Polyvinyl alcohol composition and use thereof

Patent metadata

Field	Value
Publication number	US-11208550-B2
Application number	US-201716473773-A
Country	US
Kind code	B2
Filing date	Dec 27, 2017
Priority date	Dec 28, 2016
Publication date	Dec 28, 2021
Grant date	Dec 28, 2021

Abstract

There is provided a composition (C) comprising a modified PVA (A) and a compound (B), wherein the modified PVA (A) contains 0.01 mol % or more and less than 2 mol % of double bonds derived from an unsaturated carboxylic acid or a derivative thereof in side chains; the compound (B) is a compound having a conjugated double bond and two or more hydroxy groups bonded to the conjugated double bond, or a salt or oxide thereof; and a content of the compound (B) in the composition (C) is 0.001 parts by mass or more and less than 5 parts by mass based on 100 parts by mass of the modified PVA (A). The composition (C) has excellent hue, contains less insolubles in water, and has excellent water solubility.

First claim

The invention claimed is:

1. A composition (C), comprising:
a modified polyvinyl alcohol (A) and
a compound (B), wherein
the modified polyvinyl alcohol (A) comprises 0.01 mol % or more and less than 2 mol % of double bonds derived from an unsaturated carboxylic acid or a derivative thereof in side chains;
the compound (B) is a compound having a conjugated double bond and two or more hydroxy groups bonded to the conjugated double bond, or a salt or oxide thereof;
a content of the compound (B) in the composition (C) is 0.001 parts by mass or more and less than 5 parts by mass based on 100 parts by mass of the modified polyvinyl alcohol (A); and
the compound (B) is: (i) a compound having two or more hydroxy groups bonded to a carbon constituting an aromatic ring, or a salt or oxide thereof, wherein the compound comprises at least one selected from the group consisting of hydroxybenzenes, phenolic carboxylic acids, phenolic carboxylic acid esters and catechins, or (ii) a compound having two or more hydroxy groups at α- and β-positions in an α,β-unsaturated carbonyl compound, or a salt or oxide thereof.

2. The composition (C) according to claim 1 , wherein the modified polyvinyl alcohol (A) has a viscosity-average polymerization degree of 400 or more and less than 5000 and a saponification degree of 65 mol % or more.

3. The composition (C) according to claim 1 , wherein the modified polyvinyl alcohol (A) further comprises ethylene units in a main chain; and a content of the ethylene units is 1 mol % or more and 10 mol % or less.

4. The composition (C) according to claim 1 , wherein an amount of 1,2-glycol bond in the modified polyvinyl alcohol (A) is less than 1.9 mol %.

5. A method for producing the composition (C) according to claim 1 , the method comprising reacting a polyvinyl alcohol (D) with the unsaturated carboxylic acid or a derivative thereof in the presence of the compound (B).

6. A powder consisting of the composition (C) according to claim 1 , wherein a yellow index is less than 50.

7. A dispersion stabilizer, comprising the composition (C) according to claim 1 .

8. A method for producing a vinyl polymer, the method comprising:
suspension-polymerizing a vinyl compound in the presence of the composition (C) according to claim 1 and a polyvinyl alcohol (E), wherein
one of the modified polyvinyl alcohol (A) and the polyvinyl alcohol (E) is a polyvinyl alcohol with a saponification degree of 77 mol % or more and less than 97 mol % and a viscosity-average polymerization degree of 1500 or more and less than 5000, and
the other one of the modified polyvinyl alcohol (A) and the polyvinyl alcohol (E) is a polyvinyl alcohol with a saponification degree of 65 mol % or more and less than 77 mol % and a viscosity-average polymerization degree of 400 or more and less than 1500.

9. A coating agent consisting of an aqueous solution comprising the composition (C) according to claim 1 , and 200 parts by mass or more and 100,000 parts by mass or less of water based on 100 parts by mass of the modified polyvinyl alcohol (A).

10. A method for producing the coating agent according to claim 9 , the method comprising:
reacting a polyvinyl alcohol (D) with the unsaturated carboxylic acid or a derivative thereof in the presence of the compound (B) to provide the composition (C) comprising the modified polyvinyl alcohol (A) and the compound (B); and
dissolving the composition (C) in water to produce the coating agent.

11. The coating agent according to claim 9 , which is a coating agent for paper.

12. A base paper for release paper produced by coating a paper with the coating agent according to claim 11 .

13. A release paper comprising:
the base paper according to claim 12 , and
a release layer formed on a surface of the base paper.

14. The release paper according to claim 13 , wherein the release layer comprises an addition-type silicone (F) and platinum (G), and
the release layer comprises 0.001 parts by mass or more and 0.05 parts by mass or less of platinum (G) based on 100 parts by mass of the addition-type silicone (F).

15. A composition (C), comprising:
a modified polyvinyl alcohol (A) and
a compound (B), wherein
the modified polyvinyl alcohol (A) comprises 0.01 mol % or more and less than 2 mol % of double bonds derived from an unsaturated carboxylic acid or a derivative thereof in side chains;
the compound (B) is a compound having a conjugated double bond and two or more hydroxy groups bonded to the conjugated double bond, or a salt or oxide thereof;
a content of the compound (B) in the composition (C) is 0.001 parts by mass or more and less than 5 parts by mass based on 100 parts by mass of the modified polyvinyl alcohol (A); and
an amount of 1,2-glycol bond in the modified polyvinyl alcohol (A) is less than 1.9 mol %.

16. The composition (C) according to claim 15 , wherein the modified polyvinyl alcohol (A) has a viscosity-average polymerization degree of 400 or more and less than 5000 and a saponification degree of 65 mol % or more.

17. The composition (C) according to claim 15 , wherein the modified polyvinyl alcohol (A) further comprises ethylene units in a main chain; and a content of the ethylene units is 1 mol % or more and 10 mol % or less.

18. A powder consisting of the composition (C) according to claim 15 , wherein a yellow index is less than 50.

19. A powder, comprising:
a modified polyvinyl alcohol (A) and
a compound (B), wherein
the modified polyvinyl alcohol (A) comprises 0.01 mol % or more and less than 2 mol % of double bonds derived from an unsaturated carboxylic acid or a derivative thereof in side chains;
the compound (B) is a compound having a conjugated double bond and two or more hydroxy groups bonded to the conjugated double bond, or a salt or oxide thereof;
a content of the compound (B) in the powder is 0.001 parts by mass or more and less than 5 parts by mass based on 100 parts by mass of the modified polyvinyl alcohol (A); and
a yellow index of the powder is less than 50.

20. The powder according to claim 19 , wherein the modified polyvinyl alcohol (A) has a viscosity-average polymerization degree of 400 or more and less than 5000 and a saponification degree of 65 mol % or more.

Assignees

• Kuraray Co

Inventors

• Fukuhara Tadahito
• Morikawa Keisuke
• Kaharu Taeko

Classifications

• C08F2/20

  with the aid of macromolecular dispersing agents · CPC title

• D21H27/001

  Release paper · CPC title

• D21H19/60

  Polyalkenylalcohols; Polyalkenylethers; Polyalkenylesters · CPC title

• C08K5/053

  Polyhydroxylic alcohols · CPC title

• C08L29/04 Primary

  Polyvinyl alcohol; Partially hydrolysed homopolymers or copolymers of esters of unsaturated alcohols with saturated carboxylic acids · CPC title