Regeneration of molten carbonate fuel cells for deep CO2 capture

Patent metadata

Field	Value
Publication number	US-11211621-B2
Application number	US-201916695335-A
Country	US
Kind code	B2
Filing date	Nov 26, 2019
Priority date	Nov 30, 2018
Publication date	Dec 28, 2021
Grant date	Dec 28, 2021

Abstract

Systems and methods are provided for operating molten carbonate fuel cells to allow for periodic regeneration of the fuel cells while performing elevated CO2 capture. In some aspects, periodic regeneration can be achieved by shifting the location within the fuel cells where the highest density of alternative ion transport is occurring. Such a shift can result in a new location having a highest density of alternative ion transport, while the previous location can primarily transport carbonate ions. Additionally or alternately, periodic regeneration can be performed by modifying the input flows to the fuel cell and/or relaxing the operating conditions of the fuel cell to reduce or minimize the amount of alternative ion transport.

First claim

The invention claimed is:

1. A method for producing electricity, the method comprising:
operating a molten carbonate fuel cell comprising an anode and a cathode, for a first time period, at a first operating condition comprising a first transference of 0.95 or less and a first average current density of 60 mA/cm 2 or more, to generate an anode exhaust comprising H 2 , CO, and CO 2 , and a cathode exhaust comprising 2.0 vol % or less CO 2 , 1.0 vol % or more O 2 , and 1.0 vol % or more H 2 O; and
operating the molten carbonate fuel cell, for a second time period, at a second operating condition comprising a second transference of greater than 0.95 to generate an anode exhaust and a cathode exhaust.

2. The method of claim 1 , wherein the first operating condition comprises a first measured CO 2 utilization of 75% or more, a cathode input stream having a CO 2 concentration of 10 vol % or less, or a combination thereof.

3. The method of claim 1 , wherein the second operating condition comprises one or more of a) a second measured CO 2 utilization of 70% or less, b) a cathode input stream having a CO 2 concentration of 15 vol % or more, c) a second average current density lower than the first average current density by 20 mA/cm 2 or more, and d) a cathode exhaust comprising a CO 2 content of 2.0 vol % or more.

4. The method of claim 3 , wherein operating at the second CO 2 utilization of 70% or less comprises increasing a flow rate of the cathode input gas into the cathode while maintaining the first average current density.

5. The method of claim 3 , wherein the first operating condition comprises a first flow rate for the cathode input stream, and wherein the second operating condition comprises the first cathode input stream, the first flow rate, and the second average current density.

6. The method of claim 1 , wherein the second transference is 0.98 or more.

7. The method of claim 1 , further comprising: operating the molten carbonate fuel cell, for a third time period, at a third operating condition comprising a third transference of 0.95 or less and a third average current density of 60 mA/cm 2 or more, to generate an anode exhaust comprising H 2 , CO, and CO 2 , and a cathode exhaust comprising 2.0 vol % or less CO 2 , 1.0 vol % or more O 2 , and 1.0 vol % or more H 2 O.

8. The method of claim 7 , wherein the third operating condition is substantially the same as the first operating condition.

9. The method of claim 1 , wherein the first time period and the second time period comprise a cycle period, the first time period comprising 51% or more of the cycle period.

10. The method of claim 1 , wherein the first transference is 0.90 or less.

11. The method of claim 1 , wherein the first average current density is 150 mA/cm 2 or more, or wherein the second average current density is 80 mA/cm 2 or more, or a combination thereof.

12. The method of claim 1 , wherein the cathode comprises a cathode surface having an open area of 45% or more.

13. The method of claim 1 , wherein the first operating condition comprises a cathode input stream comprising 5.0 vol % or less of CO 2 , or wherein the first operating condition comprises a cathode exhaust comprising 1.0 vol % or less of CO 2 , or a combination thereof.

14. The method of claim 1 , further comprising:
introducing an anode input stream into the anode of a molten carbonate fuel cell;
introducing a cathode input stream comprising O 2 , CO 2 , and H 2 O into the cathode of the molten carbonate fuel cell.

Assignees

• Exxonmobil Res & Eng Co
• Fuelcell Energy Inc

Inventors

• Barckholtz Timothy A
• Rosen Jonathan
• Pereira Carla S
• Blanco Gutierrez Rodrigo F
• Hershkowitz Frank
• Willman Carl A
• Geary Timothy C

Classifications

• Y02E60/50

  Fuel cells · CPC title

• H01M8/04223 Primary

  during start-up or shut-down; Depolarisation or activation, e.g. purging; Means for short-circuiting defective fuel cells · CPC title

• H01M8/04805 Primary

  of fuel cell exhausts · CPC title

• H01M8/04574

  Current · CPC title

• H01M8/0491

  of fuel cell stacks · CPC title