Oxygen solid solution titanium material sintered compact and method for producing same

Patent metadata

Field	Value
Publication number	US-11213889-B2
Application number	US-201615773018-A
Country	US
Kind code	B2
Filing date	Oct 26, 2016
Priority date	Nov 2, 2015
Publication date	Jan 4, 2022
Grant date	Jan 4, 2022

Abstract

An oxygen solid solution titanium sintered compact includes a matrix made of a titanium component having an α-phase, oxygen atoms dissolved as a solute of solid solution in a crystal lattice of the titanium component, and metal atoms dissolved as a solute of solid solution in the crystal lattice of the titanium component.

First claim

The invention claimed is:

1. A method for producing an oxygen solid solution titanium material sintered compact, comprising:
a step of mixing a combination of materials, the combination of materials consisting of:
at least one of (1) an uncoated titanium component powder made of a titanium component having an α-phase, or (2) an oil coated titanium component powder made of the titanium component and an oil; and
oxide particles of a metal other than titanium;

a step of applying a compression force to shape a mixed powder obtained through said mixing; and
a step of heating and sintering a compressed shaped compact, which is obtained through said compression shaping, in an environment that does not contain oxygen, wherein
said sintering step comprises:
decomposing said metal oxide into metal atoms and oxygen atoms;
dissolving the oxygen atoms, which have been dissociated from said metal oxide, as a solute of solid solution into a crystal lattice of the titanium component; and
allowing the metal atoms, which have been dissociated from said metal oxide, to remain in a matrix of the titanium component, and wherein

an average particle size of said metal oxide particles is 1 μm to 10 μm,
an amount of said metal oxide particles is within a range of 0.1% to 7% in terms of mass with respect to the total mixed powder, and
a lower limit of a heating and sintering temperature of said environment in the step of heating and sintering the compressed shaped compact is 700° C., and an upper limit of the heating and sintering temperature is a lower one of a temperature equal to or lower than a boiling point of the metal constituting said metal oxide and a temperature equal to or lower than a melting point of said titanium component.

2. The method for producing an oxygen solid solution titanium material sintered compact according to claim 1 , wherein said oxide particles are oxide particles of a metal selected from the group consisting of Si, Ta, Cu, Nb, Co, Fe, Mn, V, Sn, Cr, Al, Be, Zr, and Mg.

3. The method for producing an oxygen solid solution titanium material sintered compact according to claim 1 , wherein the metal atoms dissociated from said metal oxide are dissolved as a solute of solid solution into the crystal lattice of said titanium component by a treatment of said heating and sintering.

4. The method for producing an oxygen solid solution titanium material sintered compact according to claim 1 , wherein the metal atoms dissociated from said metal oxide react with said titanium component by a treatment of said heating and sintering to form a compound to be dispersed in said matrix.

5. The method for producing an oxygen solid solution titanium material sintered compact according to claim 1 , wherein the metal atoms dissociated from said metal oxide are deposited in the matrix of said titanium component by a treatment of said heating and sintering.

6. The method for producing an oxygen solid solution titanium material sintered compact according to claim 1 , wherein said compression shaping step and said sintering step are simultaneously carried out.

7. The method for producing an oxygen solid solution titanium material sintered compact according to claim 1 , further comprising a step of performing a heat treatment for homogenizing a structure of the sintered compact after said sintering step.

8. The method for producing an oxygen solid solution titanium material sintered compact according to claim 1 , further comprising a step of performing plastic forming of the sintered compact obtained after said heating and sintering.

9. A method for producing an oxygen solid solution titanium material sintered compact, comprising:
a step of mixing a combination of materials, the combination of materials consisting of:
an oil coated titanium component powder made of a titanium component having an α-phase and an oil; and
oxide particles of a metal other than titanium, wherein the oxide particles of the metal are dispersed and adhere onto the surface of titanium component powder particles;

a step of applying a compression force to shape a mixed powder obtained through said mixing; and
a step of heating and sintering a compressed shaped compact, which is obtained through said compression shaping, in an environment that does not contain oxygen, wherein
said sintering step comprises:
decomposing said metal oxide into metal atoms and oxygen atoms;
dissolving the oxygen atoms, which have been dissociated from said metal oxide, as a solute of solid solution into a crystal lattice of the titanium component; and
allowing the metal atoms, which have been dissociated from said metal oxide, to remain in a matrix of the titanium component, and wherein

an average particle size of said metal oxide particles is 1 μm to 10 μm,
an amount of said metal oxide particles is within a range of 0.1% to 7% in terms of mass with respect to the total mixed powder, and
a lower limit of a heating and sintering temperature of said environment in the step of heating and sintering the compressed shaped compact is 700° C., and an upper limit of the heating and sintering temperature is a lower one of a temperature equal to or lower than a boiling point of the metal constituting said metal oxide and a temperature equal to or lower than a melting point of said titanium component.

Assignees

• Hi Lex Corp
• Kondoh Katsuyoshi

Inventors

• Kondoh Katsuyoshi

Classifications

• C22C32/0031

  Matrix based on refractory metals, W, Mo, Nb, Hf, Ta, Zr, Ti, V or alloys thereof · CPC title

• C22C32/001

  with only oxides · CPC title

• C22C1/05

  Mixtures of metal powder with non-metallic powder (C22C1/08 takes precedence) · CPC title

• B22F1/05

  Metallic powder characterised by the size or surface area of the particles · CPC title

• B22F3/14

  simultaneously · CPC title