Use of aqueous dispersion of siloxane for reducing grain puffing of wood substrate and article comprising anti-grain puffing coating

Patent metadata

Field	Value
Publication number	US-11198230-B2
Application number	US-201816506016-A
Country	US
Kind code	B2
Filing date	Jan 11, 2018
Priority date	Jan 11, 2017
Publication date	Dec 14, 2021
Grant date	Dec 14, 2021

Abstract

The present disclosure relates to use of an aqueous dispersion of siloxane for reducing grain puffing of a wood substrate and an article comprising an anti grain puffing coating. The article comprises (a) a wood substrate having at least one major surface; (b) an anti grain puffing coating directly applied on the major surface of the wood substrate, formed from an aqueous dispersion of siloxane; and (c) one or more coatings applied on the anti grain puffing coating, formed from an aqueous coating composition, wherein the siloxane contains one or more hydrophobic group and one or more hydrophilic group chemically bonded to its molecule skeleton; and wherein the siloxane has a particle size in the range of 5 to 100 nm.

First claim

What is claimed is:

1. An article comprising
(a) a wood substrate having at least one major surface;
(b) an anti grain puffing coating directly applied on the major surface of the wood substrate, formed from an aqueous dispersion of a siloxane; and
(c) one or more coatings applied on the anti grain puffing coating, formed from an aqueous coating composition,
wherein the siloxane has the following structure:

in which
R represents independently, at each occurrence, optionally substituted C1-C20 alkyl or C6-C10 aryl;
X represents independently, at each occurrence, a hydrophilic group;
m is an integer of greater than or equal to 1 and less than 50,
n is an integer of greater than or equal to 1 and less than 50, and
the sum of m and n is an integer of greater than or equal to 2;
wherein the siloxane contains one or more hydrophobic group and one or more hydrophilic group chemically bonded to its molecule skeleton;
wherein the siloxane has a particle size in the range of 5 to 100 nm; and
wherein the siloxane comprises a mixture of the siloxane and the mixture has a ratio of m to n in the range of 0.8:1 to 1.2:1.

2. The article as claimed in claim 1 , wherein the aqueous dispersion has a viscosity of 100 mPa·s or less at 25° C.

3. The article as claimed in claim 1 , wherein the hydrophilic group comprises an amino functional group or an acid functional group selected from the group consisting of the functional groups of carboxylic acid, sulfuric acid, phosphoric acid, sulfonic acid, phosphorous acid, phosphonic acid, or salt thereof.

4. The article as claimed in claim 3 , wherein the hydrophilic group is selected from the group consisting of an amino C 1-8 alkyl group and a carboxyl C 1-8 alkyl group.

5. The article as claimed in claim 1 , wherein the R is selected from the group consisting of methyl, ethyl, propyl, butyl, pentyl, hexyl, heptyl, octyl, nonyl, decyl, undecyl, dodecyl, tridecyl, tetradecyl, pentadecyl, hexadecyl, octadecyl and eicosyl, preferably substituted with halogen, more preferably with F.

6. The article of claim 1 , wherein the wood substrate comprises a soft wood substrate, a hard wood substrate or any combination thereof;
wherein the soft wood substrate comprises pine, cedar or fir; and
wherein the hard wood substrate comprises ashtree, white ash, basswood, elm, maple, birch, alder, beech, oak, rubber wood, cherry, walnut, or rosewood.

7. The article of claim 1 , wherein the coatings comprise a primer coating, an intermediate coating, a topcoat coating or any combination thereof.

8. The article of claim 1 , wherein the aqueous coating composition is selected from the group consisting of a water soluble coating composition and a water dispersible coating composition.

9. The article as claimed in claim 8 , wherein the water dispersible coating composition contains an aqueous dispersion of organic silicone, styrene-acrylate, acrylate, organic silicone-modified acrylate, vinyl acetate, vinyl acetate-acrylate, vinyl acetate-ethylene, vinyl acetate-acrylate-esters of versatic acid, polyurethane, acrylate-polyurethane or any combination thereof.

10. The article as claimed in claim 8 , wherein the water soluble coating composition contains polyvinyl alcohol.

11. An aqueous dispersion for reducing grain puffing of a wood substrate, comprising siloxane,
wherein the siloxane has the following structure:

in which
R represents independently, at each occurrence, optionally substituted C1-C20 alkyl or C6-C10 aryl;
X represents independently, at each occurrence, a hydrophilic group;
m is an integer of greater than or equal to 1 and less than 50,
n is an integer of greater than or equal to 1 and less than 50, and
the sum of m and n is an integer of greater than or equal to 2;
wherein the siloxane contains one or more hydrophobic group and one or more hydrophilic group chemically bonded to its molecule skeleton;
wherein the siloxane has a particle size in the range of 5 to 100 nm; and
wherein the siloxane comprises a mixture of siloxane, and the mixture has a ratio of m to n is in the range of 0.8:1 to 1.2:1.

12. The aqueous dispersion of claim 11 , wherein the aqueous dispersion has a viscosity of 100 mPa·s or less at 25° C.

Assignees

• Swimc Llc

Inventors

• Duan Gang
• Fan Shigang

Classifications

• B27K3/50 Primary

  Mixtures of different organic impregnating agents · CPC title

• B27K3/15

  Impregnating involving polymerisation {including use of polymer-containing impregnating agents (macromolecular compounds derived from lignocellulosic materials C08H; compositions of lignin-containing materials C08L97/02)} · CPC title

• C08F2500/17

  Viscosity · CPC title

• B05D2518/10

  Silicon-containing polymers · CPC title

• C09D15/00 Primary

  Woodstains · CPC title