Spinel compound oxide particle, method for producing the same, resin composition including spinel compound oxide particle, and molded article

Patent metadata

Field	Value
Publication number	US-11214494-B2
Application number	US-201816611621-A
Country	US
Kind code	B2
Filing date	May 1, 2018
Priority date	May 11, 2017
Publication date	Jan 4, 2022
Grant date	Jan 4, 2022

Abstract

A spinel compound oxide particle includes metallic atoms, aluminum atoms, oxygen atoms, and molybdenum atoms, wherein the metallic atoms are selected from the group consisting of zinc atoms, cobalt atoms, and strontium atoms, and a crystallite size in a [111] plane is 100 nm or more. Included are a step (1) of firing a first mixture including a molybdenum compound and a metallic-atom-containing compound or a first mixture including a molybdenum compound, a metallic-atom-containing compound, and an aluminum compound to prepare an intermediate; and a step (2) of firing, at a temperature higher than a temperature selected in the step (1), a second mixture including the intermediate or a second mixture including the intermediate and an aluminum compound.

First claim

The invention claimed is:

1. A spinel compound oxide particle comprising: metallic atoms, aluminum atoms, oxygen atoms, and molybdenum atoms,
wherein the metallic atoms are selected from the group consisting of zinc atoms, cobalt atoms, and strontium atoms,
wherein the molybdenum content of the spinel compound oxide particle is 20 mol % or less relative to the spinel compound oxide, and
a crystallite size in a plane is 100 nm or more.

2. The spinel compound oxide particle according to claim 1 , further comprising a surface-treated layer.

3. A resin composition comprising the spinel compound oxide particle according to claim 1 and a resin.

4. A molded article formed from the resin composition according to claim 3 .

5. A resin composition comprising the spinel compound oxide particle according to claim 2 and a resin.

6. A molded article formed from the resin composition according to claim 5 .

7. A method for producing the spinel compound oxide particle comprising: metallic atoms, aluminum atoms, oxygen atoms, and molybdenum atoms,
wherein the metallic atoms are selected from the group consisting of zinc atoms,
cobalt atoms, and strontium atoms, and
a crystallite size in a [111] plane is 100 nm or more;
the method comprising:
a step (1) of firing a first mixture (A-1) including a molybdenum compound and a metallic-atom-containing compound or a first mixture (A-2) including a molybdenum compound, a metallic-atom-containing compound, and an aluminum compound to prepare an intermediate; and
a step (2) of firing, at a temperature higher than a temperature selected in the step (1), in a case of using the mixture (A-2), a second mixture including the intermediate, or, in a case of using the mixture (A-1), a second mixture including the intermediate and an aluminum compound, to produce the spinel compound oxide particle,
wherein the metallic-atom-containing compound is selected from the group consisting of zinc-containing compounds, cobalt-containing compounds, and strontium-containing compounds.

8. The production method according to claim 7 , wherein a molar ratio of a molybdenum element of the molybdenum compound to a metallic element of the metallic-atom-containing compound is 0.01 to 2.0.

9. The method for producing the spinel compound oxide particle according to claim 7 , wherein the spinel compound oxide particle further comprises a surface-treated layer formed by surface treating the spinel compound oxide particle.

10. A method for producing the spinel compound oxide particle comprising: metallic atoms, aluminum atoms, oxygen atoms, and molybdenum atoms,
wherein the metallic atoms are selected from the group consisting of zinc atoms,
cobalt atoms, and strontium atoms, and
a crystallite size in a [111] plane is 100 nm or more;
the method comprising:
a firing step of subjecting a metallic-atom-containing compound and an aluminum compound in the presence of molybdenum atoms to solid solution formation and crystal formation to cause crystal growth to the spinel compound oxide particle; and
a cooling step of crystallizing the spinel compound oxide particle provided by the crystal growth in the firing step,
wherein the metallic-atom-containing compound is selected from the group consisting of zinc-containing compounds, cobalt-containing compounds, and strontium-containing compounds.

11. The method for producing the spinel compound oxide particle according to claim 10 , wherein the spinel compound oxide particle further comprises a surface-treated layer formed by surface treating the spinel compound oxide particle.

12. The production method according to claim 10 , wherein a molar ratio of a molybdenum element of the molybdenum compound to a metallic element of the metallic-atom-containing compound is 0.01 to 2.0.

Assignees

• Dainippon Ink & Chemicals

Inventors

• Itoya Kazuo
• Iida Masaki
• Yuan Jian-Jun
• YOSHIMOTO Yasuyo
• Oki Hironobu
• Hayashi Masamichi

Classifications

• C01G51/40 Primary

  Complex oxides containing cobalt and at least one other metal element · CPC title

• C08L101/00

  Compositions of unspecified macromolecular compounds · CPC title

• C01G51/04

  Oxides · CPC title

• C01P2002/32

  spinel-type (AB2O4) · CPC title

• C01P2004/61

  Micrometer sized, i.e. from 1-100 micrometer · CPC title