Method for actively treating mining wastewater for pigment production

Patent metadata

Field	Value
Publication number	US-11198629-B2
Application number	US-201715816542-A
Country	US
Kind code	B2
Filing date	Nov 17, 2017
Priority date	Nov 17, 2016
Publication date	Dec 14, 2021
Grant date	Dec 14, 2021

Abstract

Systems and methods for actively treating mining wastewater, such as acid mine drainage, using a mixed culture of iron oxidizing bacteria, in a manner that results in both remediation of the water and the production of a useful end product. Exemplary systems and methods employ a reaction vessel where the bacteria can oxidize the iron in the mining wastewater for some amount of time, and a settling tank into which reacted water may be transferred and retained to permit iron oxyhydroxide contained in the water to settle as iron oxyhydroxide sludge. The iron oxyhydroxide sludge may be dried to produce iron oxyhydroxide solids that can be employed in the manufacture of a usable pigment.

First claim

What is claimed is:

1. A method for producing pigment by actively treating iron oxyhydroxide-containing mining wastewater, comprising:
providing a series of vessels for treating the iron oxyhydroxide containing mining wastewater, the series of vessels including a reaction vessel as a first vessel and a settling tank as a second vessel;
inoculating the reaction vessel with a mixed culture of iron oxidizing bacteria;
directing the iron oxyhydroxide-containing mining wastewater into the reaction vessel and allowing the iron oxidizing bacteria to oxidize the iron in the iron oxyhydroxide-containing mining wastewater for an amount of time between about 2-8 hours while maintaining the pH level in the reaction vessel between about 3.5-4.5;
discharging the iron oxyhydroxide-containing mining wastewater from the reaction vessel into the settling tank, and retaining the iron oxyhydroxide-containing mining wastewater in the settling tank while the iron oxyhydroxide in the mining wastewater settles as an iron oxyhydroxide sludge;
draining the resulting water from the settling tank;
removing the settled iron oxyhydroxide sludge from the settling tank;
neutralizing the removed iron oxyhydroxide sludge;
drying the neutralized iron oxhydroxide sludge to produce iron oxyhydroxide solids; and

manufacturing a pigment from the iron oxyhydroxide solids.

2. The method of claim 1 , wherein the mining wastewater is retained in the settling tank for between about 4-8 hours.

3. The method of claim 1 , further comprising neutralizing the mining wastewater drained from the settling tank.

4. The method of claim 3 , wherein the mining wastewater is neutralized to a pH level of about 7.5.

5. The method of claim 3 , further comprising returning the neutralized mining wastewater to the environment.

6. The method of claim 1 , further comprising returning a portion of the iron oxyhydroxide sludge removed from the settling tank to the reaction vessel, before the sludge is neutralized.

7. The method of claim 1 , wherein the total dissolved metals content in the mining wastewater is greater than 70 weight % iron.

8. The method of claim 1 , wherein the iron oxidizing bacteria are sourced from the same relative locale as the mining wastewater.

9. The method of claim 1 , wherein the iron oxidizing bacteria are provided as a mixed culture sourced from a number of mine drainage sites.

10. The method of claim 1 , further comprising using the pigment in the manufacture of paint.

11. A method for producing pigment by actively treating iron oxyhydroxide-containing acid mine water, comprising:
providing a series of vessels for treating the acid mine water, the series of vessels including a reaction vessel as a first vessel and a settling tank as a second vessel;
inoculating the reaction vessel with a mixed culture of iron oxidizing bacteria;
directing the iron oxyhydroxide-containing acid mine water into the reaction vessel and allowing the iron oxidizing bacteria to oxidize the iron in the iron oxyhydroxide-containing acid mine water for an amount of time between about 2-8 hours at a temperature of between 12° C.-21° C. while maintaining the pH level in the reaction vessel between about 3.5-4.5;
discharging the acid mine water from the reaction vessel into the settling tank, and retaining the iron oxyhydroxide-containing acid mine water in the settling tank for some amount of time sufficient to permit the iron oxyhydroxide in the acid mine water to settle in the settling tank as iron oxyhydroxide sludge;
draining the resulting water from the settling tank;
optionally, neutralizing the water drained from the settling tank;
optionally, returning the neutralized water to the environment;
removing the settled iron oxyhydroxide sludge from the settling tank;
optionally, returning a portion of the iron oxyhydroxide sludge to the reaction vessel;
neutralizing the iron oxyhydroxide sludge not returned to the reaction vessel;
dewatering and drying the neutralized iron oxyhydroxide sludge to produce iron oxyhydroxide solids; and
manufacturing a pigment from the iron oxyhydroxide solids.

12. The method of claim 11 , wherein the acid mine water is retained in the settling tank for between about 4-8 hours.

13. The method of claim 11 , wherein the total dissolved metals content in the acid mine water is greater than 70 weight % iron.

14. The method of claim 11 , wherein the source of the iron oxidizing bacteria is selected from the group consisting of the same relative locale as the acid mine water and the combination of a number of different acid mine drainage sites.

Assignees

• Univ Ohio

Inventors

• Riefler R Guy

Classifications

• C02F2001/007

  Processes including a sedimentation step · CPC title

• C08K2003/2265

  of iron · CPC title

• C02F11/12

  by de-watering, drying or thickening · CPC title

• C09C1/24

  Oxides of iron · CPC title

• C02F2103/10

  from quarries or from mining activities · CPC title