Oxidative coupling of methane implementations for olefin production

Patent metadata

Field	Value
Publication number	US-11208364-B2
Application number	US-202017089953-A
Country	US
Kind code	B2
Filing date	Nov 5, 2020
Priority date	Jan 9, 2014
Publication date	Dec 28, 2021
Grant date	Dec 28, 2021

Abstract

The present disclosure provides oxidative coupling of methane (OCM) systems for small scale and world scale production of olefins. An OCM system may comprise an OCM subsystem that generates a product stream comprising C 2+ compounds and non-C 2+ impurities from methane and an oxidizing agent. At least one separations subsystem downstream of, and fluidically coupled to, the OCM subsystem can be used to separate the non-C 2+ impurities from the C 2+ compounds. A methanation subsystem downstream and fluidically coupled to the OCM subsystem can be used to react H 2 with CO and/or CO 2 in the non-C 2+ impurities to generate methane, which can be recycled to the OCM subsystem. The OCM system can be integrated in a non-OCM system, such as a natural gas liquids system or an existing ethylene cracker.

First claim

What is claimed is:

1. A method for producing hydrocarbon compounds including two or more carbon atoms (C 2+ compounds), the method comprising:
(a) performing an oxidative coupling of methane (OCM) reaction in an OCM reactor to produce an OCM effluent stream comprising carbon dioxide (CO 2 ), carbon monoxide (CO), hydrogen (H 2 ), one or more C 2+ compounds, and methane (CH 4 );
(b) separating the OCM effluent stream into a first stream comprising at least some of the one or more C 2+ compounds and a second stream comprising CO, CO 2 , H 2 , and CH 4 ;
(c) separating the second stream in a pressure swing adsorption (PSA) unit to produce an OCM reactor feed comprising CH 4 and a third stream comprising H 2 and CO and/or CO 2 ; and
(d) directing the OCM reactor feed to the OCM reactor.

2. The method of claim 1 , further comprising, prior to step (b), directing the OCM effluent stream to a post-bed cracking unit to generate olefins from alkanes in the OCM effluent.

3. The method of claim 2 , further comprising directing a fourth stream comprising ethane to the post-bed cracking unit.

4. The method of claim 1 , further comprising directing the third stream to a methanation reactor to produce a second OCM reactor feed comprising CH 4 formed from the H 2 and CO and/or CO 2 in the third stream, and directing the second OCM reactor feed to the OCM reactor.

5. The method of claim 1 , further comprising directing the OCM effluent stream and a natural gas feed stream comprising CH 4 to a process gas compressor unit that is downstream of the OCM reactor.

6. The method of claim 5 , further comprising directing the natural gas feed stream to a sulfur removal unit prior to directing the natural gas feed stream to the process gas compressor.

7. The method of claim 1 , further comprising directing an ethane feed stream and an oxidant feed stream to the OCM reactor.

8. A method for producing hydrocarbon compounds including two or more carbon atoms (C 2+ compounds), the method comprising:
(a) performing an oxidative coupling of methane (OCM) reaction in an OCM reactor to produce an OCM effluent stream comprising carbon dioxide (CO 2 ), carbon monoxide (CO), hydrogen (H 2 ), one or more C 2+ compounds, and methane (CH 4 );
(b) separating the OCM effluent stream in a pressure swing adsorption (PSA) unit into a first stream comprising at least some of the one or more C 2+ compounds and CL and a second stream comprising CO, CO 2 , and H 2 ;
(c) separating the first stream in a demethanizer unit to produce an OCM reactor feed comprising CH 4 and a third stream comprising the at least some of the one or more C 2+ compounds; and
(d) directing the OCM reactor feed to the OCM reactor.

9. The method of claim 8 , further comprising, prior to step (b), directing the OCM effluent stream to a post-bed cracking unit to generate olefins from alkanes in the OCM effluent.

10. The method of claim 9 , further comprising directing a fourth stream comprising ethane to the post-bed cracking unit.

11. The method of claim 8 , further comprising directing the second stream to a methanation reactor to produce a second OCM reactor feed comprising CH 4 formed from the CO, CO 2 , and H 2 in the second stream, and directing the second OCM reactor feed to the OCM reactor.

12. The method of claim 8 , further comprising directing the OCM effluent stream and a natural gas feed stream comprising CH 4 to a process gas compressor unit that is downstream of the OCM reactor and upstream of the PSA unit.

13. The method of claim 8 , further comprising directing an ethane feed stream and an oxidant feed stream to the OCM reactor.

14. A method for producing hydrocarbon compounds including two or more carbon atoms (C 2+ compounds), the method comprising:
(a) performing an oxidative coupling of methane (OCM) reaction in an OCM reactor to produce an OCM effluent stream comprising carbon dioxide (CO 2 ), carbon monoxide (CO), hydrogen (H 2 ), one or more C 2+ compounds, and methane (CH 4 );
(b) separating the OCM effluent stream in a pressure swing adsorption (PSA) unit into a first stream comprising CH 4 and a second stream comprising at least some of the one or more C 2+ compounds, CO, CO 2 , and H 2 ;
(c) separating the second stream to produce a third stream comprising the at least some of the one or more C 2+ compounds and a fourth stream comprising carbon monoxide CO, CO 2 , and H 2 , and
(d) directing the first stream to the OCM reactor.

15. The method of claim 14 , further comprising, prior to step (b), directing the OCM effluent stream to a post-bed cracking unit to generate olefins from alkanes in the OCM effluent.

16. The method of claim 15 , further comprising directing a fifth stream comprising ethane to the post-bed cracking unit.

17. The method of claim 14 , further comprising directing the fourth stream to a methanation reactor to produce a second OCM reactor feed comprising CH 4 formed from the CO, CO 2 , and H 2 in the fourth stream, and directing the second OCM reactor feed to the OCM reactor.

18. The method of claim 14 , further comprising directing the OCM effluent stream and a natural gas feed stream comprising CH 4 to a process gas compressor unit that is downstream of the OCM reactor and upstream of the PSA unit.

19. The method of claim 14 , further comprising directing an ethane feed stream and an oxidant feed stream to the OCM reactor.

Assignees

• Lummus Technology Inc

Inventors

• Rafique Humera A
• Vuddagiri Srinivas
• Radaelli Guido
• Scher Erik C
• Mccormick Jarod
• Cizeron Joel

Classifications

• B01J35/45

  Nanoparticles · CPC title

• F25J2270/06

  with multiple gas expansion loops · CPC title

• F25J2270/04

  Internal refrigeration with work-producing gas expansion loop · CPC title

• F25J2240/02

  Expansion of a process fluid in a work-extracting turbine (i.e. isentropic expansion), e.g. of the feed stream · CPC title

• F25J2230/08

  Cold compressor, i.e. suction of the gas at cryogenic temperature and generally without afterstage-cooler · CPC title