Method of manufacturing polycarbonate resin pellets

Patent metadata

Field	Value
Publication number	US-11208552-B2
Application number	US-201615776689-A
Country	US
Kind code	B2
Filing date	Nov 8, 2016
Priority date	Nov 20, 2015
Publication date	Dec 28, 2021
Grant date	Dec 28, 2021

Abstract

Provided is a method of producing a polycarbonate resin pellet containing a polycarbonate resin serving as a component (A), a silicone compound serving as a component (B), and an ester of an aliphatic carboxylic acid having 12 to 22 carbon atoms and glycerin serving as a component (C), the production method including a step including introducing a blend containing the component (A), the component (B), and the component (C) into an extruder, and melt-kneading the blend in the extruder under such a condition that a temperature of a molten resin at an outlet of the extruder is 260° C. or more and 325° C. or less, followed by extrusion molding to provide a polycarbonate resin pellet, the resultant polycarbonate resin pellet containing 0.01 part by mass or more and 0.25 part by mass or less of the component (B), and 0.015 part by mass or more and 0.25 part by mass or less of the component (C) with respect to 100 parts by mass of the component (A).

First claim

The invention claimed is:

1. A method of producing a polycarbonate resin pellet consisting of a polycarbonate resin serving as a component (A), a silicone compound serving as a component (B), an ester of an aliphatic carboxylic acid having 12 to 22 carbon atoms and glycerin serving as a component (C), an acrylic resin serving as an optional component (D), an antioxidant serving as an optional component (E), an alicyclic epoxy compound serving as an optional component (F), and an additive serving as an optional additive, the production method comprising a step including introducing a blend consisting of the component (A), the component (B) having a sodium content of 10 ppm by mass or less, the component (C), the optional component (D), the optional component (E), the optional component (F), and the optional additive into an extruder, and a water content in the blend is regulated by introducing 0.01 part by mass or more and 0.5 part by mass or less of water, and the water is supplied from a raw material-loading port of the extruder into the extruder, wherein the extruder has a vent,
and melt-kneading the blend in the extruder under such a condition that a temperature of a molten resin at an outlet of the extruder is 260° C. or more and 325° C. or less, and a vacuum degree at an outlet of the vent is −700 mmHg or less,
followed by extrusion molding to provide a polycarbonate resin pellet,
wherein the silicone compound serving as a component (B) is a polymer or copolymer formed of a structural unit represented by following formula:
(R 1 ) a (R 2 ) b SiO (4-a-b)/2
wherein: R1 represents at least one kind selected from the group consisting of a methoxy group and a vinyl group; R2 represents a methyl group, an ethyl group, or a phenyl group; and a and b each represent an integer satisfying 0<a≤3, 0≤b<3, and 0<a+b≤3,
and wherein the optional additive is at least one or more selected from the group consisting of a UV absorber, a flame retardant, a flame retardant aid, a light stabilizer, a plasticizer, an antistatic agent, an antiblocking agent, an antimicrobial agent, a compatibilizer, and a lubricant,

the resultant polycarbonate resin pellet containing 0.01 part by mass or more and 0.25 part by mass or less of the component (B), and 0.015 part by mass or more and 0.25 part by mass or less of the component (C) with respect to 100 parts by mass of the component (A).

2. The method of producing a polycarbonate resin pellet according to claim 1 , wherein a sodium content in the component (A) to be used in the blend is 200 ppb by mass or less.

3. The method of producing a polycarbonate resin pellet according to claim 1 , wherein a sodium content in the component (C) to be used in the blend is 2 ppm by mass or less.

4. The method of producing a polycarbonate resin pellet according to claim 1 , wherein the component (C) comprises an ester of stearic acid and glycerin.

5. The method of producing a polycarbonate resin pellet according to claim 4 , wherein the ester of stearic acid and glycerin comprises glycerin monostearate.

6. The method of producing a polycarbonate resin pellet according to claim 1 , wherein the component (A) comprises an aromatic polycarbonate resin.

7. The method of producing a polycarbonate resin pellet according to claim 1 , wherein the component (A) has a viscosity-average molecular weight of 9,000 or more and 30,000 or less.

8. The method of producing a polycarbonate resin pellet according to claim 1 , wherein the component (A) has a viscosity-average molecular weight of 10,000 or more and 20,000 or less.

9. The method of producing a polycarbonate resin pellet according to claim 1 , wherein a water content in the component (A) is 50 ppm by mass or more and 3,000 ppm by mass or less.

10. The method of producing a polycarbonate resin pellet according to claim 1 , wherein an electrical conductivity of the water to be used in the regulation of the water content in the blend measured at 25° C. is 1 μS/m or less.

11. The method of producing a polycarbonate resin pellet according to claim 1 , wherein the antioxidant as the component (E) is at least one selected from the group consisting of bis(2,6-di-tert-butylphenyl)pentaerythritol diphosphite and bis(2,4-dicumylphenyl)pentaerythritol diphosphite.

Assignees

• Idemitsu Kosan Co

Inventors

• Watanabe Nobuhiro

Classifications

• C08L83/04

  Polysiloxanes · CPC title

• C08L69/00 Primary

  Compositions of polycarbonates; Compositions of derivatives of polycarbonates · CPC title

• C08K5/103

  with polyalcohols · CPC title

• B29B9/06

  in the form of filamentary material, e.g. combined with extrusion · CPC title

• B29B7/94

  Liquid charges · CPC title