Manganese oxide based catalyst and catalyst device for the removal of formaldehyde and volatile organic compounds

Patent metadata

Field	Value
Publication number	US-11203009-B2
Application number	US-201716309666-A
Country	US
Kind code	B2
Filing date	Jun 12, 2017
Priority date	Jun 30, 2016
Publication date	Dec 21, 2021
Grant date	Dec 21, 2021

Abstract

Disclosed herein are a catalyst composition, catalyst devices, and methods for removing formaldehyde, volatile organic compounds, and other pollutants from an air flow stream. The catalyst composition including manganese oxide, optionally one or more of alkali metals, alkaline earth metals, zinc, iron, binder, an inorganic oxide, or carbon.

First claim

What is claimed is:

1. A catalyst composition comprising manganese oxide, the manganese oxide comprising manganese oxide polymorph I, wherein the catalyst composition comprises one or more of an alkali metal, an alkaline earth metal, zinc, or iron, and wherein the catalyst composition is adapted to remove one or more of formaldehyde, ozone, carbon monoxide, nitrogen oxide, amines, sulfur compounds, thiols, chlorinated hydrocarbons, or volatile organic compounds from an unpurified air supply.

2. The catalyst composition of claim 1 , wherein a chloride content of the catalyst composition is less than 1 wt % based on a total weight of the catalyst composition.

3. The catalyst composition of claim 1 , wherein a sulfate content of the catalyst composition is less than 1 wt % based on a total weight of the catalyst composition.

4. The catalyst composition of claim 1 , wherein a chloride content and a sulfate content of the catalyst composition are each less than 1 wt % based on a total weight of the catalyst composition.

5. The catalyst composition of claim 1 , further comprising a binder.

6. The catalyst composition of claim 5 , wherein the binder comprises alumina.

7. The catalyst composition of claim 5 , wherein the binder comprises a polymeric binder.

8. The catalyst composition of claim 1 , further comprising an inorganic oxide.

9. The catalyst composition of claim 8 , wherein the inorganic oxide comprises ceria, zirconia, silica, titania, alumina, iron, lanthanum, praseodymium, samarium, or mixtures thereof.

10. The catalyst composition of claim 1 , wherein the catalyst composition is disposed on a solid substrate.

11. The catalyst composition of claim 10 , wherein the solid substrate comprises a polymer substrate, a ceramic substrate, a metallic substrate, a foam substrate, a paper substrate, or mixtures thereof.

12. The catalyst composition of claim 1 , wherein the catalyst composition comprises an extrudate.

13. The catalyst composition of claim 1 , further comprising activated carbon.

14. The catalyst composition of claim 1 , wherein the manganese oxide further comprises cryptomelane, amorphous manganese oxide, birnessite, vernadite, polymorphs thereof, and combinations thereof.

15. A catalyst device for purifying an air supply, comprising:
a substrate, wherein the substrate is a polymer substrate, a ceramic substrate, a metallic substrate, a foam substrate, a paper substrate, or mixture thereof, and wherein the substrate is adapted for use in an heating, ventilation, and air conditioning (HVAC) system or a vehicle; and
a catalyst composition disposed on the substrate at a loading of 1 g/in 3 to 3 g/in 3 , wherein the catalyst composition comprises manganese oxide and one or more of an alkali metal, an alkaline earth metal, zinc, or iron, and wherein the catalyst composition is adapted to remove formaldehyde, ozone, and one or more of carbon monoxide, nitrogen oxide, amines, sulfur compounds, thiols, chlorinated hydrocarbons, or volatile organic compounds from circulated air of the HVAC system or vehicle, wherein the manganese oxide comprises manganese oxide polymorph I.

16. The catalyst device of claim 15 , wherein the catalyst composition comprises a BET surface area ranging from about 5 m 2 /g to about 150 m 2 /g, and wherein the catalyst composition defines pores having a pore volume ranging from about 0.3 mL/g to about 1.5 mL/g.

17. The catalyst device of claim 15 , wherein the catalyst composition defines pores having a pore volume ranging from about 0.3 mL/g to about 0.9 mL/g.

18. A method for preparing an extruded catalyst, the method comprising:
mixing manganese oxide and water to form an extrudable paste, the manganese oxide comprising manganese oxide polymorph I; and
extruding the paste to form the extruded catalyst,
wherein the extruded catalyst has a BET surface area ranging from about 5 m 2 /g to about 150 m 2 /g, and wherein the extruded catalyst comprises one or more of an alkali metal, an alkaline earth metal, zinc, or iron.

19. The method of claim 18 , wherein the extruded catalyst defines pores having a pore volume ranging from about 0.3 mL/g to about 1.5 mL/g.

Assignees

• Basf Corp

Inventors

• Weinberger David
• Ruettinger Wolfgang
• Tran Pascaline
• Alden Laif
• Gu Ting
• Zhao Feng
• Shi Anju
• Lawrenz Nils
• Wengeler Lukas

Classifications

• Y02A50/20

  Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters · CPC title

• B01J2235/00

  Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties · CPC title

• B01J2235/15

  X-ray diffraction · CPC title

• B01J35/56

  Foraminous structures having flow-through passages or channels, e.g. grids or three-dimensional [3D] monoliths · CPC title

• B01J20/2803

  Sorbents comprising a binder, e.g. for forming aggregated, agglomerated or granulated products · CPC title