Glass ionomer compositions and methods including inorganic fibers

Patent metadata

Field	Value
Publication number	US-11207246-B2
Application number	US-201816485952-A
Country	US
Kind code	B2
Filing date	Mar 2, 2018
Priority date	Mar 15, 2017
Publication date	Dec 28, 2021
Grant date	Dec 28, 2021

Abstract

Disclosed herein are curable glass ionomer compositions that include a first paste and a second paste, and methods for using the disclosed compositions. The first paste includes water, a polyacid, and a non acid-reactive filler. The second paste includes water and an acid-reactive filler. At least one of the first paste and the second paste further includes substantially crystalline inorganic fibers. In some embodiments, the water content of the first paste and the second paste of the paste/paste GI composition disclosed herein is less than 20% by weight, based on the total weight of the composition.

First claim

What is claimed is:

1. A curable glass ionomer composition comprising:
a first paste comprising:
water,
a polyacid, and
a non acid-reactive filler;

a second paste comprising:
water, and
an acid-reactive filler; and

crystalline inorganic fibers having a crystallinity index of at least 0.05 as measured by the XRD Crystallinity Index Test Method,
wherein at least one of the first paste and the second paste comprises the crystalline inorganic fibers.

2. The composition claim 1 , further comprising a resin in an amount less than 5 wt % with respect to the weight of the composition.

3. The composition of claim 1 , wherein a combined water content between the first paste and the second paste is less than 20% by weight, based on the total weight of the composition.

4. A curable glass ionomer composition comprising:
a first paste comprising:
water,
a polyacid, and
a non acid-reactive filler; and

a second paste comprising:
water, and
an acid-reactive filler; and

crystalline inorganic fibers having a crystallinity index of at least 0.05 as measured by the XRD Crystallinity Index Test Method,
wherein at least one of the first paste and the second paste comprises the crystalline inorganic fibers, and
wherein a combined water content between the first paste and the second paste is less than 20% by weight, based on the total weight of the composition.

5. The composition of claim 4 , wherein the water content of the first paste is less than 20% by weight, based on the total weight of the first paste; and the water content of the second paste is less than 20% by weight, based on the total weight of the second paste.

6. The composition of claim 4 , wherein the composition comprises 10% by weight to 15% by weight of the crystalline inorganic fibers, based on the total weight of the composition.

7. The composition of claim 4 , wherein the crystalline inorganic fibers comprise one or more of ceramics and metal oxides.

8. The composition of claim 4 , wherein the crystalline inorganic fibers have a crystallinity index of at least 0.1 as measured by the XRD Crystallinity Index Test Method.

9. The composition of claim 4 , wherein the crystalline inorganic fibers as contained in the pastes have an average diameter of at least 3 micrometers.

10. The composition of claim 4 , wherein the crystalline inorganic fibers have an average aspect ratio of about 10:1.

11. The composition of claim 4 , wherein the crystalline inorganic fibers have an average diameter of 3 to 25 micrometers and an average length of 25 micrometers to 1 mm.

12. The composition of claim 4 , wherein the non acid-reactive filler is selected from the group consisting of quartz, nitrides, kaolin, borosilicate glass, strontium oxide based glass, barium oxide based glass, silica, alumina, titania, and zirconia, or combinations thereof.

13. The composition of claim 4 , wherein the non acid-reactive filler comprises a metal oxide selected from the group consisting of alumina, silica, zirconia, and titania, or combinations thereof.

14. The composition of claim 4 , wherein the acid-reactive filler comprises an inorganic filler selected from the group consisting of basic metal oxides, metal hydroxides, hydroxyapatite, aluminosilicate glasses, fluoroaluminosilicate glasses, and glasses having a Si/Al weight percent ratio less than 1.5, or combinations thereof.

15. The composition of claim 4 , wherein the acid-reactive filler has a mean particle size of 3 micrometers to 10 micrometers.

16. The composition of claim 4 , wherein the first paste further comprises a complexing agent.

17. A method of preparing a cured composition, the method comprising:
providing a curable glass ionomer composition of claim 1 ;
combining the first paste and the second paste to form a mixture; and
allowing the mixture to cure to form the cured composition.

18. A device for storing a composition, the device comprising:
a first compartment, and
a second compartment;
the composition comprising:
a first paste comprising:
water,
a polyacid, and
a non acid-reactive filler; and

a second paste comprising:
water, and
an acid-reactive filler; and

crystalline inorganic fibers having a crystallinity index of at least 0.05 as measured by the XRD Crystallinity Index Test Method,
wherein at least one of the first paste and the second paste comprises the crystalline inorganic fibers, and
wherein a combined water content between the first paste and the second paste is less than 20% by weight, based on the total weight of the composition;

wherein:
the first compartment contains the first paste, and
the second compartment contains the second paste.

19. The device of claim 18 , wherein the first compartment and the second compartment independently comprise a nozzle or an interface for receiving a static mixing tip.

Assignees

• 3M Innovative Properties Co

Inventors

• Agre Mark B
• Craig Bradley D
• Jahns Michael
• Chiu William V

Classifications

• A61K6/17 Primary

  Particle size · CPC title

• A61K6/889 Primary

  Polycarboxylate cements; Glass ionomer cements · CPC title