Glass sheet approaching neutrality irrespective of its thickness

Patent metadata

Field	Value
Publication number	US-11214507-B2
Application number	US-201716318558-A
Country	US
Kind code	B2
Filing date	Jul 18, 2017
Priority date	Jul 20, 2016
Publication date	Jan 4, 2022
Grant date	Jan 4, 2022

Abstract

A glass sheet having a composition comprising a total iron content of 0.002-0.03% expressed in the form of Fe 2 O 3 and in weight percentage with respect to the total weight of glass, and further satisfying the formula N* 5 ≤0.05; N* 5 being defined as N* 5 =√{square root over ((a* 5 −a* 0 ) 2 +(b* 5 −b* 0 ) 2 )}, a* 5 and b* 5 being measured for a sheet thickness of 5 mm in transmission with illuminant D65, 10°, SCI; a* 0 and b* 0 being computed for a sheet thickness of 0 mm in transmission with illuminant D65, 10°, SCI. Such a glass sheet allows a color rendering of the sheet which is essentially the same whatever the view path available for an observer of the object integrating said glass sheet (when looking through its main faces or through its edges or through a zone bearing a diffusing coating).

First claim

The invention claimed is:

1. A glass sheet having a composition comprising the following in weight percentage, expressed with respect to a total weight of the glass:
SiO 2 40-78%;
Al 2 O 3 0-18%;
B 2 O 3 0-18%;
Na 2 O 0-20%;
CaO 0-15%;
MgO 0-12%;
K 2 O 0-12%;
BaO 0-5%; and
a total iron content of 0.002-0.03% expressed in the form of Fe 2 O 3 and in weight percentage with respect to the total weight of glass, and wherein the glass satisfies the formula:
N* 5 <0.05; N* 5 being defined as N* 5 =√{square root over ((a* 5 −a* 0 ) 2 +(b* 5 −b* 0 ) 2 )}, a* 5 and b* 5 being measured for a sheet thickness of 5 mm in transmission with illuminant D65, 10°, SCI; a* 0 and b* 0 being computed for a sheet thickness of 0 mm in transmission with illuminant D65, 10°, SCI, and

wherein the composition further comprises
erbium (expressed in the form of Er 2 O 3 ) as follows: 0.003-0.5%, or
selenium (expressed as Se) as follows: 3-50 ppm and cobalt (expressed as Co) as follows: 0.1-15 ppm.

2. The glass sheet according to claim 1 , wherein the composition comprises: total iron 0.002-0.02 wt %.

3. The glass sheet according to claim 1 , wherein the composition comprises: total iron 0.002-0.015 wt %.

4. The glass sheet according to claim 1 , wherein the composition has a redox ratio ≤32%.

5. The glass sheet according to claim 1 , wherein the composition comprises erbium (expressed in the form of Er 2 O 3 ) as follows: 0.003-0.5 wt %.

6. The glass sheet according to claim 5 , wherein the composition comprises: Er 2 O 3 ≥0.01 wt %.

7. The glass sheet according to claim 1 , wherein the composition comprises: Er 2 O 3 ≤0.1 wt %.

8. The glass sheet according to claim 1 , further comprising:
erbium (expressed in the form of Er 2 O 3 ) in an amount of 30 to 150 ppm.

9. The glass sheet according to claim 1 , further comprising:
erbium (expressed in the form of Er 2 O 3 ) in an amount of 50 to 100 ppm.

10. The glass sheet according to claim 1 , wherein the composition comprises selenium (expressed as Se) as follows: 3-50 ppm and cobalt (expressed as Co) as follows: 0.1-15 ppm.

11. The glass sheet according to claim 1 , wherein the composition comprises Co as follows: 0.25-20 ppm.

12. The glass sheet according to claim 1 , further comprising:
cobalt (expressed as Co) in an amount of 0.5 to 5 ppm.

13. The glass sheet according to claim 1 , further comprising:
cobalt (expressed as Co) in an amount of 1 to 2 ppm.

14. The glass sheet according to claim 1 , wherein N* 5 ≤0.03.

15. The glass sheet according to claim 1 , wherein N* 5 ≤0.01.

16. A glass sheet having a composition comprising the following in weight percentage, expressed with respect to a total weight of the glass:
SiO 2 40-78%;
Al 2 O 3 1-6%;
B 2 O 3 0-18%;
Na 2 O 0-20%;
CaO 0-15%;
MgO 0-12%;
K 2 O 0-12%;
BaO 0-5%; and
a total iron content of 0.002-0.03% expressed in the form of Fe 2 O 3 and in weight percentage with respect to the total weight of glass, and wherein the glass satisfies the formula:
N* 5 <0.05; N* 5 being defined as N* 5 =√{square root over ((a* 5 −a* 0 ) 2 +(b* 5 −b* 0 ) 2 )}, a* 5 and b* 5 being measured for a sheet thickness of 5 mm in transmission with illuminant D65, 10°, SCI; a* 0 and b* 0 being computed for a sheet thickness of 0 mm in transmission with illuminant D65, 10°, SCI, and

wherein the composition further comprises
erbium (expressed in the form of Er 2 O 3 ) as follows: 0.003-0.5 wt %, or
selenium (expressed as Se) as follows: 3-50 ppm and cobalt (expressed as Co) as follows: 0.1-15 ppm.

Assignees

• Agc Glass Europe

Inventors

• Lambricht Thomas
• Dogimont Audrey

Classifications

• C03C3/091

  containing aluminium · CPC title

• C03C3/078

  containing an oxide of a divalent metal, e.g. an oxide of zinc · CPC title

• C03C3/085

  containing an oxide of a divalent metal · CPC title

• C03C2201/3476

  Erbium · CPC title

• C03C4/0092 Primary

  for glass with improved high visible transmittance, e.g. extra-clear glass · CPC title