System for producing a fully impregnated thermoplastic prepreg

Patent metadata

Field	Value
Publication number	US-11198259-B2
Application number	US-201815944249-A
Country	US
Kind code	B2
Filing date	Apr 3, 2018
Priority date	Jul 8, 2015
Publication date	Dec 14, 2021
Grant date	Dec 14, 2021

Abstract

According to one embodiment, a system for manufacturing a fully impregnated thermoplastic prepreg includes a mechanism for moving a fabric or mat and a drying mechanism that removes residual moisture from at least one surface of the fabric or mat. The system also includes a resin application mechanism that applies a reactive resin to the fabric or mat and a press mechanism that presses the coated fabric or mat to ensure that the resin fully saturates the fabric or mat. The system further includes a curing oven through which the coated fabric or mat is moved to polymerize the resin and thereby form a thermoplastic polymer so that upon exiting the oven, the fabric or mat is fully impregnated with the thermoplastic polymer. During at least a portion of the process, humidity in the vicinity of the coated fabric or mat is maintained at substantially zero.

First claim

What is claimed is:

1. A system for manufacturing a fully impregnated thermoplastic prepreg in a continuous process, the system comprising:
a mechanism for moving a fabric or mat from a starting point to an ending point, the fabric or mat being subjected to a plurality of processes between the starting point and the ending point;
a fabric or mat drying mechanism that is configured to remove residual moisture from the fabric or mat as the fabric or mat is moved past the drying mechanism;
a resin application mechanism that is positioned atop the fabric or mat and that is configured to apply liquid monomers or oligomers to the fabric or mat as the fabric or mat is passed under the resin application mechanism, wherein the liquid monomers or oligomers are polymerizable to form a thermoplastic polymer;
a press mechanism that is configured to press the liquid monomers or oligomers through the fabric or mat as the fabric or mat is moved past or through the press mechanism so that the liquid monomers or oligomers fully saturate the fabric or mat; and
a curing oven having a temperature of greater than 120 degrees Celsius, the curing oven being configured to effect polymerization of the liquid monomers or oligomers to form the thermoplastic polymer as the fabric or mat is moved through the curing oven such that the fabric or mat is fully impregnated with the thermoplastic polymer;
wherein the resin application mechanism is positioned above a bottom belt of the press mechanism so that the liquid monomers or oligomers are applied to the fabric or mat as the fabric or mat is passed under the resin application mechanism and atop the bottom belt, wherein the bottom belt of the press mechanism extends from the curing oven; and
wherein the resin application mechanism is positioned immediately adjacent to an inlet of the curing oven so that the fabric or mat is passed directly into the curing oven after the liquid monomers or oligomers are applied by the resin application mechanism.

2. The system of claim 1 , further comprising a mixing component that mixes the liquid monomers or oligomers with at least one of a catalyst and an activator, wherein the catalyst and activator facilitate in polymerizing the liquid monomers or oligomers to form the thermoplastic polymer.

3. The system of claim 2 , wherein the mixing component and resin application mechanism are heated to above a melting temperature of the monomers or oligomers.

4. The system of claim 1 , further comprising a gas application mechanism that is positioned to blow a moisture-free gas onto one or more surfaces of the fabric or mat in order to substantially prevent exposure of the monomers or oligomers to ambient moisture in a surrounding environment.

5. The system of claim 4 , wherein the gas application mechanism blows nitrogen gas onto one or more surfaces of the fabric or mat.

6. The system of claim 1 , wherein the liquid monomers or oligomers comprise caprolactam, laurolactam, lactones, cyclic butylene terephthalate (CBT), or mixtures thereof.

7. The system of claim 1 , wherein the fabric or mat includes a sizing composition having a coupling agent that promotes bonding between the fabric or mat and the thermoplastic polymer.

8. The system of claim 1 , wherein the press mechanism is a double belt compression press that sandwiches the fabric or mat between two belts.

9. The system of claim 1 , wherein the liquid monomers or oligomers have a viscosity of 10 centipoises or less.

10. The system of claim 1 , wherein the resin application mechanism is positioned within an enclosure that is purged with a substantially moisture-free gas in order to maintain a moisture-free environment in the vicinity of the fabric or mat.

11. The system of claim 1 , wherein the fabric or mat includes multiple layers of woven materials, and wherein each layer of woven material is fully impregnated with the thermoplastic polymer.

12. The system of claim 1 , wherein the fabric or mat includes glass fibers, carbon fibers, basalt fibers, metal fibers, ceramic fiber, natural fibers, synthetic organic fibers, aramid fibers, inorganic fibers, or combinations thereof.

13. The system of claim 1 , wherein the fabric or mat includes chopped fibers.

14. A system for manufacturing a prepreg comprising:
a mechanism for moving a fabric or mat along the system;
a drying mechanism that removes residual moisture from the fabric or mat;
a resin application mechanism that applies a reactive resin to the fabric or mat;
a gas application mechanism that is separate from the resin application mechanism;
a press mechanism that presses the fabric or mat subsequent to application of the resin to ensure that the resin fully saturates the fabric or mat; and
a curing oven through which the fabric or mat is moved to polymerize the resin and thereby form a thermoplastic polymer so that upon exiting the curing oven, the fabric or mat is fully impregnated with the thermoplastic polymer;
wherein the gas application mechanism blows a moisture-free gas onto one or more surfaces of the fabric or mat to maintain a moisture free environment in the vicinity of the fabric or mat prior to subjecting the fabric or mat to the curing oven in order to substantially prevent exposure of the resin to ambient moisture in a surrounding environment; and
wherein the resin application mechanism is positioned above a bottom belt of the press mechanism so that the resin is applied to the fabric or mat while the fabric or mat is positioned atop the bottom belt, wherein the bottom belt of the press mechanism extends from the curing oven.

15. The system of claim 14 , further comprising a mixing mechanism that mixes the resin with at least one of a catalyst and an activator prior to application of the resin to the fabric or mat.

16. The system of claim 14 , further comprising a winding mechanism that winds the fully impregnated fabric or mat into a roll product after the fully impregnated fabric or mat exits the curing oven.

17. The system of claim 14 , wherein the resin comprises caprolactam, laurolactam, lactones, cyclic butylene terephthalate (CBT), or mixtures thereof.

18. The system of claim 14 , wherein the resin application mechanism is positioned within an enclosure so as to maintain a moisture-free environment in the vicinity of the fabric or mat.

19. The system of claim 14 , wherein the fabric or mat includes multiple layers of woven materials, and wherein each layer of woven material is fully impregnated with the thermoplastic polymer.

20. The system of claim 14 , wherein the fabric or mat includes glass fibers, carbon fibers, basalt fibers, metal fibers, ceramic fiber, natural fibers, synthetic organic fibers, aramid fibers, inorganic fibers, or combinations thereof.

21. The system of claim 14 , wherein the fabric or mat includes chopped fibers.

22. The system of claim 1 , further comprising a single holding tank that includes the liquid monomers or oligomers, and wherein a catalyst or an activator is pre-applied to fibers of the fabric or mat.

23. The system of claim 22 , wherein the single holding tank includes a mixture of the liquid monomers or oligomers and the activator or catalyst that is not pre-applied to fibers of the fabric or mat.

24. The system of claim 23 , wherein the single holding tank includes a mixture of the liquid monomers or oligomers and the catalyst, and wherein the activator is pre-applied to the fibers of the fabric or mat.

Assignees

• Johns Manville

Inventors

• Zhang Mingfu
• Gleich Klaus Friedrich
• Yohannes Asheber
• Block Michael John
• Asrar Jawed
• Bristol Derek Cooper
• Sandoval Christopher P

Classifications

• D06N3/0086

  characterised by the application technique · CPC title

• D06M23/00

  Treatment of fibres, threads, yarns, fabrics or fibrous goods made from such materials, characterised by the process · CPC title

• D06M15/715

  Suction; Vacuum treatment; Degassing; Blowing · CPC title

• B29C70/504

  using rollers or pressure bands (for corrugating B29C53/22) · CPC title

• B29C70/502

  by first forming a mat composed of short fibres · CPC title