Method for tuning work function using surface photovoltage and producing ultra-low-work-function surfaces, and devices operational therewith

Patent metadata

Field	Value
Publication number	US-11205554-B1
Application number	US-201414333431-A
Country	US
Kind code	B1
Filing date	Jul 16, 2014
Priority date	Jul 16, 2013
Publication date	Dec 21, 2021
Grant date	Dec 21, 2021

Abstract

The embodiments provide a thermionic emission device and a method for tuning a work function in a thermionic emission device is provided. The method includes illuminating an N type semiconductor material of a first member of a thermionic emission device, wherein a work function of the N type semiconductor material is lowered by the illuminating. The method includes collecting, on one of the first member or a second member of the thermionic emission device, electrons emitted from one of the first member or the second member.

First claim

What is claimed is:

1. A thermionic emission device, comprising:
a first member and a second member supported in the device with a gap between the first member and the second member;
the first member comprising an N type semiconductor material;
an illumination member arranged to illuminate or direct illumination, from a source external to the second member, to a surface of the first member, the illumination member providing light that has energy greater than a bandgap of the N type semiconductor material, wherein a work function of the N type semiconductor material is decreased as a result of such illumination of the surface of the first member; and
the device arranging the second member to one of: collect electrons that are emitted by the first member having such illumination and travel across the gap to the second member, or emit electrons that travel across the gap and are collected by the first member having such illumination.

2. The thermionic emission device of claim 1 , further comprising:
a heating member arranged to heat the second member, wherein the second member includes a cathode or emitter, wherein the first member includes an anode or a collector; and
the first member and the second member configured to couple to a load or a device and to provide power from thermionic energy conversion.

3. The thermionic emission device of claim 1 , further comprising:
a voltage supply coupled to the first member and the second member, the voltage supply arranged to apply a positive voltage to the second member relative to the first member, wherein the first member includes an emitter, wherein the second member includes a collector; and
the first member configured to couple to a device and to provide refrigeration.

4. The thermionic emission device of claim 1 , further comprising:
the second member having a P type semiconductor material; and
a light source configured to illuminate the P type semiconductor material of the second member, wherein the second member is configured to produce photon enhanced thermionic emission (PETE) as a result of the P type semiconductor material being illuminated.

5. The thermionic emission device of claim 1 , further comprising:
the illumination member comprising at least one of a mirror or a lens, arranged to direct sunlight onto the second member and direct concentrated sunlight onto the first member.

6. The thermionic emission device of claim 1 , further comprising at least one from a set consisting of:
a coating on at least one of the first member or the second member; and
a surface texture, including spikes, points, or roughness, on at least one of the first member or the second member.

7. A thermionic emission device, comprising:
a device having a first member, a second member, and a gap between the first member and the second member;
an illumination member;
the device arranging the illumination member to illuminate or direct illumination from a source external to the second member to the first member, the first member comprising an N type semiconductor material, the illumination member providing light having energy greater than a bandgap of the N type semiconductor material to lower a work function of the N type semiconductor material; and
the device arranging the second member to cooperate with the first member in thermionic emission of electrons across the gap with the N type semiconductor material of the first member so illuminated, wherein one of: the second member is arranged to collect electrons emitted by the first member, or the first member is arranged to collect electrons emitted by the second member.

8. The thermionic emission device of claim 7 , further comprising:
the first member and the second member arranged as a thermionic energy converter, configured to couple the first member to a first terminal of a load or a device and to couple the second member to a second terminal of the load or the device; and
the second member configured to receive thermal energy from one of: a heat source or concentrated sunlight.

9. The thermionic emission device of claim 7 , further comprising:
the first member and the second member arranged as a thermionic energy converter configured to couple the first member to a first terminal of a load or a device and to couple the second member to a second terminal of the load or the device; and
a concentrator, including one of a mirror or a lens, arranged to heat the second member via application of concentrated sunlight.

10. The thermionic emission device of claim 7 , further comprising:
the first member configured to couple to a negative terminal of a voltage supply;
the second member configured to couple to a positive terminal of the voltage supply; and
the first member configured to attach to a device and to refrigerate the device as a result of operation of the first member and the second member in a refrigeration mode.

11. The thermionic emission device of claim 7 , further comprising:
a voltage supply having a positive terminal and a negative terminal;
the first member coupled to the negative terminal of the voltage supply;
the second member coupled to the positive terminal of the voltage supply; and
the first member configured to attach to a device and to refrigerate the device as a result of the first member and the second member operating in a refrigeration mode.

12. The thermionic emission device of claim 7 , further comprising:
the second member including a P type semiconductor material, arranged to receive illumination to produce photon enhanced thermionic emission (PETE), the first member and the second member configured to operate as a PETE device.

13. The thermionic emission device of claim 7 , further comprising:
the second member including a P type semiconductor material; and
the illumination member arranged to provide illumination to the second member so that the first member and the second member operate as a photon enhanced thermionic emission (PETE) device.

14. The thermionic emission device of claim 7 , further comprising:
the second member having a P type semiconductor material;
the illumination member comprising at least one mirror or lens, arranged to direct sunlight onto the first member; and
the at least one mirror or lens further arranged to direct concentrated sunlight onto the second member.

15. The thermionic emission device of claim 7 , further comprising:
an enclosure, with the first member and the second member arranged therein, the enclosure arranged to provide one of: a vacuum, or a plasma, such that the first member and the second member operate as one of: a thermionic energy converter, a refrigeration device, or a photon enhanced thermionic emission (PETE) device.

16. The thermionic emission device of claim 7 , further comprising:
the second member configured to attach to a heat source.

Assignees

• Univ Leland Stanford Junior

Inventors

• Riley Daniel
• Sahasrabuddhe Kunal
• Bargatin Igor
• Schwede Jared W
• Shen Zhi-Xun
• Melosh Nicholas A

Classifications

• H01J45/00

  Discharge tubes functioning as thermionic generators {(structural combination of fuel element with thermoelectric element G21C3/40; nuclear power plants using thermionic converters G21D7/04; structural combination of a radioactive source with a thermionic converter, e.g. radioisotope batteries G21H1/10; generators in which thermal or kinetic energy is converted into electrical energy by ionisation of a fluid and removal of the charge therefrom H02N3/00)} · CPC title

• H01J1/15 Primary

  Cathodes heated directly by an electric current · CPC title

• H01J1/135 Primary

  Circuit arrangements therefor, e.g. for temperature control · CPC title

• H01J1/20

  Cathodes heated indirectly by an electric current; Cathodes heated by electron or ion bombardment · CPC title