Superhydrophobic and dust mitigating coatings

Patent metadata

Field	Value
Publication number	US-11219922-B1
Application number	US-201916566127-A
Country	US
Kind code	B1
Filing date	Sep 10, 2019
Priority date	Sep 30, 2014
Publication date	Jan 11, 2022
Grant date	Jan 11, 2022

Abstract

A method is provided to form a dust mitigation coating that also mitigates or repels water, ice, and other liquids. Techniques to coat the surfaces of equipment and items with these dust, liquid, and ice mitigation coatings, minimize or eliminate mission problems caused by dust, liquid, or ice accumulation, particularly in outer space or on another planetary body or moon. Further, the dust mitigation coatings exhibit a Lotus-like effect, making the coated surfaces ultra-hydrophobic. The present invention is also directed to techniques for improving the functioning of terrestrial-based equipment and systems where dust, liquid, or ice accumulation is a problem, such as in hospitals and other health contexts, to prevent contamination.

First claim

What is claimed is:

1. A method of applying a hydrophobic dust mitigating transparent coating to a substrate; said method comprising the steps of:
making a nano-texture epoxy basecoat composition by mixing 0.55 g to 0.75 g of silica nanoparticles, an epoxy resin, an epoxy hardener, and a solvent, the silica nanoparticles comprising a ratio by mass of small particles to large particles, of from 6:1 to 10:1, the small particles having a maximum dimension particle size range of from 10 nm to 30 nm and the large particles having a maximum dimension particle size range of from 70 nm to 90 nm;
cleaning a substrate and thereafter rinsing said substrate with a solvent;
applying said epoxy basecoat composition to said substrate by rubbing the epoxy basecoat composition onto a surface of the substrate and allowing said epoxy basecoat composition to flash off and form a first basecoat;
thinning out the first basecoat to form a transparent basecoat;
baking said substrate with said transparent basecoat thereon at a temperature of from 75° C. to 125° C. for a period of time of from 15 minutes to 45 minutes to form a cured and set basecoat;
applying a self-assembling, monolayer to said cured and set basecoat by submerging the substrate with the cured and set basecoat in a self-assembling monolayer solution comprising ethanol and 1H,1H,2H,2H-perfluorooctyltriethoxysilane, 1H,1H,2H,2H-perfluorodecyltrimethoxysilane, 1H,1H,2H,2H-perfluorodecyltriethoxysilane, or a combination thereof, for 12 to 20 hours to form a self-assembling monolayer on the cured and set basecoat;
removing said substrate having the cured and set basecoat and the self-assembling monolayer thereon, from said solution;
rinsing said self-assembling monolayer with ethanol;
drying to obtain a dried coated assembly; and
then baking the dried coated assembly at a temperature of from 75° C. to 125° C. for a period of time of from 15 minutes to 45 minutes such that the self-assembling monolayer aligns and forms a self-assembled monolayer.

2. The method of claim 1 , further comprising:
coating, in a vacuum deposition chamber, said self-assembled monolayer with 75 nm to 125 nm of a fluorinated ethylene propylene under a pressure of 1×10-5 Torr to 9×10-5 Torr at a deposition rate of from 15 to 25 μg/cm2, whereby
said method produces a transparent coating exhibiting hydrophobicity such that contacting water forms droplets having contact angles averaging at least 90°.

3. The method according to claim 1 , wherein the self-assembling monolayer solution comprises 1H,1H,2H,2H-perfluorooctyltriethoxysilane.

4. The method according to claim 1 , wherein the small silica nanoparticles consist of silica nanoparticles having a maximum dimension of about 15 nm and the large silica nanoparticles consist of silica nanoparticles having a maximum dimension of about 80 nm.

5. The method according to claim 1 , wherein the applying said epoxy basecoat composition and the thinning out comprise using lint-free, nonwoven cotton wipes.

6. The method according to claim 1 , wherein the self-assembling monolayer solution comprises a combination of at least two of 1H,1H,2H,2H-perfluorooctyltriethoxysilane, 1H,1H,2H,2H-perfluorodecyltrimethoxysilane, and 1H,1H,2H,2H-perfluorodecyltriethoxysilane.

7. A method of applying a hydrophobic dust mitigating transparent coating to a substrate; said method comprising the steps of:
making a nano-texture epoxy basecoat composition by mixing 0.1 to 0.5 g of silica nanoparticles, an epoxy resin, an epoxy hardener, and a solvent, the silica nanoparticles comprising a ratio by mass of small particles to large particles, of from 6:1 to 10:1, the small particles having a maximum dimension particle size range of from 10 nm to 30 nm and the large particles having a maximum dimension particle size range of from 70 nm to 90 nm;
applying said epoxy basecoat composition to said substrate by rubbing the epoxy basecoat composition onto a surface of the substrate and allowing said epoxy basecoat composition to flash off and form a first basecoat;
thinning out the first basecoat to form a transparent basecoat;
baking said substrate with said transparent basecoat thereon at a temperature of from 75° C. to 125° C. for a period of time from 15 minutes to 45 minutes to form a cured and set basecoat;
applying a self-assembling monolayer to said cured and set basecoat by submerging the substrate with the cured and set basecoat in a self-assembling monolayer solution comprising n-decane and perfluorodecyltrichlorosilane, 1H,1H,2H,2H-perfluorooctyltrichlorosilane, or a combination thereof, for a period of time from 15 minutes to 45 minutes to form a self-assembling monolayer on the cured and set basecoat;
removing said substrate having the cured and set basecoat and self-assembling monolayer thereon, from said solution;
rinsing said self-assembling monolayer with a first solvent having a first polarity and then with a second solvent having a second polarity that is greater than the first polarity, to remove unreacted perfluorodecyltrichlorosilane, unreacted 1H,1H,2H,2H-perfluorooctyltrichlorosilane, or both, to form a coated substrate; and then
baking the coated substrate at a temperature of from 75° C. to 125° C. for a period of time from 15 minutes to 45 minutes such that the self-assembling monolayer aligns and forms a self-assembled monolayer, whereby
said method produces a transparent coating exhibiting hydrophobicity such that contacting water forms droplets having contact angles averaging greater than 90°.

8. The method according to claim 7 , wherein the self-assembling monolayer solution comprises perfluorodecyltrichlorosilane.

9. The method according to claim 7 , wherein the self-assembling monolayer solution comprises 1H,1H,2H,2H-perfluorooctyltrichlorosilane.

10. The method according to claim 7 , wherein the small silica nanoparticles consist of silica nanoparticles having a maximum dimension of about 15 nm and the large silica nanoparticles consist of silica nanoparticles having a maximum dimension of about 80 nm.

11. The method according to claim 7 , wherein said method produces a transparent coating exhibiting hydrophobicity such that contacting water forms droplets having contact angles averaging at least 118°.

12. The method according to claim 7 , wherein the self-assembling monolayer solution consists essentially of 1H,1H,2H,2H-perfluorooctyltrichlorosilane.

13. The method according to claim 7 , wherein the self-assembling monolayer solution consists essentially of perfluorodecyltrichlorosilane and 1H,1H,2H,2H-perfluorooctyltrichlorosilane.

14. A method of applying a hydrophobic dust mitigating transparent coating to a substrate, said method comprising the steps of:
making a nano-texture epoxy basecoat composition by mixing 0.1 to 0.5 g of silica nanoparticles, an epoxy resin, an epoxy hardener, and a solvent, the silica nanoparticles comprising a ratio by mass of small particles to large particles, of from 6:1 to 10:1, the small particles having a maximum dimension particle size range of from 10 nm to 30 nm and the large particles having a maximum dimension particle size range of from 70 nm to 90 nm;
applying said epoxy basecoat composition to said substrate surface by rubbing the epoxy basecoat composition, using a lint-free nonwoven cotton wipe, onto the surface of the substrate and allowing said epoxy basecoat composition to flash off and turn matte in appearance;
thereafter using a second lint-free nonwoven cotton wipe to thin out the epoxy basecoat composition and form a transparent basecoat; and
baking said substrate with said transparent basecoat at a temperature of

Assignees

• Nasa

Inventors

• Straka Sharon
• O'Connor Kenneth
• Hasegawa Mark
• Chen Boxi
• Hawthorne Nathaniel Patrick
• Stotzer Victoria Jane Pederzani

Classifications

• C03C2218/31

  Pre-treatment · CPC title

• C03C2218/118

  by roller-coating · CPC title

• C03C2218/116

  by spin-coating, centrifugation · CPC title

• C03C23/006

  by plasma or corona discharge · CPC title

• C03C2218/112

  by spraying · CPC title