Expanded thermoplastic polyurethane particles and expanded thermoplastic polyurethane particle molded article

US11208537B2 · US · B2

Patent metadata
FieldValue
Publication numberUS-11208537-B2
Application numberUS-201716463755-A
CountryUS
Kind codeB2
Filing dateNov 15, 2017
Priority dateNov 28, 2016
Publication dateDec 28, 2021
Grant dateDec 28, 2021

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  1. Title

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  2. Abstract

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  3. Assignees and inventors

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  4. Key dates

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  5. First independent claim

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  6. CPC / IPC classifications

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  7. Citations and related patents

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Abstract

Official abstract text for this publication.

The present invention provides expanded beads of thermoplastic polyurethane, wherein the thermoplastic polyurethane constituting the expanded beads is an ether-based thermoplastic polyurethane, and a difference (T1−T2) between a melting peak temperature (T1) and a melting peak temperature (T2) is from 0 to 8° C., wherein the melting peak temperature (T1) is a melting peak temperature at the time of first heating in a DSC curve obtained by heating the expanded beads from 20° C. to 260° C. at a heating rate of 10° C./min, the melting peak temperature (T2) is a melting peak temperature at the time of second heating in a DSC curve obtained by cooling from 260° C. to 20° C. at a cooling rate of 10° C./min after the first heating and further heating again from 20° C. to 260° C. at a heating rate of 10° C./min, and the DSC curves are obtained by the heat flux differential scanning calorimetry in conformity with JIS K7121-1987. The expanded beads of thermoplastic polyurethane not only have excellent surface appearance and fusion bonding properties but also have a low shrinkage factor.

First claim

Opening claim text (preview).

The invention claimed is: 1. Expanded beads of thermoplastic polyurethane, wherein the thermoplastic polyurethane constituting the expanded beads is an ether-based thermoplastic polyurethane, and a difference (T 1 −T 2 ) between a melting peak temperature (T 1 ) and a melting peak temperature (T 2 ) is from 0 to 8° C., wherein the melting peak temperature (T 1 ) is a melting peak temperature at the time of first heating in a DSC curve obtained by heating the expanded beads from 20° C. to 260° C. at a heating rate of 10° C./min, the melting peak temperature (T 2 ) is a melting peak temperature at the time of second heating in a DSC curve obtained by cooling from 260° C. to 20° C. at a cooling rate of 10° C./min after the first heating and further heating again from 20° C. to 260° C. at a heating rate of 10° C./min, and the DSC curves are obtained by the heat flux differential scanning calorimetry in conformity with JIS K7121-1987, wherein a type A durometer hardness of the thermoplastic polyurethane is 85 to 90, and wherein an average cell diameter of the expanded beads is 100 μm to 400 μm. 2. The expanded beads of thermoplastic polyurethane according to claim 1 , wherein the difference (T 1 −T 2 ) between the melting peak temperature (T 1 ) at the time of first heating and the melting peak temperature (T 2 ) at the time of second heating is from 1 to 6° C. 3. The expanded beads of thermoplastic polyurethane according to claim 1 , wherein the melting peak temperature (T 2 ) at the time of second heating is from 155 to 170° C. 4. The expanded beads of thermoplastic polyurethane according to claim 1 , wherein a melt flow rate at 190° C. under a load of 10 kg of the expanded beads is from 18 to 35 g/10 min. 5. The expanded beads of thermoplastic polyurethane according to claim 1 , wherein an apparent density of the expanded beads is from 80 to 300 kg/m 3 . 6. An expanded thermoplastic polyurethane beads molded article obtained through in-mold molding of the expanded beads of thermoplastic polyurethane according to claim 1 . 7. The expanded beads of thermoplastic polyurethane according to claim 1 , wherein the thermoplastic polyurethane consists essentially of the ether-based thermoplastic polyurethane. 8. The expanded beads of thermoplastic polyurethane according to claim 1 , wherein the average cell diameter of the expanded beads is 150 μm to 400 μm.

Assignees

Inventors

Classifications

  • C08J9/122Primary

    Hydrogen, oxygen, CO2, nitrogen or noble gases · CPC title

  • Expandable microspheres, e.g. Expancel® · CPC title

  • CO2, N2 or noble gases · CPC title

  • C08J9/232Primary

    by sintering expandable particles · CPC title

  • from polyethers · CPC title

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What does patent US11208537B2 cover?
The present invention provides expanded beads of thermoplastic polyurethane, wherein the thermoplastic polyurethane constituting the expanded beads is an ether-based thermoplastic polyurethane, and a difference (T1−T2) between a melting peak temperature (T1) and a melting peak temperature (T2) is from 0 to 8° C., wherein the melting peak temperature (T1) is a melting peak temperature at the tim…
Who is the assignee on this patent?
Jsp Corp
What technology area does this patent fall under?
Primary CPC classification C08J9/122. Mapped technology areas include Chemistry & Metallurgy.
When was this patent published?
Publication date Tue Dec 28 2021 00:00:00 GMT+0000 (Coordinated Universal Time) (B2). Legal status and post-grant events are not shown on this page.
What related patents are in patentsdb?
We list 6 related publications on this page (citations in our corpus or others sharing the same primary CPC).