Method for fabricating an electrochemical device and electrochemical device

Patent metadata

Field	Value
Publication number	US-11217823-B2
Application number	US-201716334483-A
Country	US
Kind code	B2
Filing date	Sep 18, 2017
Priority date	Sep 19, 2016
Publication date	Jan 4, 2022
Grant date	Jan 4, 2022

Abstract

The method for fabricating an electrochemical device includes the following successive steps: a first stack successively including a first electrode and an electrically insulating electrolyte having a first main surface in contact with the first electrode and an opposite second main surface; a polymerisation step of the electrolyte so as to define at least a first area presenting a first degree of cross-linking and a first cross-linking density and a second area presenting a second degree of cross-linking different from the first degree of cross-linking and/or a second cross-linking density different from the first cross-linking density, said at least first and second areas connecting the first main surface with the second main surface; and placing the second electrode in contact with the electrolyte.

First claim

The invention claimed is:

1. Method for fabricating an electrochemical device comprising the following steps:
providing a first electrode,
providing a second electrode,
providing an electrolyte in contact with the first electrode, the electrolyte being electronically insulating and ionically conducting, and containing a polymer formed from a mixture containing monomers, pre-polymers thereof, or monomers and pre-polymers thereof, the electrolyte presenting an initial degree of cross-linking of the polymer and an initial cross-linking density of the polymer,
cross-linking the electrolyte so as to define at least one polymerisation area comprising a first polymerisation area presenting a first degree of cross-linking of the polymer and a first cross-linking density of the polymer and a second polymerisation area presenting a second degree of cross-linking of the polymer different from the first degree of cross-linking of the polymer or a second cross-linking density of the polymer different from the first cross-linking density of the polymer, the first and second degrees of cross-linking of the polymer being higher than the initial degree of cross-linking of the polymer and the first and second cross-linking densities of the polymer being higher than the initial cross-linking density of the polymer.

2. Method for fabricating the electrochemical device according to claim 1 , wherein cross-linking the electrolyte defines an alternation of first polymerisation areas and second polymerisation areas in a direction parallel to a first main surface of the electrolyte, the main surface being in contact with the electrolyte.

3. Method for fabricating the electrochemical device according to claim 1 , wherein at least one electromagnetic radiation is applied on the electrolyte to polymerise the electrolyte.

4. Method for fabricating the electrochemical device according to claim 3 , wherein the at least one electromagnetic radiation is provided by an electromagnetic radiation source configured to emit a first electromagnetic radiation power to form the first polymerisation area and the second polymerisation area.

5. Method for fabricating the electrochemical device according to claim 3 , wherein the at least one electromagnetic radiation is provided by an electromagnetic radiation source configured to simultaneously emit a first electromagnetic radiation power defining the first polymerisation area and a second electromagnetic radiation power different from the first power defining the second polymerisation area.

6. Method for fabricating the electrochemical device according to claim 3 , comprising applying the at least one electromagnetic radiation through a mask, the mask defining at least two regions presenting different transmission rates at said at least one electromagnetic radiation to form said at least first and second polymerisation areas.

7. Method for fabricating the electrochemical device according to claim 6 , wherein the at least two regions of the mask are configured to allow said at least one electromagnetic radiation to pass.

8. Method for fabricating the electrochemical device according to claim 4 , comprising applying the at least one electromagnetic radiation in a single step to form said at least first and second polymerisation areas.

9. Method for fabricating the electrochemical device according to claim 4 , wherein applying the at least one electromagnetic radiation is performed with a same exposure time to form said at least first and second polymerisation areas.

10. Method for fabricating the electrochemical device according to claim 4 , wherein applying the at least one electromagnetic radiation is performed with a first exposure time to form the first polymerisation area and with a second exposure time different from the first exposure time to form the second polymerisation area.

11. Method for fabricating the electrochemical device according to claim 1 , wherein, before cross-linking the electrolyte, the electrolyte is in liquid form and cross-linking the electrolyte is configured to form at least one of the first and second polymerisation areas in solid or gel form and to keep the other of the first and second polymerisation areas in liquid form.

12. Method for fabricating the electrochemical device according to claim 1 , wherein, before cross-linking the electrolyte, the electrolyte is in liquid form and cross-linking the electrolyte is configured to form the first polymerisation area in solid or gel form and the second polymerisation area in solid or gel form.

13. Method for fabricating the electrochemical device according to claim 1 , wherein the electrochemical device is a battery or an electrochrome device, wherein
the first electrode comprises:
a first support substrate,
a first current collector covering the first support substrate,
a first electrochemically active layer in electric contact with the first current collector,
the electrolyte is in contact with the first electrochemically active layer and the second electrode comprises:
a second electrochemically active layer separated from the first electrochemically active layer by the electrolyte,
a second current collector in contact with the second electrochemically active layer, the second current collector being separated from the first current collector by the electrolyte,
a second support substrate.

14. Method for fabricating the electrochemical device according to claim 1 , wherein cross-linking the electrolyte is performed with ultraviolet radiation.

15. Method for fabricating the electrochemical device according to claim 1 , wherein the second electrode is in contact with the electrolyte before cross-linking the electrolyte.

16. Method for fabricating the electrochemical device according to claim 1 , wherein the second electrode is placed in contact with the electrolyte after cross-linking the electrolyte.

17. Electrochemical device comprising a first electrode and a second electrode separated by an electrically insulating electrolyte in solid form,
wherein the electrolyte comprises a first polymerisation area presenting a first degree of cross-linking of a polymer and a first cross-linking density of the polymer and a second polymerisation area presenting a second degree of cross-linking of the polymer different from the first degree of cross-linking of the polymer or a second cross-linking density of the polymer different from the first cross-linking density of the polymer, the polymer of the first polymerisation area and the polymer of the second polymerisation area each being derived from the same initial polymer reactant, said first polymerisation area connecting the first electrode with the second electrode and said second polymerisation area connecting the first electrode with the second electrode.

Assignees

• Commissariat Energie Atomique

Inventors

• Bazin Arnaud
• Oukassi Sami

Classifications

• H10F99/00

  Subject matter not provided for in other groups of this subclass · CPC title

• H01M6/22

  Immobilising of electrolyte · CPC title

• H01M10/054

  Accumulators with insertion or intercalation of metals other than lithium, e.g. with magnesium or aluminium · CPC title

• H01M6/40

  Printed batteries {, e.g. thin film batteries} · CPC title

• H01M10/052

  Li-accumulators · CPC title