Use of semi-aromatic copolyamide for transporting refrigerant fluid

Patent metadata

Field	Value
Publication number	US-11209105-B2
Application number	US-202016784323-A
Country	US
Kind code	B2
Filing date	Feb 7, 2020
Priority date	Feb 18, 2013
Publication date	Dec 28, 2021
Grant date	Dec 28, 2021

Abstract

Provided is a method for heating or cooling a liquid or a body by means of a vapor compression circuit containing a heat transfer fluid. The vapor compression circuit element includes at least one layer that includes copolyamide of formula X/10.T/Y, where the structural variables are described herein.

First claim

The invention claimed is:

1. A heat transfer device comprising a vapor compression circuit which comprises at least one vapor compression circuit element comprising at least one layer consisting of (1) 30% to 99% by mass of at least one copolyamide comprising units of the formula X, 10.T and Y and (2) at least one member selected from the group consisting of functionalized polyolefins, plasticizers, conversion aids, fillers, heat stabilizers, UV stabilizers, nucleating agents, dyes, pigments, mold release agents, flame retardants, surfactants, fluorescent whiteners, additional polymers, and antioxidants, wherein:
X represents alternatively the residues of an aliphatic amino acid comprising from 8 to 18 carbon atoms, or a lactam, or the unit X 1 .X 2 which represents the residues resulting from the condensation of an aliphatic diamine comprising from 6 to 18 carbon atoms and a (cyclo)aliphatic dicarboxylic acid comprising from 6 to 18 carbon atoms;
10. T represents the residues from the condensation of a decane diamine and terephthalic acid;
Y represents the residues from the condensation of an aliphatic diamine comprising from 9 to 14 carbon atoms and an aromatic dicarboxylic acid, Y being different from the unit 10.T;
the molar proportion of units 10.T in the copolyamide is greater than 0%;
the molar proportion of the units Y relative to the total of units 10.T and Y is from 0% to 30%;
the proportion of units X is from 0.4 to 0.8 mol per mole of semi-aromatic units 10.T and Y; and
the vapor compression circuit element is suitable for transporting a heat transfer fluid selected from the group consisting of hydrocarbon, hydrofluorocarbon, ether, hydrofluoroether, and fluoroolefin compounds.

2. The heat transfer device as claimed in claim 1 , wherein the copolyamide is a copolyamide of formula X/10.T.

3. The heat transfer device as claimed in claim 1 , wherein X represents either the residues of an aliphatic amino acid comprising from 10 to 12 carbon atoms or the unit X 1 .X 2 which represents the residues resulting from the condensation of an aliphatic diamine comprising from 6 to 12 carbon atoms and an aliphatic diacid comprising from 6 to 12 carbon atoms.

4. The heat transfer device as claimed in claim 1 , wherein Y represents a unit 10.1, 9.T, 12.T, or 14.T.

5. The heat transfer device as claimed in claim 1 , wherein the copolyamide is selected from the group consisting of copolyamides of formulae 11/10.T, 12/10.T, 6.10/10.T, 6.12/10.T, 10.6/10.T, 10.10/10.T, 10.12/10.T, 12.12/10.T, and 10.14/10.T.

6. The heat transfer device as claimed in claim 1 , wherein the proportion of units X in the copolyamide is from 0.5 to 0.7 mol per mole of semi-aromatic units 10. T and Y.

7. The heat transfer device as claimed in claim 1 , wherein the vapor compression circuit element is an extruded article.

8. The heat transfer device as claimed in claim 1 , wherein the copolyamide is PA 11/10.T.

9. The heat transfer device as claimed in claim 1 , wherein the layer includes a functionalized polyolefin.

10. The heat transfer device as claimed in claim 9 , wherein the layer comprises 10% to 40% by weight of the functionalized polyolefin.

11. The heat transfer device as claimed in claim 9 , wherein the functionalized polyolefin is an alpha-olefin polymer comprising a reactive unit.

12. The heat transfer device as claimed in claim 11 , wherein the reactive unit is a carboxylic acid function, anhydride function, or an epoxy function.

Assignees

• Arkema France

Inventors

• Blondel Philippe
• Brule Benoît
• Gamache Eric
• Meurice Pierrat Estelle

Classifications

• B29C49/0005

  characterised by the material · CPC title

• B32B27/308 Primary

  comprising acrylic (co)polymers · CPC title

• F16L11/085 Primary

  comprising one or more braided layers (in combination with layers of a helically wound core or wire F16L11/088) · CPC title

• B32B27/38

  comprising epoxy resins · CPC title

• B32B5/026

  Knitted fabric · CPC title