Ionic liquid carbon nanotube composites for wireless chemical sensing

Patent metadata

Field	Value
Publication number	US-11200474-B2
Application number	US-201916732095-A
Country	US
Kind code	B2
Filing date	Dec 31, 2019
Priority date	Jun 17, 2016
Publication date	Dec 14, 2021
Grant date	Dec 14, 2021

Abstract

A wireless sensor platform design and a single walled carbon nanotube/ionic liquid-based chemidosimeter system can incorporated into a highly sensitive and selective chemical hazard badge that can dosimetrically detect an analyte down to a sub parts-per-million concentration.

First claim

What is claimed is:

1. A device for detecting a stimulus comprising:
a radio frequency identification tag including an integrated circuit and a sensor portion including:
a chemiresistor including a carbon nanotube incorporated in parallel with the integrated circuit, and
a resistor in series with the integrated circuit,
wherein the sensor portion is configured to change resistance when the radio frequency identification tag contacts or interacts with the stimulus, and wherein the change in resistance alters an output of the radio frequency identification tag in response to chemical, biological, or physical changes around the sensor portion.

2. The device of claim 1 , wherein the chemiresistor includes a plurality of nanotubes.

3. The device of claim 2 , wherein the nanotubes are single walled carbon nanotubes.

4. The device of claim 1 , wherein the chemiresistor includes a plurality of conducting polymers.

5. The device of claim 1 , wherein the device is a diagnostic device.

6. The device of claim 5 , wherein the device is a breath analyzer.

7. The device of claim 1 , wherein the chemiresistor includes an ionic liquid.

8. The device of claim 7 , wherein the ionic liquid is 1-butyl-3-methylimidazolium chloride.

9. The device of claim 1 , wherein the resistor sets a threshold at which the integrated circuit is activated.

10. The device of claim 1 , wherein the stimulus includes an analyte.

11. The device of claim 10 , wherein the change in resistance affects a characteristic of the spectrum of the radio frequency identification tag.

12. The device of claim 11 , wherein the change in resistance is irreversible.

13. The device of claim 11 , wherein a change in the characteristic of the spectrum of the radio frequency identification tag is related to a concentration of the analyte.

14. The device of claim 11 , wherein the characteristic of the spectrum of the radio frequency identification tag is a change in a gain of the radio frequency identification tag, wherein the change in the gain of the radio frequency identification tag is related to a cumulative exposure to the analyte.

15. A system comprising:
a device for detecting a stimulus, the device comprising:
a radio frequency identification tag including an integrated circuit and a sensor portion, the sensor portion comprising:
a chemiresistor including a carbon nanotube incorporated in parallel with the integrated circuit, and
a resistor in series with the integrated circuit,

wherein the sensor portion is configured to change resistance when the radio frequency identification tag contacts or interacts with the stimulus, and wherein the change in resistance alters an output of the radio frequency identification tag in response to chemical, biological, or physical changes around the sensor portion; and
a portable reader comprising a radio frequency transceiver wherein the radio frequency transceiver is adapted to transmit and receive signals to and from the device.

16. The system of claim 15 , wherein the portable reader relates the output of the radio frequency identification tag to an equivalent exposure of the device to the analyte.

17. The system of claim 16 , wherein the portable reader synchronizes the equivalent exposure of the device to the analyte with a cloud-based database.

18. The system of claim 17 , further comprising a processing unit wherein the processing unit is adapted to interrogate the cloud-based database and expose spatio-temporal trends.

19. A system for detecting a stimulus comprising:
a radio frequency device containing a circuit comprising an inductive element, a capacitive element, a resistive element and an integrated circuit, wherein the resistive element is in parallel with the integrated circuit and wherein the resistive element is responsive to an analyte; and
a portable reader adapted to
transmit radio frequency waves to the radio frequency device;
receive a spectrum of radio frequency waves from the radio frequency device; and
relate a characteristic of the spectrum to a concentration of the analyte, wherein the characteristic of the spectrum is a gain of the radio frequency device.

Assignees

• Massachusetts Inst Technology

Inventors

• Swager Timothy M
• Azzarelli Joseph Michael
• Zhu Rong

Classifications

• G01N27/122 Primary

  Circuits particularly adapted therefor, e.g. linearising circuits · CPC title

• G01N27/127

  comprising nanoparticles · CPC title

• A61B5/082

  Evaluation by breath analysis, e.g. determination of the chemical composition of exhaled breath (A61B5/083, A61B5/091 take precedence) · CPC title

• G01N27/4146

  involving nanosized elements, e.g. nanotubes, nanowires · CPC title

• A61B2562/029

  Humidity sensors · CPC title