Methods for hydrogen gas production through water electrolysis

Patent metadata

Field	Value
Publication number	US-11198941-B2
Application number	US-201816483631-A
Country	US
Kind code	B2
Filing date	Feb 1, 2018
Priority date	Feb 3, 2017
Publication date	Dec 14, 2021
Grant date	Dec 14, 2021

Abstract

A method of producing hydrogen gas comprises introducing gaseous water to an electrolysis cell comprising a positive electrode, a negative electrode, and a proton conducting membrane between the positive electrode and the negative electrode. The proton conducting membrane comprises an electrolyte material having an ionic conductivity greater than or equal to about 10−2 S/cm at one or more temperatures within a range of from about 150° C. to about 650° C. The gaseous water is decomposed using the electrolysis cell. A hydrogen gas production system and an electrolysis cell are also described.

First claim

What is claimed is:

1. A method of producing hydrogen gas, comprising:
introducing gaseous water to an electrolysis cell comprising a positive electrode, a negative electrode, and a proton-conducting membrane between the positive electrode and the negative electrode, the proton-conducting membrane comprising at least one perovskite material having an ionic conductivity greater than or equal to about 10 −2 S/cm at one or more temperatures within a range of from about 150° C. to about 650° C. and selected to comprise one or more of yttrium- and ytterbium-doped barium-zirconate-cerate (BZCYYb) of the composition BaZr 0.8−y Ce y Y 0.2−x Yb x O 3−δ , and yttrium- and ytterbium-doped barium-strontium-niobate (BSNYYb) of the composition Ba 3 (Sr 1−x Nb 2−y Y x Yb y )O 9−δ , wherein x and y are dopant levels and δ is oxygen deficit; and
decomposing the gaseous water using the electrolysis cell.

2. The method of claim 1 , further comprising selecting the at least one perovskite material to have a H + conductivity greater than or equal to about 10 −2 S/cm at one or more temperatures within a range of from about 350° C. to about 650° C.

3. The method of claim 2 , further comprising selecting the at least one perovskite material to comprise a stack of at least two different perovskite materials each individually having the H + conductivity greater than or equal to about 10 −2 S/cm at the one or more temperatures within the range of from about 350° C. to about 650° C.

4. The method of claim 2 , further comprising:
selecting the positive electrode to comprise one or more of a double perovskite material, a single perovskite material, a Ruddleson-Popper-type perovskite material, and a composite material comprising at least two different perovskite materials; and
selecting the negative electrode to comprise a cermet material comprising at least one metal and at least one perovskite.

5. The method of claim 1 , wherein introducing gaseous water to the electrolysis cell comprises exposing the positive electrode of the electrolysis cell to the gaseous water without exposing the negative electrode of the electrolysis cell to the gaseous water.

6. The method of claim 1 , further comprising heating the gaseous water to a temperature within the range of from about 150° C. to about 650° C. effectuating the ionic conductivity greater than about 10 −2 S/cm within the proton-conducting membrane prior to decomposing the gaseous water using the at least one electrolysis cell.

7. The method of claim 1 , wherein the yttrium- and ytterbium-doped barium-zirconate-cerate (BZCYYb) comprises BaZr 0.3 Ce 0.5 Y 0.1 Yb 0.1 O 3−δ .

8. The method of claim 1 , further comprising selecting the proton-conducting membrane to have a thickness within a range of from about 5 μm to about 1000 μm.

9. The method of claim 1 , further comprising selecting the proton-conducting membrane to be substantially homogeneous.

10. The method of claim 1 , further comprising selecting the positive electrode to comprise MBa 1−x Sr x Co 2−y Fe y O 5+δ , where M is Pr, Nd, or Sm.

11. The method of claim 10 , further comprising selecting the positive electrode to comprise one or more of PrBa 0.5 Sr 0.5 Co 1.5 Fe 0.5 O 5+δ , NdBa 0.5 Sr 0.5 Co 1.5 Fe 0.5 O 5+δ , and SmBa 0.5 Sr 0.5 Co 1.5 Fe 0.5 O 5+δ .

12. The method of claim 1 , further comprising selecting the positive electrode to comprise M 2 NiO 4−δ , where M is La, Pr, Gd, or Sm.

13. The method of claim 1 , further comprising selecting the positive electrode to comprise a composite material comprising Sm 1−x Sr x CoO 3−δ and BaZr 0.8−y Ce y Y 0.2−x Yb x O 3−δ .

14. The method of claim 1 , further comprising selecting the negative electrode to comprise a cermet material comprising nickel and one of yttrium- and ytterbium-doped barium-zirconate-cerate (BZCYYb), yttrium- and ytterbium-doped barium-strontium-niobate (BSNYYb), barium-yttrium-stannate, and barium-calcium-niobate.

Assignees

• Battelle Energy Alliance Llc

Inventors

• He Ting
• Ding Dong
• Wu Wei

Classifications

• C25B9/23

  comprising ion-exchange membranes in or on which electrode material is embedded · CPC title

• C25B11/047

  Ceramics · CPC title

• C25B15/021

  of heating or cooling · CPC title

• C25B9/73

  of the filter-press type · CPC title

• C25B13/04 Primary

  characterised by the material · CPC title