Use of amorphous calcium carbonate in a fire-resistant inorganic mortar system based on aluminous cement to increase load values at elevated temperatures
US-2020377424-A1 · Dec 3, 2020 · US
US11214519B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-11214519-B2 |
| Application number | US-201615764897-A |
| Country | US |
| Kind code | B2 |
| Filing date | Oct 19, 2016 |
| Priority date | Oct 20, 2015 |
| Publication date | Jan 4, 2022 |
| Grant date | Jan 4, 2022 |
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A two-component mortar system, which includes a component A; and a component B, which is in aqueous-phase for initiating a curing process. Component A comprises water, aluminous cement, at least one plasticizer, and at least one blocking agent selected from the group consisting of phosphoric acid, metaphosphoric acid, phosphorous acid, and a phosphoric acid. Component B includes an initiator, at least one retarder, at least one mineral filler, and water.
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The invention claimed is: 1. A two-component mortar system, comprising: a component A; and a component B, which is in aqueous-phase for initiating a curing process, wherein component A comprises water, aluminous cement, at least one plasticizer, and at least one blocking agent selected from the group consisting of phosphoric acid, metaphosphoric acid, phosphorous acid, and a phosphonic acid and wherein component B comprises an initiator, at least one retarder, at least one mineral filler, and water, and wherein i) the initiator comprises a mixture of at least two members selected from the group consisting of an alkali metal salt, an alkaline earth metal salt, and a combination thereof, ii) the at least one retarder is selected from the group consisting of citric acid, tartaric acid, lactic acid, salicylic acid, gluconic acid, and a mixture thereof, iii) the at least one mineral filler is selected from the group consisting of a limestone filler, sand, corundum, dolomite, alkaline-resistant glass, crushed stone, gravel, pebble, and a mixture thereof, iv) component A is a curable composition, and component A and component B are separate, wherein the two-component mortar system has an initial set time of at least 10 min. 2. The two-component mortar system according to claim 1 , wherein the initiator comprises a mixture of at least two lithium metal salts. 3. The two-component mortar system according to claim 1 , wherein at least one retarder is citric acid, tartaric acid, or a mixture thereof. 4. The two-component mortar system according to claim 1 , wherein the at least one mineral filler has an average particle size of not more than 500 μm. 5. The two-component mortar system according to claim 1 , wherein the at least one mineral filler is a limestone filler or a mixture of at least two limestone fillers. 6. The two-component mortar system according to claim 1 , wherein the water to aluminous cement ratio (W/CAC) or water to calcium sulfoaluminate cement (W/CAS), in the product obtained by mixing components A and B, is lower than 1.5. 7. The two-component mortar system according to claim 1 , wherein the shelf life of component A and component B is at least six months. 8. The two-component mortar system according to claim 1 , wherein component A and component B are in form of a slurry or paste. 9. The two-component mortar system according to claim 1 , wherein the pH-value of component B is above 10. 10. A two-component mortar system, comprising: a component A; and a component B, which is in aqueous-phase for initiating a curing process, wherein component A comprises water, aluminous cement, at least one plasticizer, and at least one blocking agent selected from the group consisting of phosphoric acid, metaphosphoric acid, phosphorous acid, and a phosphonic acid and wherein component B comprises an initiator, at least one retarder, at least one mineral filler, and water, and wherein i) the initiator comprises a mixture of at least two members selected from the group consisting of an alkali metal salt, an alkaline earth metal salt, and a combination thereof, ii) the at least one retarder is selected from the group consisting of citric acid, tartaric acid, lactic acid, salicylic acid, gluconic acid, and a mixture thereof, iii) the at least one mineral filler is selected from the group consisting of a limestone filler, sand, corundum, dolomite, alkaline-resistant glass, crushed stone, gravel, pebble, and a mixture thereof, iv) component A is a curable composition, and component A and component B are separate, wherein component B comprises 0.1 wt.-% to 4 wt.-% of lithium hydroxide, 0.1 wt.-% to 5 wt.-% of lithium sulfate or lithium sulfate monohydrate, 0.05 wt.-% to 5 wt.-% of citric acid, 0.05 wt.-% to 4 wt.-% of tartaric acid, 35 wt.-% to 45 wt.-% of a first mineral filler, 15 wt.-% to 25 wt.-% of a second mineral filler, 10 wt.-% to 20 wt.-% of a third mineral filler, 0.01 wt.-% to 0.5 wt.-% of a thickening agent, and 15 wt.-% to 25 wt.-% of water based on a total weight of component B. 11. The two-component mortar system according to claim 10 , wherein the first mineral filler, the second mineral filler, and the third mineral filler are three different calcium carbonate fines. 12. A method of chemically fastening an anchor in a mineral surface, the method comprising: setting the anchor in the mineral surface in the presence of the two-component mortar system according to claim 1 ; and curing the two-component mortar system. 13. The method according to claim 12 , wherein the anchor is at least one member selected from the group consisting of an anchor rod, a threaded anchor rod, a bolt, and a steel reinforcement bar. 14. The method according to claim 12 , wherein the mineral surface is at least one member selected from the group consisting of brickwork, concrete, pervious concrete, and natural stone.
of calcium · CPC title
Aluminous cements (monolithic refractories or refractory mortars C04B35/66) · CPC title
containing phosphorus in the anion, e.g. phosphates · CPC title
Use of waste materials as fillers for mortars or concrete · CPC title
containing hydroxy groups · CPC title
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