-B2
Application number	US-201816203127-A
Country	US
Kind code	B2
Filing date	Nov 28, 2018
Priority date	Nov 28, 2018
Publication date	Jan 11, 2022
Grant date	Jan 11, 2022

Abstract

A method for applying a coating to a surface includes the step of providing a reaction mixture comprising a silicon alkoxide and an alcohol. A reaction limiting amount of water is added. The silicon alkoxides and water are allowed to react to form silica precursor particles during an initial reaction period. A coating precursor composition is prepared by adding an acid soluble in the alcohol to the reaction mixture during a second reaction period after the initial reaction period. The precursor silica particles grow to form silica nanofeatures having a major dimension that is larger than a major dimension of the silica precursor particles. The coating precursor composition is applied to a surface, and the alcohol and water are allowed to evaporate and the silica nanofeatures to adhere to the surface and form a nanostructured layer on the surface. A coating precursor composition and a coated article are also disclosed.

First claim

We claim:

1. A method for applying a coating to a surface, comprising the steps of:
providing a first reaction mixture comprising a silicon alkoxide and an alcohol, the silicon alkoxide being at least partially soluble in the alcohol;
adding no more than a reaction limiting amount of water to the silicon alkoxide and alcohol, the water being at least partially miscible with the alcohol, to create a second reaction mixture;
allowing the silicon alkoxide and water of the second reaction mixture to react to form silica precursor particles during an initial reaction period of from 1-30 minutes;
preparing a coating precursor composition by adding an acid soluble in the alcohol to the second reaction mixture during a second reaction period after the initial reaction period, whereby the silica precursor particles will grow to form silica nanofeatures having a major dimension that is larger than a major dimension of the silica precursor particles;
applying the coating precursor composition to a surface, and allowing the alcohol and water to evaporate and the silica nanofeatures to adhere to the surface and form a nanostructured layer on the surface.

2. The method of claim 1 , wherein the silicon alkoxide is at least one selected from the group consisting of tetraethyl orthosilicate (TEOS) and [or tetramethylorthosilicate (TMOS).

3. The method of claim 1 , wherein the alcohol is ethanol.

4. The method of claim 1 , wherein the acid is at least one selected from the group consisting of hydrochloric acid and sulfuric acid.

5. The method of claim 1 , wherein the nanofeatures comprise at least one selected from the group consisting of silica spheres and silica rods.

6. The method of client 1 , wherein after the step of applying the coating precursor composition to a surface, a heat treatment is applied to the coating precursor composition, the heat treatment having a temperature of 20° C. to 500° C.

7. The method of claim 1 , wherein the applying step is performed at ambient temperature and pressure.

8. The method of claim 1 , wherein the second reaction mixture comprises 1 silicon alkoxide, 2-10 alcohol, and 1-4 water, by molar ratios.

9. The method of claim 1 , wherein the acid is added to the second reaction mixture 15 min after the water is added to the silicon alkoxide and alcohol.

10. The method of claim 1 , wherein after the acid is added, waiting at least 15 min and then cooling the mixture to room temperature.

11. The method of claim 1 , wherein the second reaction period is from 1-30 min.

12. The method of claim 1 , wherein the coating is applied at a thickness of between 0.01-1 μm.

13. The method of claim 1 , wherein the nanofeatures have a diameter of 10-500 nm.

14. The method of claim 1 , wherein the nanofeatures have a width of 200 nm-1500 nm.

15. The method of claim 1 , wherein the nanofeatures have a height of 10-100 nm.

16. The method of claim 1 , wherein the nanofeatures have a spacing of 1-500 nm.

17. The method of claim 1 , further comprising the step of applying a hydrophobic composition to the nanostructured layer.

18. The method of claim 1 , wherein the silicon alkoxide/alcohol molar ratio is 1 silicon alkoxide to 2-6 alcohol to obtain silica spheres.

19. The method of claim 1 , wherein the silicon alkoxide/alcohol molar ratio is 1 silicon alkoxide to 7-10 alcohol to obtain silica rods.

20. The method of claim 1 , wherein the silicon alkoxide/alcohol molar ratio is from 1:4 to 1:8.

21. The method of claim 1 , wherein the silicon alkoxide/alcohol molar ratio is 1:8.

Assignees

• Ut Battelle Llc

Inventors

• Lee Dominic F
• Park Jaehyeung
• Sharma Jaswinder
• Polyzos Georgios

Classifications

• C03C17/25

  by deposition from the liquid phase · CPC title

• C03C2218/32

  After-treatment · CPC title

• C03C2218/113

  by sol-gel processes · CPC title

• C03C2217/90

  Other aspects of coatings · CPC title

• C03C2217/77

  Coatings having a rough surface · CPC title