Method and apparatus for producing direct reduced iron utilizing a catalytical pretreatment of hydrocarbons as a source of reducing gas

Patent metadata

Field	Value
Publication number	US-11203791-B2
Application number	US-201716322689-A
Country	US
Kind code	B2
Filing date	Aug 2, 2017
Priority date	Aug 3, 2016
Publication date	Dec 21, 2021
Grant date	Dec 21, 2021

Abstract

A method and apparatus for producing direct reduced iron using a pre-treated make-up gas as a reducing agent in a direct reduced iron reactor are provided. The method involves pre-treating a stream of make-up gas containing heavy hydrocarbons by subjecting the stream to low temperature adiabatic reforming at a temperature between 300° C. and 600° C., prior to using the stream of make-up gas as a reducing agent for producing direct reduced iron. The method also involves adjusting the humidity content of the stream of make-up gas after the low temperature adiabatic reforming by bypassing the stream to selectively split it into a first part of the stream of make-up gas and a second part of the stream of make-up gas, subjecting the first part to water separation, and then mixing the first part with the second part to obtain a reducing stream to be sent to direct reduced iron production.

First claim

The invention claimed is:

1. A method for producing direct reduced iron, said method comprising:
pre-treating a stream of make-up gas containing heavy hydrocarbons by subjecting the stream of make-up gas to a low temperature adiabatic reforming at a temperature comprised between 300° C. and 600° C. to form a stream of pre-treated make-up gas to be used as a reducing agent for producing direct reduced iron;
subjecting said stream of pre-treated make-up gas to adjust humidity content of said stream of pre-treated make-up gas after said low temperature adiabatic reforming by bypassing said stream of pre-treated make-up gas to selectively split said stream of pre-treated make-up gas into a first part ( 128 ) of said stream of pre-treated make-up gas and a second part ( 130 ) of said stream of pre-treated make-up gas and subjecting only said first part ( 128 ) to a water separation in a water separation unit ( 136 ) and then mixing said first part ( 128 ) to said second part ( 130 ) to obtain a reducing stream ( 146 );
sending said reducing stream ( 146 ) to a direct reduced iron reactor ( 10 ) and carrying out a zero-reformer process in which catalytic reformation of the pre-treated make-up gas is carried-out in situ within the direct reduced iron reactor ( 10 ) to produce direct reduced iron, wherein the pre-treated make-up gas is not subjected to any further catalytic reaction besides the catalytic reactions that occur inside said direct reduced iron reactor ( 10 ).

2. The method of claim 1 , wherein said method comprises pre-heating the make-up gas prior to the low temperature adiabatic reforming.

3. The method of claim 2 , wherein said method comprises de-sulphurizing said make-up gas after pre-heating and prior to the low temperature adiabatic reforming.

4. The method of claim 3 , wherein said method comprises injecting steam into the stream of make-up gas after de-sulphurizing and prior to the low temperature adiabatic reforming.

5. The method of claim 4 , wherein said method comprises heating the stream of make-up gas after steam injection and prior to the low temperature adiabatic reforming.

6. The method of claim 1 , said method comprising subjecting off reducing gas from the direct reduced iron reactor ( 10 ) to at least water separation.

7. The method of claim 6 , said method comprising mixing the off reducing gas, after the at least water separation, with said stream of pre-treated make-up gas.

8. The method of claim 6 , said method comprising mixing the off reducing gas, after the at least water separation, with the stream of pre-treated make-up gas subjected to adjust humidity content after the low temperature adiabatic reforming.

9. The method of claim 6 , said method comprising subjecting the off reducing gas, after the at least water separation, to carbon dioxide removal and possible humidity content adjustment.

10. The method of claim 9 , said method comprising mixing the off reducing gas, after the carbon dioxide removal and possible humidity content adjustment, with said stream of pre-treated make-up gas.

11. The method of claim 9 , said method comprising mixing the off reducing gas, after the carbon dioxide removal and possible humidity content adjustment, with a stream of pre-treated make-up gas that has been subjected to adjust humidity content after the low temperature adiabatic reforming.

12. An apparatus for producing direct reduced iron, said apparatus comprising:
a direct reduced iron equipment ( 400 ) comprising a direct reduced iron reactor ( 10 );
wherein said direct reduced iron equipment ( 400 ) is configured for carrying-out a zero-reformer process in which catalytic reformation of the pre-treated make-up gas is carried-out in situ within the direct reduced iron reactor ( 10 ) such that the pre-treated make-up gas is subjected to no further catalytic reaction besides the catalytic reactions that occur inside said direct reduced iron reactor ( 10 ),
wherein said apparatus comprises a low temperature adiabatic reforming section ( 300 ) comprising a low temperature adiabatic reforming reactor ( 122 ) configured for subjecting a stream of make-up gas containing heavy hydrocarbons to a low temperature adiabatic reforming at a temperature comprised between 300° C. and 600° C., prior to using said stream of make-up gas as a reducing agent for producing direct reduced iron in said direct reduced iron equipment ( 400 ), in order to obtain a pre-reformed gas suitable for use as a reducing agent for producing direct reduced iron in said direct reduced iron equipment ( 400 ); and in that it comprises a humidity adjustment unit ( 500 ) configured for adjusting humidity content of said stream of make-up gas after the low temperature adiabatic reforming reactor ( 122 ), said humidity adjustment unit ( 500 ) comprising:
a bypass ( 131 ) located downstream of the low temperature adiabatic reforming reactor ( 122 ) and provided with a first branch ( 137 ) and a second branch ( 138 ) to selectively split said stream of make-up gas into a first part ( 128 ) of said stream of make-up gas and a second part ( 130 ) of said stream of make-up gas;
a water separation unit ( 136 ) associated to said first branch ( 137 ) and configured for subjecting said first part ( 128 ) to a water separation to be then mixed with said second part ( 130 ) to obtain a reducing stream ( 146 ) to be sent to said direct reduced iron equipment ( 400 ).

13. The apparatus of claim 12 , wherein said low temperature adiabatic reforming section ( 300 ) comprises a gas pre-heater ( 104 ) upstream the low temperature adiabatic reforming reactor ( 122 ).

14. The apparatus of claim 13 , wherein said low temperature adiabatic reforming section ( 300 ) comprises a de-sulphurizer ( 108 ) downstream of the gas pre-heater ( 104 ) and upstream of the low temperature adiabatic reforming reactor ( 122 ).

15. The apparatus of claim 14 , wherein said low temperature adiabatic reforming section ( 300 ) comprises a steam source ( 112 ) for injecting steam ( 114 ) into the stream of make-up gas after the de-sulphurizer ( 108 ) and upstream of the low temperature adiabatic reforming reactor ( 122 ).

16. The apparatus of claim 15 , wherein said low temperature adiabatic reforming section ( 300 ) comprises a heater ( 118 ) after the steam injection ( 114 ) and upstream of the low temperature adiabatic reforming reactor ( 122 ).

17. The apparatus of claim 12 , said apparatus further comprising a water separation unit ( 36 ) for subjecting off reducing gas from the direct reduced iron reactor ( 10 ) to at least water separation.

18. The apparatus of claim 17 , said apparatus further comprising a carbon dioxide removal and possible humidity content adjustment section ( 800 ), for removing carbon dioxide from the off reducing gas after the water separation unit ( 36 ).

19. The apparatus of claim 18 , wherein said carbon dioxide removal and possible humidity content adjustment section ( 800 ) is connected to a connection pipe ( 151 ) provided to connect said humidity adjustment unit ( 500 ) to the direct reduced iron equipment ( 400 ).

Assignees

• Danieli Off Mecc
• Hyl Tech S A De C V

Inventors

• Condosta Michele
• Dalle Nogare Daniela
• Primavera Alessandra
• Martinis Alessandro
• Zendejas Martinez Eugenio

Classifications

• C21B2100/42

  Sulphur removal · CPC title

• C21B2400/068

  with a sealed or controlled environment · CPC title

• C21B13/14

  Multi-stage processes {processes carried out in different vessels or furnaces} · CPC title

• C21B13/02

  in shaft furnaces · CPC title

• C21B2100/282

  of carbon dioxide · CPC title