Method for manufacturing a membrane assembly for a fuel cell with catalyst free edge areas; membrane assembly and fuel cell with membrane assembly

Patent metadata

Field	Value
Publication number	US-11201344-B2
Application number	US-202016812655-A
Country	US
Kind code	B2
Filing date	Mar 9, 2020
Priority date	Mar 9, 2020
Publication date	Dec 14, 2021
Grant date	Dec 14, 2021

Abstract

A method for manufacturing a membrane assembly for a fuel cell. To overcome a problem of chemical degradation at an edge of the membrane, the method comprises the following steps:
positioning a first decal layer, which is made of the same material as a first catalyst layer, on a first side of the membrane, positioning a second decal layer, which is made of the same material as a second catalyst layer, on a second side of the membrane, pressing a compression pad, which is positioned on the first decal layer with the first decal layer and the second decal layer fully overlapping the compression pad, and the second decal layer against each other with the first decal layer and the membrane positioned in-between, whereby pressure on the first and the second decal layer is applied only in an area covered by the compression pad.

First claim

The invention claimed is:

1. A method for manufacturing a membrane assembly for a fuel cell, which membrane assembly comprises
a membrane with a first side and a second side, and
first catalyst layer arranged on the first side of the membrane and a second catalyst layer arranged on the second side of the membrane,
wherein the method comprises the following steps:
providing a compression pad having the shape and size of the first and second catalyst layers to be formed,
providing a first decal layer on a first backer, the first decal layer larger in size than the compression pad in two directions parallel to the decal layer,
providing a second decal layer on a second backer, the second decal layer larger in size than the compression pad in two directions parallel to the decal layer,
positioning the first decal layer, which is made of the same material as the first catalyst layer, on the first side of the membrane, so that the first decal layer is between the first backer and the first side of the membrane,
positioning the second decal layer, which is made of the same material as the second catalyst layer, on the second side of the membrane, so that the second layer is between the second backer and the second side of the membrane,
pressing the compression pad against the first backer so that pressure force causes a first decal layer part to adhere to the first side of the membrane and a second decal layer part to adhere to the second side of the membrane, the part of the first decal layer adhering to the first side of the membrane forming the first catalyst layer, the part of the second decal layer adhering to the second side of the membrane forming the second catalyst layer, the adhering of the decal layers only taking place in the areas of the respective decal layers where the compression pad pressure is applied,
releasing the compression pad,
removing the first and second backer, whereby the rest of the decal layers not adhered to the membrane and remaining on the backer are removed from the membrane together with their respective backer.

2. The method according to claim 1 , wherein the pressing is carried out with the compression pad and an opposing pressing surface.

3. The method according to claim 1 , wherein the pressing is carried out in a continuous process by two rollers.

4. The method according to claim 3 , wherein the compression pad is a protruding part of the two rollers.

5. The method according to claim 1 , wherein due to a size and/or the positioning of the compression pad relative to the membrane an edge region of the membrane remains free from the first catalyst layer and/or the second catalyst layer.

6. A membrane assembly for a fuel cell, comprising
a membrane with a first side and a second side, and
a first catalyst layer arranged on the first side of the membrane and a second catalyst layer arranged on the second side of the membrane, wherein
the first catalyst layer is formed from a first decal layer made of the same material as the first catalyst layer by decal transfer and the second catalyst layer is formed from a second decal layer made of the same material as the second catalyst layer by decal transfer, and
the first and the second catalyst layer are formed by:
providing a compression pad having the shape and size of the first and second catalyst layers to be formed,
providing a first decal layer on a first backer, the first decal layer larger in size than the compression pad in two directions parallel to the decal layer,
providing a second decal layer on a second backer, the second decal layer larger in size than the compression pad in two directions parallel to the decal layer,
positioning the first decal layer on the first side of the membrane, so that the first decal layer is between the first backer and the first side of the membrane,
positioning the second decal layer on the second side of the membrane, so that the second layer is between the second backer and the second side of the membrane,
pressing the compression pad against the first backer so that pressure force causes a first decal layer part to adhere to the first side of the membrane and a second decal layer part to adhere to the second side of the membrane, the part of the first decal layer adhering to the first side of the membrane forming the first catalyst layer, the part of the second decal layer adhering to the second side of the membrane forming the second catalyst layer, the adhering of the decal layers only taking place in the areas of the respective decal layers where the compression pad pressure is applied,
releasing the compression pad,
removing the first and second backer, whereby the rest of the decal layers not adhered to the membrane and remaining on the backer are removed from the membrane together with their respective backer.

7. The membrane assembly according to claim 6 , wherein an edge region of the membrane is free from the first catalyst layer and/or the second catalyst layer.

8. The membrane assembly according to claim 6 , wherein the first catalyst layer and the second catalyst layer form an electrode each.

9. A fuel cell with at least one membrane assembly according to claim 6 .

Assignees

• Daimler Ag
• Ford Motor Co

Inventors

• Prass Sebastian
• Ghuman Manpal
• Leow Andrew
• Eastcott Jennie
• Thomas Owen

Classifications

• Y02E60/50

  Fuel cells · CPC title

• H01M4/8896

  Pressing, rolling, calendering (membrane electrode assemblies H01M8/1004) · CPC title

• H01M4/8814

  Temporary supports, e.g. decal · CPC title

• H01M2008/1095

  Fuel cells with polymeric electrolytes · CPC title

• H01M8/1004 Primary

  characterised by membrane-electrode assemblies [MEA] (H01M8/12 takes precedence) · CPC title