Catalytic composition and structures made thereof

Patent metadata

Field	Value
Publication number	US-11192095-B2
Application number	US-201615765212-A
Country	US
Kind code	B2
Filing date	Sep 30, 2016
Priority date	Sep 30, 2015
Publication date	Dec 7, 2021
Grant date	Dec 7, 2021

Abstract

A catalytic composition is built up from a ceramic material including a catalytic material and a first inorganic binder and a second inorganic binder and a catalytic structure made thereof. Preferably, the structure is made by a colloidal ceramic shaping technique. The structure is usable for catalytic or ion exchange applications as well. It is demonstrated that the catalytic structures have excellent mechanical, physicochemical and catalytic properties.

First claim

The invention claimed is:

1. A method of building a bulk catalytic structure, comprising:
shaping a composition comprising a ceramic material to obtain a green structure, wherein said ceramic material comprises a catalytic material and a first and a second inorganic binder, the shaping comprising preparing a suspension, slurry or paste of the composition and extruding the suspension, slurry or paste as fibers by three-dimensional fiber deposition to obtain the green structure, wherein the fibers are spaced apart to form a porous layered network;
the total amount of the first and second inorganic binder in the ceramic material comprising between 10 wt % and 50 wt % by total solid weight of the formed catalytic structure;
wherein the first inorganic binder is a clay material and the second inorganic binder is selected from: colloidal silica, colloidal alumina, colloidal zirconia, colloidal yttrium oxide, or colloidal tin oxide; or the first inorganic binder is selected from: colloidal silica, colloidal alumina, colloidal zirconia, colloidal yttrium oxide and the second inorganic binder is an inorganic thermohardening compound;
drying and calcining the green structure to obtain the bulk catalytic structure, wherein the structure is monolithic and comprises first channels having a length extending in a flow direction and second channels having a length extending in a radial direction, wherein the first channels and the second channels are fluidly connected.

2. The method claim 1 , wherein the fibers are spaced apart to define the first channels and/or the second channels between the fibers.

3. The method of claim 1 , wherein the layered network comprises alternating layers, the shaping step comprising arranging the fibers in the alternating layers oblique to one another.

4. The method of claim 3 , comprising arranging the fibers in the alternating layers orthogonal to one another.

5. The method of claim 3 , wherein the fibers are parallel to one another in each of the alternating layers.

6. The method of claim 3 , wherein the alternating layers comprise a first alternate layer and a second alternate layer, wherein a disposition of the fibers in successive ones of the first alternate layer is aligned and wherein a disposition of the fibers in successive ones of the second alternate layers is aligned.

7. The method of claim 3 , wherein the alternating layers comprise a first alternate layer and a second alternate layer, comprising disposing the fibers in successive ones of the first alternate layer aligned to one another and disposing the fibers in successive ones of the second alternate layer in a staggered fashion.

8. The method of claim 1 , wherein the fibers are straight.

9. The method of claim 1 , wherein the ratio of catalytic material to the first and the second inorganic binders comprises between 85/15 and 65/35 by weight.

10. The method of claim 1 , wherein the first channels are straight.

11. The method of claim 1 , wherein the first channels are tortuous.

12. The method of claim 1 , wherein the second channels are straight.

Assignees

• Vito Nv Vlaamse Instelling Voor Tech Onderzoek Nv
• Univ Antwerpen

Inventors

• Mullens Steven
• Protasova Lidia
• Lefevere Jasper

Classifications

• B01J29/40 Primary

  of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively · CPC title

• Y02P20/52

  using catalysts, e.g. selective catalysts · CPC title

• C10G2400/20

  C2-C4 olefins · CPC title

• C04B2111/0081

  as catalysts or catalyst carriers · CPC title

• C04B2111/00181

  Mixtures specially adapted for three-dimensional printing (3DP), stereo-lithography or prototyping · CPC title