Fine particles, particle group, anti-counterfeiting ink, anti-counterfeiting toner, anti-counterfeiting sheet, and anti-counterfeiting medium
US-9223235-B2 · Dec 29, 2015 · US
US11207910B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-11207910-B2 |
| Application number | US-201816651085-A |
| Country | US |
| Kind code | B2 |
| Filing date | Sep 27, 2018 |
| Priority date | Sep 29, 2017 |
| Publication date | Dec 28, 2021 |
| Grant date | Dec 28, 2021 |
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Official abstract text for this publication.
A method of forming a security device includes selectively providing a high refractive index (HRI) layer to a first outwardly facing surface of a security device substrate, the HRI layer having a substantially transparent host material and particles having a dimension along at least one axis less than 200 nm, such that they are substantially non-scattering to visible light and the HRI layer is substantially transparent to visible light, and wherein; the particles have a refractive index of at least 1.8 and are present within the host material in a proportion such that the resultant refractive index of the HRI layer is at least 1.6. A corresponding security device, as well as security articles and security documents, are also disclosed.
Opening claim text (preview).
The invention claimed is: 1. A method of forming a security device, the method comprising: selectively providing a high refractive index (HRI) layer to a first outwardly facing surface of a security device substrate, the HRI layer comprising a substantially transparent host material and particles having a dimension along at least one axis less than 200 nm, such that the particles are substantially non-scattering to visible light and the HRI layer is substantially transparent to visible light; wherein the particles have a refractive index of at least 1.8 and are present within the host material in a proportion such that a resultant refractive index of the HRI layer is at least 1.6, and wherein the first outwardly facing surface of the security device substrate comprises a surface relief structure, and the HRI layer is selectively provided to the surface relief structure. 2. The method of claim 1 , wherein the particles comprise at least one metal oxide selected from: titanium dioxide, alumina, zirconia, zinc oxide, or mixed oxides thereof. 3. The method of claim 1 , wherein the resultant refractive index of the HRI layer is in a range of 1.6 to 2.5. 4. The method of claim 1 , wherein the selectively providing the HRI layer is performed by a printing process. 5. The method of claim 4 , wherein the printing process is one of inkjet printing, flexographic printing or gravure printing. 6. The method of claim 1 , wherein the HRI layer further comprises a colorant such that the HRI layer exhibits a first color to a viewer. 7. The method of claim 1 , wherein the HRI layer further comprises a dispersion of scattering particles having a dimension along at least one axis such that the HRI layer exhibits a first color when viewed in reflection and a second, different color when viewed in transmission. 8. The method of claim 7 , wherein the scattering particles of the dispersion have a dimension D along at least one axis substantially according to D= 2λ/π( n 1 −n 2 ); wherein λ is a wavelength of light incident on the HRI layer, n 1 is a refractive index of the particles and n 2 is a refractive index of the host material. 9. The method of claim 1 , further comprising selectively providing an optical effect layer to the HRI layer. 10. The method of claim 9 , wherein the optical effect layer comprises a colorant such that the optical effect layer exhibits a first color to a viewer, or wherein the optical effect layer comprises a dispersion of scattering particles having a dimension along at least one axis such that the optical effect layer exhibits a first color when viewed in reflection, and a second, different color when viewed in transmission. 11. The method of claim 1 , wherein the surface relief structure is a diffractive surface relief structure. 12. The method of claim 11 , wherein the diffractive surface relief structure is a hologram surface relief or a diffraction grating. 13. The method of claim 1 , wherein the surface relief structure comprises at least one refractive structure, and the HRI layer is selectively provided to said at least one refractive structure. 14. The method of claim 13 , wherein the at least one refractive structure is a lens or microprism. 15. The method of claim 1 , wherein the HRI layer is selectively provided so as to define indicia. 16. The method of claim 1 , wherein the security device substrate comprises one of a security thread, strip, patch, label, transfer foil, paper substrate or a polymer substrate. 17. A method of manufacturing a plurality of security devices, wherein each security device is manufactured according to the method of claim 1 and wherein the HRI layer is selectively provided in a different form for at least two of the plurality of security devices. 18. The method of claim 1 , wherein the particles have a dimension along at least one axis less than 100 nm. 19. A method of manufacturing a plurality of security documents, the method of manufacturing each document comprising the steps of: providing a security document substrate comprising a diffractive or refractive surface relief structure, and; selectively providing a high refractive index (HRI) layer to said diffractive or refractive surface relief structure, the HRI layer comprising a substantially transparent host material and particles having a dimension along at least one axis less than 200 nm, such that the particles are substantially non-scattering to visible light and the HRI layer is substantially transparent to visible light; wherein the particles have a refractive index of at least 1.8 and are present within the host material in a proportion such that a resultant refractive index of the HRI layer is at least 1.6, and wherein the HRI layer is provided in a different form for at least two of the plurality of security documents. 20. A security device comprising: a security device substrate having a first outwardly facing surface; a high refractive index (HRI) layer selectively provided to said first outwardly facing surface, wherein the HRI layer comprises a substantially transparent host material and particles having a dimension along at least one axis less than 200 nm, such that the particle are substantially non-scattering to visible light and the HRI layer is substantially transparent to visible light; wherein the particles have a refractive index of at least 1.8 and are present within the host material in a proportion such that a resultant refractive index of the HRI layer is at least 1.6, and wherein the first outwardly facing surface of the security device substrate comprises a surface relief structure, and the HRI layer is selectively provided to said surface relief structure.
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