Method of flue gas denitrification

Patent metadata

Field	Value
Publication number	US-11213788-B2
Application number	US-201716329111-A
Country	US
Kind code	B2
Filing date	Aug 31, 2017
Priority date	Aug 31, 2016
Publication date	Jan 4, 2022
Grant date	Jan 4, 2022

Abstract

A method for flue gas denotation includes the step of, in the presence of ammonia, enabling flue gas in a denitration reactor to pass through a plurality of catalyst beds from the bottom to the top to participate in a denitration reaction. Each catalyst bed contains a catalyst support component and a granular denitration catalyst stacked on the catalyst support component, and, in every single catalyst bed, the granular denitration catalyst moves along a same direction on the catalyst support component. Between every two adjacent catalyst beds, the granular denitration catalyst falls from the tail of a previous catalyst support component to the head of a next catalyst support component, making the granular denitration catalyst travel along the catalyst support components reciprocatively.

First claim

The invention claimed is:

1. A method of flue gas denitrification, comprising: in the presence of ammonia, passing a flue gas through a plurality of catalyst beds disposed from bottom to top in a denitrification reactor to undergo a denitrification reaction, wherein each catalyst bed comprises a catalyst support component and a granular denitrification catalyst stacked on the catalyst support component; an upper catalyst support component and a lower catalyst support component in every two adjacent catalyst beds travel in directions opposite to each other, and the granular denitrification catalyst on the upper catalyst support component moves with the upper catalyst support component to a tail end of the upper catalyst support component, and falls by gravity to a head end of the lower catalyst support component.

2. A method of flue gas denitrification, comprising: introducing a flue gas into a denitrification reactor to a bottom part of a denitrification reactor;
injecting a gas mixture containing ammonia into the flue gas through one or more ammonia injection grilles;
passing a gas flow through a plurality of catalyst beds arranged in a horizontally staggered manner from bottom to top to undergo a denitrification reaction to remove NO X ,
filtering the flue gas to remove dust from the catalyst beds; and
discharging a denitrificated and dedusted flue gas from a top portion of the denitrification reactor,
wherein each catalyst bed comprises a net conveyor belt and a granular denitrification catalyst stacked on the net conveyor belt; the two conveyor belts in every two adjacent catalyst beds, i.e. an upper net conveyor belt and a lower net conveyor belt, travel in directions opposite to each other, the granular denitrification catalyst on the upper conveyor belt moves with the upper conveyor belt to a tail end of the upper conveyor belt, and falls by gravity to a head end in the travel direction of the lower conveyor belt; and the granular denitrification catalyst fells from the tail end of the bottom catalyst bed is collected and recycled.

3. The method according to claim 1 , wherein the catalyst support component is a net conveyor belt.

4. The method according to claim 3 , wherein the net conveyor belt has a mesh size of 0.1-3 mm.

5. The method according to claim 1 , wherein a distance of number of the catalyst beds is 3-10.

6. The method according to claim l, wherein a distance in a vertical distance between every two adjacent catalyst beds is 1,200-2,000 mm.

7. The method according to claim 1 , wherein the flue gas entering the denitrification reactor has a temperature of 300-420° C.

8. The method according to claim 1 , wherein the ammonia is introduced in the form of a gas mixture containing ammonia and air, and a volumetric concentration of the ammonia in the gas mixture is 0.5-10%.

9. The method according to claim 8 , wherein the gas mixture is injected below the bottom catalyst bed.

10. The method according to claim 1 , wherein a molar ratio of ammonia to nitrogen oxides in terms of nitrogen atoms in the flue gas is 0.9-1.15:1.

11. The method according to claim 1 , wherein a velocity of the flue gas is 2-15 m/s, and a residence time for reaction is 0.5-20 s.

12. The method according to claim 1 , wherein the granular denitrification catalyst has a granule size of 3-6 mm, a stacking density of 0.2-0.8 g/cm 3 , and a specific surface area of 80-120 m 2 /g.

13. The method according to claim 1 , wherein the granular denitrification catalyst forms a layer on the catalyst support component having a thickness of 50-500 mm.

14. The method according to claim 3 , wherein a speed of the net conveyor belt is 0.1-10 mm/s.

15. The method according to claim 1 , wherein the ammonia is injected into the denitrification reactor through an ammonia injection grille.

16. The method according to claim 15 , wherein a deviation of concentration distribution of the ammonia in the gas mixture injected through the ammonia injection grille is 5%-30%.

17. The method according to claim 2 , wherein the net conveyor belt has a mesh size of 0.1-3 mm.

18. The method according to claim 2 , wherein a speed of the net conveyor belt is 0.1-10 mm/s.

19. The method according to claim 2 , wherein a deviation of concentration distribution of the ammonia in the gas mixture injected through the ammonia injection grille is is 5%-30%.

Assignees

• China Petroleum & Chem Corp
• Fushun Res Institute Of Petroleum And Petrochemicals Sinopec Corp

Inventors

• Li Xin
• Liu Shuhe
• Han tianzhu
• Wang Mingxing

Classifications

• B01J35/40

  characterised by dimensions, e.g. grain size (in a colloidal state B01J35/23; crystallite size B01J35/77) · CPC title

• B01D2258/0283

  Flue gases · CPC title

• B01D53/83 Primary

  with moving reactants · CPC title

• B01D2257/404

  Nitrogen oxides other than dinitrogen oxide · CPC title

• B01D2257/302

  Sulfur oxides · CPC title