Method and system for polymerizing acrylates

Patent metadata

Field	Value
Publication number	US-11220557-B2
Application number	US-201716330208-A
Country	US
Kind code	B2
Filing date	Sep 5, 2017
Priority date	Sep 6, 2016
Publication date	Jan 11, 2022
Grant date	Jan 11, 2022

Abstract

The invention relates to a method for polymerizing acrylates using a reactor (50). Reaction heat produced in the reactor (50) is discharged via a boiling cooler (40) in that gaseous vapors produced in the reactor (50) are supplied to the boiling cooler (40), and condensed vapors are returned to the reactor (50) from the boiling cooler (40). At least one component containing acrylate is at least partly added via the boiling cooler (40) and reaches the reactor (50) via the boiling cooler (40). The invention additionally relates to a system for polymerizing an acrylate, comprising a reactor (50) and a boiling cooler (40) for discharging reaction heat produced in the reactor (50). The boiling cooler (40) has at least one filling opening (46) for supplying at least one component containing acrylate.

First claim

The invention claimed is:

1. A process for polymerizing acrylates by a reactor, where
heat of reaction arising in the reactor is removed by an evaporative cooler by feeding gaseous vapor formed in the reactor to the evaporative cooler and recirculating condensed vapor from the evaporative cooler to the reactor,
wherein at least one component containing acrylate is introduced at least partly via the evaporative cooler and goes via the evaporative cooler into the reactor,
wherein a reduced pressure is generated in the reactor,
wherein a reduced pressure compared to atmospheric pressure prevails in the reactor during the polymerization of the acrylate.

2. The process of claim 1 , wherein the at least one component contains butyl acrylate.

3. The process of claim 1 , wherein a further component containing a monomer having two double bonds is at least partly introduced into the evaporative cooler.

4. The process of claim 1 , wherein the at least one component is at least partly introduced from above through a cap of the evaporative cooler.

5. The process of claim 1 , wherein the at least one component is at least partly introduced from above into a plurality of vertical tubes of the evaporative cooler.

6. The process of claim 1 , wherein the reactor is evacuated through the evaporative cooler by a vacuum pump via a subatmospheric pressure conduit.

7. The process of claim 1 , wherein the polymerization of the acrylate is carried out as discontinuous process in the reactor.

8. The process of claim 1 , wherein water is introduced into the evaporative cooler.

9. The process as claimed in claim 8 , wherein the water is introduced at the same time as the at least one component.

10. The process of claim 8 , wherein the water is introduced at a time after the at least one component.

11. The process of claim 1 , wherein the at least one component is partly introduced directly into the reactor.

12. The process of claim 1 , wherein a reduced pressure in the range from 150 mbar to 350 mbar is generated in the reactor.

13. A system for polymerizing acrylates, comprising
a reactor, and
an evaporative cooler for removing heat of reaction arising in the reactor,
wherein the evaporative cooler has at least one feed opening for introducing at least one component containing acrylate,
wherein the reactor can be evacuated through the evaporative cooler by a vacuum pump in order to generate a required subatmospheric pressure in the range from 150 mbar to 350 mbar in the reactor, where a subatmospheric pressure conduit is connected to the vacuum pump and is joined to a three-way valve and the three-way valve is connected by a suction conduit to a cap of the evaporative cooler and by a bypass conduit to a lower region of the evaporative cooler, which region is arranged opposite the cap and adjacent to the reactor.

14. The system of claim 13 , wherein the at least one feed opening is arranged in a cap of the evaporative cooler.

15. The system of claim 14 , wherein nozzles are arranged in the cap in such a way that the component introduced through the at least one feed opening is distributed from above over vertical tubes of the evaporative cooler.

16. The system of claim 13 , wherein the reactor and the evaporative cooler are arranged in such a way that vapor formed in the reactor ascends against the force of gravity into the evaporative cooler and that vapor condensed in the evaporative cooler flows together with the at least one component under the force of gravity into the reactor.

Assignees

• Ineos Styrolution Group Gmbh

Inventors

• Fischer Wolfgang
• Ittemann Peter
• Patcas Florian
• Ruf Michael

Classifications

• C08F2/01 Primary

  characterised by special features of the polymerisation apparatus used · CPC title

• B01J19/18

  Stationary reactors having moving elements inside (B01J19/08, B01J19/26 take precedence) · CPC title

• B01J19/0013 Primary

  Controlling the temperature of the process · CPC title

• C08F279/04

  Vinyl aromatic monomers and nitriles as the only monomers · CPC title

• C08F265/06

  Polymerisation of acrylate or methacrylate esters on to polymers thereof · CPC title