Methods and compositions for increased thermoelectric oxide ceramic performance
US-2024132412-A1 · Apr 25, 2024 · US
US11217738B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-11217738-B2 |
| Application number | US-201916555449-A |
| Country | US |
| Kind code | B2 |
| Filing date | Aug 29, 2019 |
| Priority date | Aug 31, 2018 |
| Publication date | Jan 4, 2022 |
| Grant date | Jan 4, 2022 |
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Various methods and devices for ultrasensitive infrared photodetection, infrared imaging, and other optoelectronic applications using the plasmon assisted thermoelectric effect in graphene are described. Infrared detection by the photo-thermoelectric uses the generation of a temperature gradient (ΔT) for the efficient collection of the generated hot-carriers. An asymmetric plasmon-induced hot-carrier Seebeck photodetection scheme at room temperature exhibits a remarkable responsivity along with an ultrafast response in the technologically relevant 8-12 μm band. This is achieved by engineering the asymmetric electronic environment of the generated hot carriers on chemical vapor deposition (CVD) grown large area nanopatterned monolayer graphene, which leads to a record ΔT across the device terminals thereby enhancing the photo-thermoelectric voltage beyond the theoretical limit for graphene. The results provide a strategy for uncooled, tunable, multispectral infrared detection.
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What is claimed is: 1. A method, comprising: providing an infrared detector, the infrared detector having an asymmetrically patterned graphene layer, wherein the infrared detector comprises a dielectric slab sandwiched between the asymmetrically patterned graphene layer and a back reflector; receiving infrared radiation illumination at the infrared detector; detecting a thermoelectric voltage generated by the received infrared radiation illumination; and in response to detecting the thermoelectric voltage, indicating reception of infrared radiation illumination. 2. The method of claim 1 , wherein the infrared detector is an uncooled infrared detector. 3. The method of claim 1 , wherein infrared radiation illumination is within the 3 μm-5 μm band. 4. The method of claim 1 , wherein infrared radiation illumination is within the 8 μm-12 μm band. 5. The method of claim 1 , wherein the asymmetrically patterned graphene layer is nanopatterned. 6. The method of claim 1 , wherein the asymmetrically patterned graphene layer comprises a first patterned graphene section and a second graphene section, the second graphene section having no pattern. 7. The method of claim 6 , wherein the first graphene section and the second, patterned graphene section extend in parallel along the length of a graphene channel. 8. The method of claim 1 , wherein the asymmetrically patterned graphene layer comprises a pattern of holes in a hexagonal array. 9. A device, comprising: an infrared detector with an asymmetrically patterned graphene layer configured to generate a thermoelectric voltage in response to a received infrared radiation illumination, the infrared detector having a source, drain and gate; a function generator connected to the source; a lock-in amplifier connected to the drain; and a gate voltage connected to the gate. 10. The device of claim 9 , wherein a first connection of the lock-in amplifier is connected to the source and a second, opposite connection of the lock-in amplifier is connected to ground. 11. The device of claim 10 , wherein an amplifier resistor is connected in parallel with the lock-in amplifier. 12. The device of claim 9 , wherein the function generator is connected to the source via a resistor. 13. The device of claim 9 , wherein the asymmetrically patterned graphene layer comprises a first patterned graphene section and a second graphene section, the second graphene section having no pattern. 14. The device of claim 13 , wherein the pattern comprises a hexagonal array of holes. 15. The device of claim 9 , wherein the infrared detector comprises a graphene channel, and wherein the graphene channel comprises the asymmetrically patterned graphene layer. 16. The device of claim 15 , wherein the asymmetrically patterned graphene layer comprises a first patterned graphene section and a second, unpatterned graphene section, the first patterned graphene section and the second, unpatterned graphene section extending in parallel along the length of the graphene channel. 17. The device of claim 9 , wherein the asymmetrically patterned graphene layer is coupled to an optical cavity. 18. The device of claim 9 , wherein the asymmetrically patterned graphene layer is a monolayer graphene layer. 19. The device of claim 9 , wherein the infrared detector is an uncooled infrared detector.
using thermoelectric elements, e.g. thermocouples · CPC title
comprising compounds containing boron, carbon, oxygen or nitrogen · CPC title
Arrangements for indicating or recording specially adapted for radiation pyrometers · CPC title
Physics · mapped topic
Physics · mapped topic
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