Resin composition

Patent metadata

Field	Value
Publication number	US-11198784-B2
Application number	US-201716097655-A
Country	US
Kind code	B2
Filing date	May 1, 2017
Priority date	May 2, 2016
Publication date	Dec 14, 2021
Grant date	Dec 14, 2021

Abstract

A resin composition is provided which includes a resin component, a fibrous filler, and a plate-like filler. With respect to 100 parts by mass of the resin component, the content of the fibrous filler is from 30 parts by mass or more to 100 parts by mass or less, the content of the plate-like filler is from 20 parts by mass or more to 80 parts by mass or less, and the total content of the fibrous filler and the plate-like filler is from 50 parts by mass or more to 180 parts by mass or less. The resin component includes an amorphous resin, and the content of the amorphous resin is from 60 parts by mass or more to 100 parts by mass or less.

First claim

The invention claimed is:

1. A resin composition comprising:
a resin component including a polyether sulfone amorphous resin and a liquid crystal polyester resin;
a glass fiber; and
a plate-like filler,
wherein,
a content of said plate-like filler is from 20 parts by mass or more to 80 parts by mass or less with respect to 100 parts by mass of said resin component,
a total content of said glass fiber and said plate-like filler is from 50 parts by mass or more to 140 parts by mass or less with respect to 100 parts by mass of said resin component,
a content of said polyether sulfone is from 60 parts by mass or more to 95 parts by mass or less with respect to 100 parts by mass of said resin component,
wherein the plate-like filler is at least one selected from scaly graphite, talc and mica,
a content of the glass fiber is from 40 parts by mass or more to 100 parts by mass or less with respect to 100 parts by mass of the resin component, and
wherein when a molded body is formed using a mold cavity having a cavity of 64 mm (MD)×64 mm (TD)×3 mm (thickness),
a TD molding shrinkage rate obtained from the following formula (1) is 0.23% or less,
an MD molding shrinkage rate obtained from the following formula (2) is 0.15% or less, and
(said TD molding shrinkage rate)/(said MD molding shrinkage rate) is 1.5 or less:
TD molding shrinkage rate (%)=([average value of lengths of two sides in TD of the cavity of the mold cavity]−[average value of lengths of two sides in TD of the molded body])/[average value of lengths of two sides in TD of the cavity of the mold cavity]×100  (1)

MD molding shrinkage rate (%)=([average value of lengths of two sides in MD of the cavity of the mold cavity]−[average value of lengths of two sides in MD of the molded body])/[average value of lengths of two sides in MD of the cavity of the mold cavity]×100  (2).

2. The resin composition according to claim 1 , wherein said (TD shrinkage rate)/(MD shrinkage rate) is 1.0 or less.

3. The resin composition according to claim 1 , which is for molding an automobile part.

4. An oil control valve, a solenoid valve, a car air conditioning vane or a turbocharger casing/shroud formed from the resin composition according to claim 1 .

5. A resin composition comprising:
a resin component including a polyether sulfone amorphous resin and a liquid crystal polyester resin;
a glass fiber; and
a plate-like filler,
wherein
a content of said plate-like filler is from 20 parts by mass or more to 80 parts by mass or less with respect to 100 parts by mass of said resin component,
a total content of said glass fiber and said plate-like filler is from 50 parts by mass or more to 140 parts by mass or less with respect to 100 parts by mass of said resin component,
a content of said polyether sulfone is from 60 parts by mass or more to 95 parts by mass or less with respect to 100 parts by mass of said resin component,
wherein the plate-like filler is at least one selected from scaly graphite, talc and mica,
a content of the glass fiber is from 40 parts by mass or more to 100 parts by mass or less with respect to 100 parts by mass of the resin component, and
wherein when a molded body is formed using a mold cavity under the following conditions,
a TD molding shrinkage rate obtained from the following formula (3) is from 0.02% or more to 0.20% or less,
an MD molding shrinkage rate obtained from the following formula (4) is from −0.05% or more to 0.05% or less,
a sum of said MD molding shrinkage rate and said TD molding shrinkage rate is 0.25% or less:
(conditions)
mold cavity: includes, in a base substance of 64 mm (MD)×64 mm (TD)×3 mm (thickness), a cavity having a shape in which four square pyramids are attached so that apexes overlap corners of an imaginary square of 50 mm×50 mm in plan view which are assumed to be 7 mm inside from an outer periphery of said base substance;
said square pyramid: 2 mm×2 mm (bottom surface), 0.2 mm (height)
TD molding shrinkage rate (%)=([average value of two lengths between apexes of two square pyramids spaced apart in TD of the mold cavity]−[average value of two lengths between apexes of two square pyramids spaced apart in TD of the molded body])/[average value of two lengths between apexes of two square pyramids spaced apart in TD of the mold cavity]×100  (3)

MD molding shrinkage rate (%)=([average value of two lengths between apexes of two square pyramids spaced apart in MD of the mold cavity]−[average value of two lengths between apexes of two square pyramids spaced apart in MD of the molded body])/[average value of two lengths between apexes of two square pyramids spaced apart in MD of the mold cavity]×100   (4).

6. The resin composition according to claim 5 , wherein the sum of said MD molding shrinkage rate and said TD molding shrinkage rate is 0.15% or less.

Assignees

• Sumitomo Chemical Co

Inventors

• Komori Kazuhiro

Classifications

• B29B9/12

  characterised by structure or composition · CPC title

• B29B7/90

  Fillers or reinforcements {, e.g. fibres} · CPC title

• B29B7/726

  Measuring properties of mixture, e.g. temperature or density (B29B7/724 takes precedence) · CPC title

• B29B7/007

  for continuous mixing · CPC title

• C08L81/06 Primary

  Polysulfones; Polyethersulfones · CPC title