Method for producing water-absorbing polymer particles by suspension polymerization

Patent metadata

Field	Value
Publication number	US-11203005-B2
Application number	US-201515532153-A
Country	US
Kind code	B2
Filing date	Nov 24, 2015
Priority date	Dec 4, 2014
Publication date	Dec 21, 2021
Grant date	Dec 21, 2021

Abstract

A process for producing water-absorbing polymer particles by suspension polymerization and thermal surface postcrosslinking, wherein the agglomerated base polymer obtained by suspension polymerization has a centrifuge retention capacity of at least 37 g/g and the thermal surface postcrosslinking is conducted at 100 to 190° C.

First claim

The invention claimed is:

1. A process for producing water-absorbing polymer particles by polymerizing a monomer solution comprising
a) at least one ethylenically unsaturated monomer which bears an acid group and optionally is at least partly neutralized,
b) optionally one or more crosslinker,
c) at least one initiator,
d) optionally one or more ethylenically unsaturated monomer copolymerizable with the monomer mentioned under a), and
e) optionally one or more water-soluble polymer,
the monomer solution suspended in a hydrophobic organic solvent during the polymerization and agglomerating in the hydrophobic organic solvent during or after the polymerization, and thermally surface postcrosslinking the resultant agglomerated polymer particles by means of an organic surface postcrosslinker, wherein the amount of crosslinker b) is selected such that the agglomerated polymer particles before the surface postcrosslinking have a centrifuge retention capacity of at least 37 g/g and the thermal surface postcrosslinking is conducted at 100 to 190° C.,
wherein the water-absorbing polymer particles have a centrifuge retention capacity of at least 37 g/g, an absorption under a pressure of 21.0 g/cm 2 of at least 30 g/g, an absorption under a pressure of 49.2 g/cm 2 of at least 14 g/g, a sum total of centrifuge retention capacity and absorption under a pressure of 21.0 g/cm 2 of at least 69 g/g, a sum total of centrifuge retention capacity and absorption under a pressure of 49.2 g/cm 2 of at least 54 g/g, and less than 20% by weight of extractables.

2. The process according to claim 1 , wherein agglomeration is effected in the hydrophobic organic solvent after the polymerization.

3. The process according to claim 1 , wherein the polymerization is conducted in the presence of a chain transfer reagent.

4. The process according to claim 1 , wherein the amount of crosslinker b) is selected such that the polymer particles before the surface postcrosslinking have a centrifuge retention capacity of at least 40 g/g.

5. The process according to claim 1 , wherein the thermal surface postcrosslinking is conducted at 120 to 170° C.

6. The process according to claim 1 , wherein the organic surface postcrosslinker is selected from the group consisting of alkylene carbonates, 2-oxazolidinones, bis- and poly-2-oxazolidinones, 2-oxotetrahydro-1,3-oxazines, N-acyl-2-oxazolidinones, cyclic ureas, bicyclic amido acetals, oxetanes, and morpholine-2,3-diones.

7. The process according to claim 1 , wherein from 1 to 5% by weight of organic surface postcrosslinker is used, based on the resultant polymer particles.

8. The process according to claim 1 , wherein at least one dispersing aid is used in the polymerization.

9. The process according to claim 1 , wherein the resultant polymer particles are at least partly dewatered azeotropically after the polymerization.

10. The process according to claim 9 , wherein the resultant polymer particles are filtered and dried after the azeotropic dewatering.

11. The process according to claim 1 , wherein the thermal surface postcrosslinking is conducted in a mixer with moving mixing tools.

Assignees

• Basf Se

Inventors

• Mark Tina
• Daniel Thomas
• Lutz Erich
• Molter Stefan
• Kowalski Anna

Classifications

• C08F6/22

  Coagulation · CPC title

• C08J3/245

  Differential crosslinking of one polymer with one crosslinking type, e.g. surface crosslinking · CPC title

• C08F2/18 Primary

  Suspension polymerisation · CPC title

• B01J20/265 Primary

  modified or post-treated polymers (polymer carriers or substrates subjected to further impregnating or coating B01J20/3208) · CPC title

• A61L15/60

  Liquid-swellable gel-forming materials, e.g. super-absorbents · CPC title