Semiconductor nanocrystals

Patent metadata

Field	Value
Publication number	US-11217662-B2
Application number	US-201816609125-A
Country	US
Kind code	B2
Filing date	Apr 27, 2018
Priority date	Apr 28, 2017
Publication date	Jan 4, 2022
Grant date	Jan 4, 2022

Abstract

Present subject matter provides a semiconductor nanocrystal comprises a core and a shell. The core is fabricated from a first semiconductor. The shell is fabricated from a second semiconductor. The optical cross section of the semiconductor nanocrystal is in a range of 10−17 cm2-10−12 cm2 in a 2-3 eV region. The core is less than 2 nanometers from an outer surface of the shell in at least one region of the semiconductor nanocrystal. Present subject matter also provides method for preparation of the semiconductor nanocrystals and method for photosynthesis of organic compounds.

First claim

We claim:

1. A method for preparing a semiconductor nanocrystal comprising:
preparing a core, wherein the core is a copper aluminium sulfide core, wherein preparing the core comprises:
preparing a core anion precursor by contacting sulfur with a mixture of oleylamine and octadecene in an inert atmosphere at a temperature range of 25° C. -300° C. to obtain the core anion precursor;
preparing a core cation precursor by contacting a copper salt and aluminium salt with a liquid medium comprising an organic acid in an inert atmosphere at 85-285° C. for a time period of 10-20 minutes to obtain the core cation precursor; and
contacting the core anion precursor with the core cation precursor to obtain the core; by:

contacting the core cation precursor with an organic thiol to obtain a first mixture;
and contacting the core anion precursor with the first mixture at a temperature range of 160-285° C. to obtain the copper aluminium sulfide core; and
preparing a shell enclosing the core, wherein the shell is a zinc sulfide shell, wherein preparing the shell comprises:
heating the core to a temperature in a range of 150-280° C.; and
contacting the core with shell precursors to obtain the semiconductor nanocrystal, wherein the optical cross section of the semiconductor nanocrystal is in a range of 10 -31 17 cm 2 -10 −  cm 2 in a 2 - 3 eV region, and wherein the core is less than 2 nanometers from an outer surface of the shell in at least one region of the semiconductor nanocrystal.

2. A method for photosynthesis of organic compounds, the method comprising:
contacting a plurality of semiconductor nanocrystals with a dispersion of salts selected from the group consisting of carbonates, bicarbonates, and carboxylates in water to obtain a first composition, wherein each of the plurality of semiconductor nanocrystals comprises:
a core fabricated from a first semiconductor; and
a shell fabricated from a second semiconductor, wherein the optical cross section of the semiconductor nanocrystal is in a range of 10 −17 cm 2 -10 −12 cm 2 in a 2-3 eV region, and wherein the core is less than 2 nanometers from an outer surface of the shell in at least one region of the semiconductor nanocrystal; and
irradiating the first composition with light to obtain the organic compounds.

3. The method as claimed in claim 2 , wherein products of irradiating the first composition are organic compounds selected from the group comprising formate, acetate, methanol and butanol.

4. The method as claimed in claim 2 , wherein the contacting comprises:
contacting salts with water to obtain the dispersion; and
adding the plurality of semiconductor nanocrystals to the dispersion.

5. The method as claimed in claim 2 , wherein the contacting comprises:
depositing the plurality of semiconductor nanocrystals on an inner surface of a vessel to obtain a coated vessel;
contacting the salts with water to obtain the dispersion; and
adding the dispersion to the coated vessel.

6. The method as claimed in claim 2 , wherein concentration of salts in the dispersion is in a range of 1 micromolar to 10 molars.

7. The method as claimed in claim 2 , wherein the dispersion comprises a first fraction of salts soluble in water and a second fraction of salts insoluble in water.

8. The method as claimed in claim 2 , wherein the method comprises providing the plurality of semiconductor nanocrystals as a plurality of layers on an inert substrate.

9. The method as claimed in claim 8 , wherein the inert substrate comprises a granular material with a grain size in a range of 50 nm to 1 cm, wherein the inert substrate is selected from the group consisting of glass, silicate glass, non-silicate glass, silica, activated silica, zeolite, sapphire, alumina, calcite, calcium fluoride, magnesium fluoride, barium fluoride, mica, teflon, anodized aluminum, ZnO, TiO 2 , and combinations thereof.

Assignees

• Indian Inst Scient

Inventors

• Pandey Anshu
• Bhattacharyya Biswajit
• Rajasekar Guru Pratheep
• Simlandy Amit Kumar

Classifications

• B01J2235/05

  Nuclear magnetic resonance [NMR] · CPC title

• B01J2235/00

  Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties · CPC title

• B01J2235/30

  Scanning electron microscopy; Transmission electron microscopy · CPC title

• B01J35/45

  Nanoparticles · CPC title

• B01J2235/15

  X-ray diffraction · CPC title