System and method for power production including methanation

Patent metadata

Field	Value
Publication number	US-11208323-B2
Application number	US-202016828758-A
Country	US
Kind code	B2
Filing date	Mar 24, 2020
Priority date	Feb 18, 2016
Publication date	Dec 28, 2021
Grant date	Dec 28, 2021

Abstract

The present disclosure relates to a power production system that is adapted to achieve high efficiency power production with carbon capture when using a solid or liquid hydrocarbon or carbonaceous fuel. More particularly, the solid or liquid fuel first is partially oxidized in a partial oxidation reactor that is configured to provide an output stream that is enriched in methane content. The resulting partially oxidized stream can be cooled, filtered, additionally cooled, and then directed to a combustor of a power production system as the combustion fuel. The partially oxidized stream is combined with a compressed recycle CO2 stream and oxygen. The combustion stream is expanded across a turbine to produce power and passed through a recuperator heat exchanger. The recycle CO2 stream is compressed and passed through the recuperator heat exchanger and optionally the POX heat exchanger in a manner useful to provide increased efficiency to the combined systems.

First claim

The invention claimed is:

1. A combined partial oxidation (PDX) system and power production system (PPS) comprising:
a catalytic PDX reactor adapted to partially oxidize a liquid or solid fuel in the presence of oxygen, a catalyst, and optionally steam to form a PDX stream comprising methane;
one or more components adapted to cool the PDX stream;
a particle filter and a water scrubber downstream from the one or more components adapted to cool the PDX stream and configured to separate one more of solids, molten metals, and acid gases from the PDX stream and provide a cleaned PDX stream, wherein the solids separated from the PDX stream comprise one or more of ash particles, unreacted char, and catalyst;
a splitter arranged to split the cleaned PDX stream into a first fraction stream and a second fraction stream;
a catalytic water gas shift reactor arranged to receive and process the first fraction stream;
a carbonyl sulfide (COS) hydrolysis reactor arranged to receive and process the second fraction stream;
a POX heat exchanger arranged to receive the first fraction stream from the catalytic water gas shift reactor and receive the second fraction stream from the COS hydrolysis reactor and adapted to withdraw heat therefrom and output a cooled POX fuel gas;
a compressor arranged to receive the cooled POX fuel gas and provide a compressed POX fuel gas at a pressure of about 10 MPa or greater;
a PPS combustor adapted to combust the compressed POX fuel gas in the presence of oxygen and a compressed recycle CO 2 stream and form a PPS combustion product stream at a pressure of about 10 MPa or greater;
a turbine adapted to expand the PPS combustion product stream to provide an expanded PDX combustion product stream and generate power in a connected generator;
a recuperator heat exchanger adapted to withdraw heat from the expanded PPS combustion product stream and add the heat to the compressed recycle CO 2 stream;
a PPS compressor adapted to compress the recycle CO 2 stream to a pressure of about 10 MPa or greater and form the compressed recycle CO 2 stream;
optional flow components adapted to direct a portion of the compressed recycle CO 2 stream to the POX heat exchanger;
optional flow components adapted to direct a portion of the compressed recycle CO 2 stream to the PPS recuperator heat exchanger; and
optional flow components adapted to direct the compressed recycle CO 2 stream from the PDX heat exchanger to the PPS recuperator heat exchanger.

2. The system of claim 1 , wherein the catalyst used in the POX reactor is selected from the group consisting of alkali metals, alkaline earth metals, transition metals, compounds thereof, complexes thereof, and combinations thereof.

3. The system of claim 1 , wherein the PDX reactor is operated at a temperature of about 1000° C. or less.

4. The system of claim 1 , wherein the catalytic POX reactor is adapted to partially oxidize the liquid or solid fuel in the presence of oxygen, the catalyst, and steam to form the PDX stream comprising methane.

5. The system of claim 1 , further comprising a convective cooler arranged to receive the POX stream from the POX reactor and through which the POX stream is passed through against a cooling stream and thereby cooled.

6. The system of claim 5 , wherein the cooling stream comprises one or more of:
a high pressure recycle fluid stream withdrawn from and returned to the PPS;
a high pressure water stream;
a nitrogen stream;
a stream of POX reactor liquid fuel feed;
a high pressure stream of O 2 and CO 2 ; and
a stream of cleaned and cooled POX fuel gas.

7. The system of claim 1 , wherein the first fraction stream exiting the catalytic water gas shift reactor has an H 2 to CO ratio of about 5:1 to about 1:1.

8. The system of claim 1 , wherein the POX heat exchanger arranged to receive a cooling stream comprising one or more of:
a high pressure recycle fluid stream withdrawn from and returned to the PPS;
a high pressure water stream;
a nitrogen stream;
a stream of POX reactor liquid fuel feed;
a high pressure stream of O 2 and CO 2 ; and
a stream of cleaned and cooled POX fuel gas.

9. The system of claim 1 , further comprising one or both of a mercury removal unit and an acid gas removal unit arranged upstream from the compressor and downstream from the POX heat exchanger, the one or both of a mercury removal unit and an acid gas removal unit being configured to receive at least a portion of the cooled POX fuel gas stream and pass it therethrough.

10. The system of claim 9 , further comprising an activated, sulfur-impregnated, carbon bed adsorption system configured to receive at least a portion of the POX fuel gas stream and remove mercury from the cooled POX fuel gas.

11. The system of claim 9 , further comprising an acid gas removal unit configured to receive at least a portion of the cooled POX fuel gas stream and remove part or substantially all of at least one of H 2 S and CO 2 from the cooled POX fuel gas stream.

12. The system of claim 1 , further comprising a methanation unit arranged upstream from the compressor and downstream from the POX heat exchanger, the methanation unit being configured to receive at least a portion of the cooled POX fuel gas stream and convert CO and H 2 to CH 4 and H 2 O.

13. The system of claim 12 , wherein the methanation unit is a catalytic unit, and optionally wherein methanation is carried out using a nickel-based catalyst.

14. The system of claim 12 , wherein the POX fuel gas exiting the methanation unit has a methane content of about 50% or greater by volume.

15. The system of claim 12 , further comprising a post-methanation heat exchanger, wherein the POX fuel gas exiting the methanation unit is passed through the post-methanation heat exchanger against a cooling stream, optionally wherein the cooling stream comprises one or more of: a high pressure recycle fluid stream withdrawn from and returned to the PPS; a high pressure water stream; a nitrogen stream; a high pressure stream of 0 2 and CO 2 ; a stream of POX reactor liquid fuel feed; and a stream of cleaned and cooled POX fuel gas.

16. The system of claim 12 , further comprising a separator configured to receive the POX fuel gas stream from the methanation unit, wherein at least a portion of any water produced in the methanation reactor is removed.

17. The system of claim 1 , wherein the compressed POX fuel gas is heated by passage through the POX heat exchanger after the cooled POX fuel gas is compressed by the compressor and before the compressed POX fuel gas is combusted in the PPS combustor.

18. The system of claim 1 , further comprising:
a PPS recuperator heat exchanger configured to receive the expanded PPS combustion product stream and thereby withdraw heat from the PPS combustion product stream and form a cooled PPS combustion product stream;
an optional water cooler configured to receive the cooled PPS combustion product stream and pass the cooled PPS combustion product stream therethrough;
a PPS scrubber configured to treat the cooled PPS combustion product stream to form a recycle CO 2 stream by removing substantially all non-CO 2 components; and
a PPS compressor configured to pressurize the recycle CO 2 stream to form a compressed recycle CO 2 stream.

Assignees

• 8 Rivers Capital Llc

Inventors

• Forrest Brock Alan
• Lu Xijia

Classifications

• C10K1/20

  by treating with solids; Regenerating spent purifying masses {(separation by adsorption B01D53/02; separation by chemical reaction B01D53/34; refining of hydrocarbon oils with acids C10G17/02, C10G27/02, C10G29/12)} · CPC title

• C10J2300/1653

  integrated in a gasification combined cycle [IGCC] · CPC title

• C10J3/82

  Gas withdrawal means · CPC title

• C01B2203/0261

  containing a catalytic partial oxidation step [CPO] · CPC title

• F02C3/22

  the fuel or oxidant being gaseous at standard temperature and pressure (F02C3/28 takes precedence) · CPC title