Frangible degradable materials

Patent metadata

Field	Value
Publication number	US-11208868-B2
Application number	US-201415037616-A
Country	US
Kind code	B2
Filing date	Nov 18, 2014
Priority date	Nov 19, 2013
Publication date	Dec 28, 2021
Grant date	Dec 28, 2021

Abstract

A borehole tool can include a frangible degradable alloy that includes an oxidizable base element and at least one alloying element.

First claim

What is claimed is:

1. A borehole tool for use in a downhole environment comprising:
a frangible and dissolvable composite metallic material comprising:
a first granular alloy that is frangible, the first granular alloy comprising at least one selected from the group consisting of: a first aluminum alloy; a first magnesium alloy; and a titanium alloy, the first granular alloy being susceptible to stress corrosion cracking; and
a second granular alloy that is dissolvable, the second granular alloy comprising at least one selected from the group consisting of: a second aluminum alloy; and a second magnesium alloy, the second granular alloy being dissolvable in oilfield fluids, wherein the second granular alloy is different from the first granular alloy,
wherein dissolution of the second granular alloy causes the first granular alloy to further degrade into a plurality of smaller pieces.

2. The borehole tool of claim 1 ,
wherein the first granular alloy comprises the first aluminum alloy,
wherein the first aluminum alloy comprises aluminum oxide, and
wherein hydration of the aluminum oxide generates self-induced internal tensile stresses in the first granular alloy.

3. The borehole tool of claim 1 ,
wherein the second granular alloy comprises the second aluminum alloy, and
wherein the second aluminum alloy comprises gallium as an alloying element.

4. The borehole tool of claim 1 comprising a frac plug formed at least in part of the frangible and dissolvable composite metallic material.

5. The borehole tool of claim 1 comprising a seat formed at least in part of the frangible and dissolvable composite metallic material.

6. The borehole tool of claim 1 further comprising: an oxidizing agent.

7. The borehole tool of claim 6 wherein the oxidizing agent comprises ammonium perchlorate.

8. The borehole tool of claim 1 , wherein the first granular alloy comprises the first aluminum alloy, and wherein the second granular alloy comprises the second aluminum alloy.

9. The borehole tool of claim 8 wherein the first aluminum alloy comprises magnesium, copper, zinc and lithium as alloying elements.

10. The borehole tool of claim 8 wherein the second aluminum alloy comprises at least one selected from the group consisting of gallium, magnesium, calcium and lithium.

11. The borehole tool of clai 1 ,
wherein the first granular alloy comprises the first aluminum alloy, and
wherein the first aluminum alloy comprises a 7079 aluminum alloy.

12. The borehole tool of claim 1 ,
wherein the first granular alloy comprises the first aluminum alloy, and
wherein the first aluminum alloy comprises a 7075 aluminum alloy.

13. The borehole tool of claim 1 ,
wherein the first granular alloy comprises the first aluminum alloy, and
wherein the first aluminum alloy comprises composition ranges in weight percentages as follows: zinc 3.8 to 4.8, magnesium 2.9 to 3.7, copper 0.40 to 0.8, chromium 0.10 to 0.25, manganese 0.10 to 0.30, silicon to a maximum of 0.30, iron to a maximum of 0.40, titanium to a maximum of 0.10, impurities to a maximum of 0.15, and aluminum to balance.

14. The borehole tool of claim 1 ,
wherein the oilfield fluids are in a downhole corrosive environment,
wherein the dissolution of the second granular alloy causes the first granular alloy to further degrade into a plurality of smaller pieces by producing at least one of hydrogen and a corrosion byproduct, which increases a volume of the frangible and dissolvable composite metallic material, and causes the first granular alloy to fail at a stress level below a material-rated yield strength of the frangible and dissolvable composite metallic material.

15. The borehole tool of claim 1 ,
wherein the first granular alloy comprises the first aluminum alloy, and
wherein the first aluminum alloy has a Vickers hardness above 150.

16. A method comprising:
positioning a borehole tool in a downhole environment wherein the borehole tool comprises a frangible and dissolvable composite metallic material comprising:
a first granular alloy that is frangible, the first granular alloy comprising at least one selected from the group consisting of: a first aluminum alloy; a first magnesium alloy; and a titanium alloy, the first granular alloy being susceptible to stress corrosion cracking; and
a second granular alloy that is dissolvable, the second granular alloy comprising at least one selected from the group consisting of: a second aluminum alloy; and a second magnesium alloy, the second granular alloy being dissolvable in oilfield fluids, wherein the second granular alloy is different from the first granular alloy,
wherein the frangible and dissolvable composite metallic material comprises an age-hardenable material; and
prior to a predetermined age hardening time, dissolving the second granular alloy, which causes the first granular alloy to further degrade into a plurality of smaller pieces.

17. The method of claim 16 wherein the predetermined age hardening time corresponds to a reduction in susceptibility to stress corrosion cracking of the first granular alloy.

18. The method of claim 16 wherein the predetermined age hardening time depends on temperature in the downhole environment.

19. The method of claim 16 ,
wherein the borehole tool comprising the frangible and dissolvable composite metallic material is a plug,
wherein positioning the borehole tool in the downhole environment comprises dropping the plug from a surface location into a seat such that the plug seals against the seat,
wherein the method further comprises setting a packer before dissolving the second granular alloy of the plug.

20. A method, comprising:
processing a frangible and dissolvable composite metallic material to form a borehole tool, the frangible and dissolvable composite metallic material comprising: a first granular alloy that is frangible; and a second granular alloy that is dissolvable,
wherein the first granular alloy comprises at least one selected from the group consisting of: a first aluminum alloy; a first magnesium alloy; and a titanium alloy, the first granular alloy being susceptible to stress corrosion cracking,
wherein the second granular alloy comprising at least one selected from the group consisting of: a second aluminum alloy; and a second magnesium alloy, the second granular alloy being configured to dissolve in oilfield fluids,
wherein the second granular alloy is different from the first granular alloy, and
wherein the second granular alloy is configured to dissolve, causing the first granular alloy to further degrade into a plurality of smaller pieces.

21. The method of claim 20 , wherein the processing step comprises: mixing the first granular alloy with the second granular alloy.

22. The method of claim 20 , wherein the processing step comprises:
forming a body made of the first granular alloy, the body comprising a plurality of passages;
disposing the second granular alloy within the plurality of passages of the body; and
forming the body into the borehole tool.

Assignees

• Schlumberger Technology Corp

Inventors

• Marya Manuel P

Classifications

• E21B43/26

  by forming crevices or fractures · CPC title

• E21B33/12

  Packers; Plugs (used for cementing E21B33/134, E21B33/16) · CPC title

• E21B34/063 Primary

  Valve or closure with destructible element, e.g. frangible disc (E21B34/103 takes precedence) · CPC title

• C22C21/00

  Alloys based on aluminium · CPC title

• E21B33/13

  Methods or devices for cementing, for plugging holes, crevices or the like · CPC title