CMP method for forming smooth diamond surfaces
US-9259819-B2 · Feb 16, 2016 · US
US11213927B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-11213927-B2 |
| Application number | US-201816233943-A |
| Country | US |
| Kind code | B2 |
| Filing date | Dec 27, 2018 |
| Priority date | Dec 28, 2017 |
| Publication date | Jan 4, 2022 |
| Grant date | Jan 4, 2022 |
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A method of processing chemical mechanical polishing (CMP) pad conditioners includes providing the CMP pad conditioner including conditioner substrate that is a metal, ceramic or a metal-ceramic material with a plurality of hard conditioner particles with a Vickers hardness greater than 3,000 Kg/mm2 bonded to a top surface of the conditioner substrate, and a slurry including an aqueous medium and a plurality of hard slurry particles having a hardness greater than 3,000 Kg/mm2. The surface of the pad conditioner is polished in a CMP apparatus using a polishing pad. After the polishing each conditioner particle has at least one exposed facet, and the plurality of hard conditioner particles have a maximum average protrusion-to-protrusion flatness (PPF) difference of 20 microns, and a sharpest edge measured by a value of a cutting edge radius (CER) that lies at an edge of the facet for at least 80% of the facets.
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The invention claimed is: 1. A method of processing a chemical mechanical polishing (CMP) pad conditioner, comprising: providing said CMP pad conditioner comprising a conditioner substrate including a metal, ceramic or a metal-ceramic material having a patterned surface with a polycrystalline diamond film thereon, and a slurry including an aqueous medium and a plurality of hard slurry particles having a Vickers hardness greater than 3,000 Kg/mm 2 , and polishing said polycrystalline diamond film in a CMP apparatus using a polishing pad and the slurry, wherein said polycrystalline diamond film after said polishing includes tallest grains having a height lying in a top 20 percent of a peak-valley range, with at least 80 percent of said tallest grains having an orientation within 20 degrees from a (111) orientation. 2. The method of claim 1 , wherein said plurality of hard slurry particles comprise diamond particles. 3. The method of claim 2 , when an average size of said diamond particles range from 10 micron to 200 microns. 4. The method of claim 2 , wherein a concentration of said diamond particles in said slurry is between 1% and 20% by weight. 5. The method of claim 1 , wherein said polishing pad comprises a metal or a ceramic material with a Vickers hardness greater than 50 kg/m 2 . 6. The method of claim 1 , wherein said polishing pad comprises copper, steel, or a metal alloy including at least two metals. 7. The method in claim 1 , when a viscosity of said slurry ranges from 2 centipoise to 1,500 centipoise. 8. The method of claim 2 , further comprising secondary particles selected from alumina, or silica, with a Vickers hardness less than 3,000 Kg/mm 2 with a size between 10 nm to 10 micron, and a concentration between 1% to 60 weight percent. 9. The method of claim 8 , wherein said plurality of hard slurry particles comprise diamond particles, and wherein a size of said secondary particles is at least 30 percent smaller than a size of said diamond particles.
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