Method of making ceramic matrix slurry infused ceramic tows and ceramic matrix composites

Patent metadata

Field	Value
Publication number	US-11220462-B2
Application number	US-201916963874-A
Country	US
Kind code	B2
Filing date	Jan 21, 2019
Priority date	Jan 22, 2018
Publication date	Jan 11, 2022
Grant date	Jan 11, 2022

Abstract

Methods of making ceramic matrix prepregs are described. The methods include exposing a coated tow of ceramic fibers to a ceramic matrix slurry comprising a solvent and ceramic precursor. The coating is at least partially removed and the slurry infuses into the ceramic fibers to form prepreg. Steps to form ceramic matrix composites are also described, including forming the prepreg into a green body, and sintering the ceramic precursor.

First claim

What is claimed is:

1. A method of making a ceramic prepreg comprising:
a) exposing at least one coated tow to a ceramic matrix slurry comprising a solvent and a ceramic precursor, wherein the coated tow comprises a bundle of ceramic fibers surrounded by at least 0.2 weight percent of a coating based on the total weight of the coated tow; and
b) infusing the slurry into the bundle of ceramic fibers to form the ceramic prepreg; wherein at least 80 percent by weight of the coating is soluble in the solvent at 25° C.;
wherein during or subsequent to step (b), at least 50 wt. % of the coating is dissolved from the surface of the coated tow into the slurry.

2. A method of making a ceramic matrix composite comprising:
c) forming the ceramic prepreg of claim 1 into a green body; and
d) exposing the green body to a temperature sufficient to sinter the ceramic precursor to form the ceramic matrix composite, wherein at least 50 wt. % of the coating is dissolved from the surface of the coated tow into the slurry prior to step (d).

3. The method of claim 2 , wherein the temperature is at least 1000° C.

4. The method of claim 2 , wherein forming the ceramic prepreg into the green body comprises using filament winding to place the ceramic prepreg to form the green body.

5. The method of claim 2 , wherein forming the ceramic prepreg into the green body comprises using advanced fiber placement to place the ceramic prepreg to form the green body.

6. The method of claim 5 , wherein the tow is a spread tow.

7. The method of claim 6 , wherein the ceramic fibers comprise oxide ceramic fibers.

8. The method of claim 7 , wherein the solvent comprises water.

9. The method of claim 2 , wherein the tow is a spread tow.

10. The method of claim 1 , wherein the tow is a spread tow.

11. The method of claim 1 , wherein the ceramic fibers comprise oxide ceramic fibers.

12. The method of claim 1 , wherein the solvent comprises water.

13. The method of claim 1 , wherein the coated tow comprises no greater than 3 weight percent of the coating based on the total weight of the coated tow.

14. The method of claim 1 , wherein at least 95 percent by weight of the coating is soluble in the solvent at 25° C.

15. The method of claim 1 , wherein during or subsequent to step (b), at least 80 wt. % of the coating is dissolved from the surface of the coated tow into the slurry.

16. The method of claim 1 , wherein step (a) comprises exposing a plurality of coated tows to the ceramic matrix slurry.

17. The method of claim 16 , wherein the coated tows are braided.

18. The method of claim 16 , wherein the coated tows are woven to form a fabric.

19. The method of claim 16 , wherein at least a portion of the plurality of the coated tows are spread tows.

Assignees

• 3M Innovative Properties Co

Inventors

• Beaber Aaron R
• Simpson Marc G
• Mcgee Kari Ann
• Barnes Amy S
• Parkar Zeba

Classifications

• C04B35/185

  Mullite {3Al2O3-2SiO2} · CPC title

• C04B35/117 Primary

  Composites · CPC title

• C04B35/62813

  Alumina or aluminates · CPC title

• C04B35/63408

  Polyalkenes · CPC title

• C04B35/10

  based on aluminium oxide · CPC title