Method for making composite structure with porous metal

Patent metadata

Field	Value
Publication number	US-11192337-B2
Application number	US-201715798756-A
Country	US
Kind code	B2
Filing date	Oct 31, 2017
Priority date	Jun 9, 2017
Publication date	Dec 7, 2021
Grant date	Dec 7, 2021

Abstract

A method for making composite structure with porous metal comprising: S20, providing a substrate; S30, fixing a porous metal structure on the substrate to obtain a first middle structure; S40, fixing at least one carbon nanotube structure on the porous metal structure in the first middle structure to obtain a second middle structure; and S50, shrinking the second middle structure to form a composite structure with porous metal.

First claim

What is claimed is:

1. A method for making a composite structure with porous metal comprising:
providing a substrate;
fixing a porous metal structure on the substrate to obtain a first middle structure, wherein the porous metal structure defines a plurality of pores; the porous metal structure comprises a first surface and a second surface opposite to the first surface, the first surface is in contact with the substrate; and a material of the porous metal structure is selected from the group consisting of silver, platinum, and gold;
laying a carbon nanotube wire or a carbon nanotube film on the second surface of the porous metal structure, wherein the carbon nanotube wire or the carbon nanotube film consists of a plurality of carbon nanotubes extending along a same direction, so that only the plurality of carbon nanotubes is on the second surface of the porous metal structure when laying the carbon nanotube wire or the carbon nanotube film on the second surface of the porous metal structure, and the plurality of carbon nanotubes still extend along a same direction, to obtain a second middle structure; and the plurality of carbon nanotubes covers the porous metal structure; and
shrinking the second middle structure to form the composite structure with a porous metal.

2. The method of claim 1 , wherein the substrate is made of plastic, the substrate is melted by heating to bond the porous metal structure.

3. The method of claim 2 , wherein the plastic is polystyrene.

4. The method of claim 1 , wherein the porous metal structure is a nanoporous gold film, wherein the method further comprises: making the nanoporous gold film by:
providing a gold and silver alloy film;
placing the gold and silver alloy film in a concentrated nitric acid solution to form the nanoporous gold film until the gold and silver alloy film is changed from a silver-white color film to a brown-red color film; and
cleaning the nanoporous gold film by deionized water.

5. The method of claim 1 , wherein the plurality of carbon nanotubes form at least one carbon nanotube structure, in arranging the plurality of carbon nanotubes on the porous metal structure, the method further comprises: dropping an organic binder material to a surface of the at least one carbon nanotube structure, wherein the organic binder material permeates into the porous metal structure from micropores in the carbon nanotubes; and the organic binder material envelops at least one contact surface between the porous metal structure and the at least one carbon nanotube structure.

6. The method of claim 5 , wherein the plurality of carbon nanotubes are arranged so that micropores are defined by adjacent carbon nanotubes to facilitate permeation of the organic binder material.

7. The method of claim 1 , wherein in arranging the plurality of carbon nanotubes on the porous metal structure, the method further comprises:
transferring the second middle structure into a metal ion solution; and
adding a reducing agent to the metal ion solution to form metal atoms, wherein the metal atoms are deposited around at least one contact surface between the porous metal structure and the plurality of carbon nanotubes.

8. The method of claim 7 , wherein the metal ion solution is selected from a group consisting of gold ion, silver ion, copper ion, and a combination thereof.

9. The method of claim 1 , wherein the method of shrinking the second middle structure comprises heating the second middle structure so that the substrate in the second middle structure shrinks.

10. The method of claim 1 , wherein the porous metal structure is fixed on the substrate and the plurality of carbon nanotubes is arranged on the porous metal structure, and the substrate drives the porous metal structure and the plurality of carbon nanotubes to shrink together.

11. The method of claim 1 , wherein the porous metal structure and the plurality of carbon nanotubes are shrunk together to form a plurality of wrinkled parts, and the plurality of wrinkled parts are connected to each other to form a continuous structure.

12. The method of claim 1 , wherein the method of shrinking the second middle structure comprises heating the second middle structure to a temperature of approximately 160° C. for approximately 2 minutes.

13. The method of claim 1 , wherein the plurality of carbon nanotubes form at least one carbon nanotube structure, the at least one carbon nanotube structure is placed on the second surface, thereby forming a three layered structure consisting of the at least one carbon nanotube structure, the porous metal structure, and the substrate stacked said order.

14. The method of claim 1 , wherein the plurality of carbon nanotubes form at least one carbon nanotube structure, and the at least one carbon nanotube structure follows an outer profile of the porous metal structure.

15. The method of claim 1 , wherein the plurality of carbon nanotubes form at least one carbon nanotube structure, and the at least one carbon nanotube structure is placed on the second surface to cover an outer profile of the porous metal structure.

16. The method of claim 1 , wherein the plurality of carbon nanotubes is substantially parallel to each other to form a bundle-like structure.

17. A method for making a composite structure with porous metal comprising:
providing a substrate;
fixing a porous metal structure on the substrate to obtain a first middle structure, wherein the porous metal structure defines a plurality of pores; and a material of the porous metal structure is selected from the group consisting of silver, platinum, and gold;
fixing at least one carbon nanotube structure on a surface of the porous metal structure to obtain a second middle structure, wherein the at least one carbon nanotube structure consists of a plurality of carbon nanotubes extending along a same direction, so that only the plurality of carbon nanotubes is on the surface of the porous metal structure away from the substrate;
transferring the second middle structure into a metal ion solution;
adding a reducing agent to the metal ion solution to form metal atoms, wherein the metal atoms are deposited around contact surfaces of the porous metal structure and the at least one carbon nanotube structure to enclose the contact surfaces, and a material of the metal atoms is the same as a material of the porous metal structure; and
shrinking the second middle structure to form the composite structure with a porous metal.

18. The method of claim 17 , wherein the at least one carbon nanotube structure comprises at least one carbon nanotube wire, and the at least one carbon nanotube wire consists of the plurality of carbon nanotubes substantially parallel to each other to form a bundle-like structure.

19. The method of claim 17 , wherein a material of the porous metal structure is gold, so that the porous metal structure is a porous gold structure; and the second middle structure is transferred into a gold ion solution to form gold atoms, and the gold atoms are grown directly around the contact surfaces of the porous gold structure and the at least one carbon nanotube structure to enclose the contact surfaces.

20. The method of claim 17 , wherein the metal ion solution comprises a metal ion, and the metal ion is selected from gold ion, silver ion, copper ion, and a combination thereof.

Assignees

• Univ Tsinghua
• Hon Hai Prec Ind Co Ltd

Inventors

• Fu hong-ying
• Li Wen-Zhen

Classifications

• C23C18/42 Primary

  Coating with noble metals · CPC title

• C23C18/38

  Coating with copper · CPC title

• B32B37/06

  characterised by the heating method · CPC title

• C23C18/1648

  Porous product · CPC title

• B32B9/04

  comprising such {particular} substance as the main or only constituent of a layer, {which is} next to another layer of {the same or of} a {different material (next to a glass layer B32B17/06; layered products with at least two ceramic layers composed mainly of ceramic B32B18/00)} · CPC title