Method for promoting densification of metal body by utilizing metal expansion induced by hydrogen absorption

Patent metadata

Field	Value
Publication number	US-11219949-B2
Application number	US-201916979871-A
Country	US
Kind code	B2
Filing date	Mar 15, 2019
Priority date	Apr 25, 2018
Publication date	Jan 11, 2022
Grant date	Jan 11, 2022

Abstract

Provided is a method for promoting densification of a metal body by utilizing metal expansion induced by hydrogen absorption. The hydrogen absorption expansion refers to a volume expansion effect produced by absorbing hydrogen on some metal blocks or metal powder in a hydrogen atmosphere under certain temperature conditions. Hydrogen is introduced into a rigid closed mold filled with a hydrogen absorption expansion material or filled with the hydrogen absorption expansion material and a material to be densified, and the mold and/or the material to be densified are/is densified by using the volume expansion effect of the hydrogen absorption expansion material. The present method may be used for eliminating residual pores from a metal material so as to improve the properties of the material.

First claim

What is claimed is:

1. A method for promoting densification of a metal body by utilizing metal expansion induced by hydrogen absorption, wherein hydrogen is introduced into a rigid closed mold filled with a hydrogen absorption expansion material or filled with the hydrogen absorption expansion material and a metal material to be densified, and a volume expansion effect of the hydrogen absorption expansion material is used to densify the hydrogen absorption expansion material and/or the metal material to be densified; wherein the method comprises the following steps: step 1: putting a first pre-densified metal body into the rigid closed mold, performing encapsulation and fastening, and reserving a gas opening to obtain a pretreatment assembly, wherein the first pre-densified metal body comprises a metal material with hydrogen absorption capability; in the pretreatment assembly, an outer wall of the first pre-densified metal body is in contact with an inner wall of the rigid closed mold, or a gap exists between the outer wall of the first pre-densified metal body and the inner wall of the rigid closed mold; and the gap is smaller than a linear expansion after the first pre-densified metal body absorbs hydrogen,
or charging a second pre-densified metal body and a hydrogen absorbable metal powder into the rigid closed mold together, performing encapsulation and fastening, and reserving the gas opening to obtain the pretreatment assembly,
or putting the metal material to be densified onto a set position of a mold inner cavity, putting the hydrogen absorbable metal powder onto other positions of the mold inner cavity, performing encapsulation and fastening, and reserving the gas opening to obtain the pretreatment assembly; step 2: putting the pretreatment assembly obtained in the step 1 into a sintering furnace, introducing hydrogen, raising a temperature to a hydrogen absorption temperature, and performing heat soaking to obtain a hydrogenated assembly: then, regulating an atmosphere into an inert atmosphere or a vacuum atmosphere and/or performing heat soaking at a dehydrogenation temperature so that the hydrogenated assembly releases hydrogen to obtain a dehydrogenated assembly; and step 3: after the dehydrogenated assembly is cooled, removing the rigid closed mold to obtain a densified metal body.

2. The method for promoting densification of the metal body according to claim 1 , wherein the hydrogen absorption expansion material comprises a metal with hydrogen absorption capability.

3. The method for promoting densification of the metal body according to claim 1 , wherein throughout step 2, the rigid closed mold keeps the pretreatment assembly tight and firm without loosening.

4. The method for promoting densification of the metal body according to claim 1 , wherein after complete hydrogen absorption by the metal material with hydrogen absorption capability or the hydrogen absorbable metal powder, a volume of the first pre-densified metal body or the hydrogen absorbable metal powder realizes at least more than 5 vol % expansion compared with a volume of the first pre-densified metal body or the hydrogen absorbable metal powder before the hydrogen absorption.

5. The method for promoting densification of the metal body according to claim 1 , wherein a material of the rigid closed mold does not react with hydrogen.

6. The method for promoting densification of the metal body according to claim 1 , wherein the metal material with hydrogen absorption capability or the hydrogen absorbable metal powder absorbs hydrogen at the hydrogen absorption temperature under a condition that a hydrogen partial pressure is greater than or equal to a hydrogen equilibrium partial pressure of the metal material with hydrogen absorption capability or the hydrogen absorbable metal powder, the hydrogen absorption temperature is determined by physicochemical properties of the metal material with hydrogen absorption capability and/or the hydrogen absorbable metal powder.

7. The method for promoting densification of the metal body according to claim 1 , wherein
the metal material with hydrogen absorption capability and/or the hydrogen absorbable metal powder comprise/comprises at least one element of Ti, Mg, Zr, V, Nb, Ta, Pd and rare earth elements.

8. The method for promoting densification of the metal body according to claim 1 , wherein step 2 is repeated until a product with a set density is obtained.

9. The method for promoting densification of the metal body according to claim 1 , wherein the steps 1, 2 and 3 are sequentially repeated until a product with a set density is obtained.

Assignees

• Univ Central South

Inventors

• Zhou Chengshang
• Liu Yong
• Sun Pei
• Liu Bin

Classifications

• B33Y10/00

  Processes of additive manufacturing · CPC title

• B22F3/156 Primary

  by a pressure medium in liquid or powder form · CPC title

• B22F2998/10

  Processes characterised by the sequence of their steps · CPC title

• Y02P10/25

  Process efficiency · CPC title

• B22F2999/00

  Aspects linked to processes or compositions used in powder metallurgy · CPC title