Sheet, method for manufacturing the same, and tire comprising the same

Patent metadata

Field	Value
Publication number	US-11214095-B2
Application number	US-201816201966-A
Country	US
Kind code	B2
Filing date	Nov 27, 2018
Priority date	Dec 22, 2017
Publication date	Jan 4, 2022
Grant date	Jan 4, 2022

Abstract

Provided are a sheet, a method of its preparation, and a tire comprising the sheet, wherein the sheet comprises tire cords, a topping rubber for topping the tire cords, and a conductive fiber located on the surface of the topping rubber.
The sheet can provide tires, on which a rubber composition with a low electricity-transmitting property and low rolling resistance is applied, with excellent conductivity.

First claim

What is claimed is:

1. A sheet, comprising:
tire cords;
a topping rubber, which is for topping the tire cords; and
a conductive fiber, which is located on the topping rubber,
wherein the conductive fiber comprises a carbon fiber, or a fiber in which a metal is coated on at least one fiber selected from the group consisting of a first synthetic fiber, a first regenerated cellulose fiber, and a first natural fiber,
wherein the carbon fiber is blended with any fiber selected from the group consisting of a second synthetic fiber, a second regenerated cellulose fiber, and a second natural fiber,
wherein the topping rubber comprises composition (a) or composition (b),
wherein composition (a) includes:
100 parts by weight of a raw material rubber, which comprises 20 to 50 parts by weight of a natural rubber and 50 to 80 parts by weight of a styrene butadiene rubber; and
20 to 60 parts by weight of carbon black, which has a statistical thickness surface area (STSA) value of 29 m 2 /g to 39 m 2 /g, an oil absorption number of compressed sample (COAN) value of 69 cc/100 g to 79 cc/100 g, an oil absorption number of sample (OAN) value of 85 cc/100 g to 95 cc/100 g, and an iodine adsorption value of 31 mg/g to 41 mg/g, and

wherein composition (b) includes:
100 parts by weight of a raw material rubber, which comprises 10 to 40 parts by weight of a synthetic styrene butadiene rubber and 60 to 90 parts by weight of a natural rubber,
10 to 40 parts by weight of a first carbon black, which has an STSA value of 29 m2/g to 39 m2/g, a COAN value of 69 cc/100 g to 79 cc/100 g, an OAN value of 85 cc/100 g to 95 cc/100 g, and an iodine adsorption value of 31 mg/g to 41 mg/g, and
20 to 50 parts by weight of a second carbon black, which has an STSA value of 70 m2/g to 80 m2/g, a COAN value of 83 cc/100 g to 93 cc/100 g, an OAN value of 96 cc/100 g to 108 cc/100 g, and an iodine adsorption value of 76 mg/g to 88 mg/g.

2. The sheet of claim 1 ,
wherein each of the first and second synthetic fiber is one selected from the group consisting of a polyester fiber, a polyamide fiber, a polyacrylonitrile fiber, and a polyurethane fiber.

3. The sheet of claim 1 ,
wherein each of the first and second natural fiber is one selected from the group consisting of a hemp fiber and a cotton fiber.

4. The sheet of claim 1 ,
wherein each of the first and second regenerated cellulose fiber is one selected from the group consisting of rayon and a regenerated cellulose fiber prepared using N-methylmorpholine N-oxide (NMMO).

5. The sheet of claim 1 ,
wherein the fiber on which a metal is coated is a fiber, in which a metal is coated on one selected from the group consisting of a synthetic fiber, a regenerated cellulose fiber, and a natural fiber, by a method selected from the group consisting of electroplating, electroless plating, chemical vapor deposition plating, and physical vapor deposition plating.

6. The sheet of claim 1 ,
wherein the fiber on which a metal is coated or the carbon fiber is blended with any one fiber selected from the group consisting of a synthetic fiber, a regenerated cellulose fiber, and a natural fiber in a weight ratio of 10:90 to 90:10.

7. The sheet of claim 1 ,
wherein a diameter of the conductive fiber is selected from the group consisting of 0.05 mm to 0.5 mm, 5 'S to 100 'S based on spun yarn, and 50 denier to 1,000 denier based on filament yarn.

8. The sheet of claim 1 ,
wherein the sheet comprises 1 to 60 conductive fibers.

9. A method for preparing a sheet, comprising:
preparing a first fiber,
wherein the first fiber is a carbon fiber or a fiber in which a metal is coated on at least one fiber selected from the group consisting of a synthetic fiber, a regenerated cellulose fiber, and a natural fiber;
processing the first fiber by texturing;
preparing a conductive fiber by blending the texturing-processed fiber with any one fiber selected from the group consisting of a synthetic fiber, a regenerated cellulose fiber, and a natural fiber; and
topping tire cords with a topping rubber and attaching the conductive fiber to the topping rubber at a time of rolling or cutting,
wherein the topping rubber comprises composition (a) or composition (b),
wherein composition (a) includes:
100 parts by weight of a raw material rubber, which comprises 20 to 50 parts by weight of a natural rubber and 50 to 80 parts by weight of a styrene butadiene rubber; and
20 to 60 parts by weight of carbon black, which has a statistical thickness surface area (STSA) value of 29 m 2 /g to 39 m 2 /g, an oil absorption number of compressed sample (COAN) value of 69 cc/100 g to 79 cc/100 g, an oil absorption number of sample (OAN) value of 85 cc/100 g to 95 cc/100 g, and an iodine adsorption value of 31 mg/g to 41 mg/g, and

wherein composition (b) includes:
100 parts by weight of a raw material rubber, which comprises 10 to 40 parts by weight of a synthetic styrene butadiene rubber and 60 to 90 parts by weight of a natural rubber,
10 to 40 parts by weight of a first carbon black, which has an STSA value of 29 m 2 /g, to 39 m 2 /g, a COAN value of 69 cc/100 g to 79 cc/100 g, an OAN value of 85 cc/100 g to 95 cc/100 g, and an iodine adsorption value of 31 mg/g to 41 mg/g, and
20 to 50 parts by weight of a second carbon black, which has an STSA value of 70 m 2 /g to 80 m 2 /g, a COAN value of 83 cc/100 g to 93 cc/100 g, an OAN value of 96 cc/100 g to 108 cc/100 g, and an iodine adsorption value of 76 mg/g to 88 mg/g.

10. A tire comprising the sheet of claim 1 .

11. The sheet of claim 1 , wherein the tire cords are surrounded by the topping rubber.

12. The sheet of claim 1 , wherein the conductive fiber is partially embedded within the topping rubber.

13. The sheet of claim 1 , wherein the conductive fiber is oriented relative to the tire cords at an acute angle.

14. The sheet of claim 1 , wherein the conductive fiber is oriented parallel to the tire cords.

Assignees

• Hankook Tire Co Ltd

Inventors

• Lee Ji Wan
• Lee Mi Jung
• Kim Sung Tae
• Ko Kil Ju
• Park Il Yong
• Sung Su Hong

Classifications

• C08L9/06

  Copolymers with styrene · CPC title

• B60C19/084 Primary

  using conductive carcasses · CPC title

• B29D30/38

  Textile inserts, e.g. cord or canvas layers, for tyres (making woven fabrics D03D); Treatment of inserts prior to building the tyre (pretreatment of inserts B29B15/00; manufacture of layers comprising fibrous parallel reinforcements of substantial or continuous length B29C70/20) · CPC title

• B29D30/08

  Building tyres · CPC title

• C08L9/00

  Compositions of homopolymers or copolymers of conjugated diene hydrocarbons · CPC title